IVAS 2022 banner
IVES 9 IVES Conference Series 9 IVAS 9 IVAS 2022 9 Specificities of red wines without sulfites: which role for acetaldehyde and diacetyl? A compositional and sensory approach.

Specificities of red wines without sulfites: which role for acetaldehyde and diacetyl? A compositional and sensory approach.

Abstract

Sulfur dioxide is the most commonly used additive in oenology to protect wine from oxidation and microorganisms. Once added to wine SO2 is able to react with carbonyl compounds to form carbonyl bisulfites what affects their reactivity. All together these carbonyl bisulfites correspond to bound SO2. The affinity of each carbonyl for sulfur dioxide is defined by the dissociation constant Kd of its carbonyl bisulfite. Among wine compounds, acetaldehyde which carbonyl bisulfite Kd is 2.4×10-3 mM is considered as the one with the highest affinity for SO2. Acetaldehyde origins is both an intermediary in alcoholic fermentation pathway but could also be produced from ethanol oxidation. Diacetyl (2,3 butanedione), has also a microbiological origin and an appreciable affinity for sulfur dioxide (carbonyl bisulfite Kd is 0.1 mM). Moreover, diacetyl is able to be produced but also reduced by yeasts and their potential sensory impact on red wines has already been established.
To evaluate if acetaldehyde and diacetyl could be at the origin of sensory specificities in wines without SO2, sensory profiles were classically determined, using sensory descriptors generation and panel training, on different modalities illustrating average levels of diacetyl, acetaldehyde and free SO2 in wines with or without sulfites and prepared from the same commercial without sulfites wine. Such an approach allowed to reveal that acetaldehyde and free SO2 were involved in the perception of “Coolness” depending of their concentrations in wines with and without added SO2. Diacetyl, meanwhile, impacted fruity aroma perception in wines with added SO2 and was responsible for sensory differences between wine with and without added SO2. Thus, the addition of diacetyl and SO2, at average concentrations found in wines with SO2, in a wine without added SO2 led to a decrease of “Fresh Black Fruits”, “Fresh Raspberry” and “Coolness” perception and an increase of “Jammy Black Fruits” perception.  These results are in line with sensory differences already highlighted in studies dealing with global olfactive characterization of reds wines with and without sulfites and help to explain red wines without sulfites sensory specificities

DOI:

Publication date: June 23, 2022

Issue: IVAS 2022

Type: Article 

Authors

Pelonnier-Magimel Edouard¹, Cameleyre Margaux¹, Riquier Laurent¹and Barbe Jean-Christophe ¹

¹Univ. Bordeaux, INRAE, ISVV, Bordeaux INP, Bordeaux Sciences Agro, OENO, UMR 1366, ISVV

Contact the author

Keywords

Wine without sulfites, acetaldehyde, diacetyl, carbonyl bisulfite, sensory analysis

Tags

IVAS 2022 | IVES Conference Series

Citation

Related articles…

INVESTIGATING TERROIR TYPICITY: A COMPREHENSIVE STUDY BASED ON THE AROMATIC AND SENSORIAL PROFILES OF RED WINES FROM CORBIÈRES APPELLATION

Volatile compounds play a significant role on the organoleptic properties defining wines quality. This particular role was exploited in several studies with the aim to differentiate wines from a more or less extensive production area, according to their sensory profile [1], as well as their chemical composition [2,3] (Di Paola-Naranjo et al., 2011; Kustos et al., 2020). Indeed, since aroma compounds development in grapes depends primarily on the environmental conditions of the vines and grapes (soil and climate), it is conceivable that these parameters craft the aromatic signature of the wine produced, in relation to its origin (Van Leeuwen et al., 2020). In this work, a general study on the aromatic and sensorial profile of wines produced in five sub-regions of the Corbières denomination, a renowned red grape varieties viticultural region in South France, was reported.

Oligosaccharides from Vitis vinifera grape seeds: a focus on gentianose as a novel bioactive compound

AIM. Grape seeds (Vitis vinifera) are among the main constituents of grape pomace, also exploited in ingredients for nutraceutics and cosmeceutics, particularly regarding the phenolic fraction. The macromolecules of grape/wine include polyphenols, proteins and polysaccharides.

Monitoring of mannoprotein cessions during wine aging on lees: development of a simple enzymatic method

Mannoproteins are polysaccharides released by Saccharomyces cerevisiae yeast during alcoholic fermentation or by enzymatic action during aging on yeast lees (autolysis). These molecules play a major role in wine characteristics processing, namely, in the tartaric stabilization and protein haze prevention; moreover, they improve color stability and reduce astringency.

Exploring intra-vineyard variability with sensor- and molecular-based approaches 

The application of remote and proximal sensing is a fast and efficient method to monitor grapevine vegetative and physiological parameters and is considered valuable to derive information on associated yield and quality traits in the vineyard. Further details can be obtained by the application of molecular analysis at the gene expression level aiming at elucidating how pathways controlling the formation of different grape quality traits are influenced by spatial variability. This work aims at evaluating intra-vineyard variability in grape composition at harvest and at comparing this with remotely sensed canopy vegetation data and molecular-based approaches.

Effects of different crop load and pruning aplications on vi̇ne growing, grape yi̇eld and quality parameters of early sweet (Vitis vinifera L.) grape variety

It is important to examine the yield quality elements of table grape varieties. There are great differences in winter and summer pruning of the early sweet grape variety. For this reason, in the study, the effects of different crop loads and pruning processes on grape yield, quality characteristics and vine development in the early sweet (vitis vinifera L.) Grape variety were investigated.