IVAS 2022 banner
IVES 9 IVES Conference Series 9 IVAS 9 IVAS 2022 9 Evaluating Smoke Contaminants in Wine Using 13C-Labelled Barley as a Fuel Source

Evaluating Smoke Contaminants in Wine Using 13C-Labelled Barley as a Fuel Source

Abstract

Wildfires are becoming more common in many areas of the world that are also associated with wine grape production, especially the Pacific northwest United States, Australia and even some areas of France. Wine grapes have shown to be incredibly sensitive towards the smoke produced from nearby wildfires, acquiring negative sensory characteristics, such as ashy, burnt, or campfire-like flavors and aromas. The chemical markers often associated with smoke, guaiacol and 4-ethyl guaiacol, can delineate the presence of a nearby fire, though there has been some disagreement on the chemical components responsible for some of the negative flavors and aromas.1,2 This study uses a 13C-tagged fuel source, barley (Hordeum vulgare), that is grown in 13CO2 for 10 days of its life cycle using pulse-labelling techniques. 13C content of the barley was evaluated using isotope ratio mass spectrometry, revealing 13C/12C content as high as 4.47 ± 0.75% compared to the natural ~1.08% for natural abundance in plant material. Grapes were exposed to 13C-labelled smoke in separate post- and pre-harvest trials, burning 5 g and 10 g dried barley bundles, respectively, every 30 minutes for 6 hours. Smoke density was piped “cold” to enclosures containing wine grapes and smoke was maintained at 20-100 mg/m3 for smoke particles < 1 μm, simulating a very nearby fire. The exposed grapes were Pinot noir and Chardonnay grown in Monroe, Oregon at Woodhall III Vineyards. The 13C is ideal for chemical identification using 13C-NMR after HPLC and GCMS separation and evaluation to identify novel targets for smoke chemicals affecting wine. Determining better chemical targets for amelioration will ultimately lead toward better, more targeted, amelioration techniques.

DOI:

Publication date: June 23, 2022

Issue: IVAS 2022

Type: Article

Authors

Cerrato D.Cole1, Garcia Lindsay1, Eberz Elaina1, Penner Mike1 and Tomasino Elizabeth1

1Oregon State University, 100 Wiegand Hall, 3051 SW Campus Way, Corvallis, Oregon, USA 97331

Contact the author

Keywords

Smoke, 13C, Pinot noir, Chardonnay

Tags

IVAS 2022 | IVES Conference Series

Citation

Related articles…

Discrimination of monovarietal Italian red wines using derivative voltammetry

Identification of specific analytical fingerprints associated to grape variety, origin, or vintage is of great interest for wine producers, regulatory agencies, and consumers. However, assessing such varietal fingerprint is complex, time consuming, and requires expensive analytical techniques. Voltammetry is a fast, cheap, and user-friendly analytical tool that has been used to investigate and measure wine phenolics.

Identification of several glycosidic aroma precursors in six varieties of winemaking grapes and assessment of their aroma potential by acid hydrolysis

In winemaking grapes, it is known that most aroma compounds are present as non-volatile precursors, such as glycosidic precursors. In fact, there is strong evidence supporting the connection between the content of aroma precursors and the aromatic quality of wine [1]. Acid hydrolysis is preferred to reveal the aroma potential of winemaking grapes, as it predicts more accurately the chemical rearrangements occurring during fermentation in acidic environments [2]. In this study, a method involving a fast fermentation followed by acid hydrolysis at 75ºC was used to evaluate the accumulation of aroma compounds over time in fractions obtained from six different varieties of winemaking grapes.

Polyphenol content examination of Tokaji Aszú wines

We must state that two conditions above are only prevalent in the case when the processed grapes are full or over ripened, besides following the Tokaj wines preparation criterions (grape variety, soil, microclimate, vintage, etc.). These two conditions mentioned before were followed up only sensory based analysis up to now, altough the study of chemical idetified compounds which confirms these are obviuos.

Three new Apulian seedless varieties available for the table grape supply chain

The table grape industry in Europe is undergoing significant changes. For instance, in Italy, the national register of vine varieties was established in 1969, and since then, many varieties of table grapes have been registered. In the first thirty years, from 1969 to 1999, 62 seeded and 24 seedless varieties were registered. In the subsequent period, from 2000 to the present day, 23 seeded varieties and 99 seedless varieties were registered.

Il Cabernet di Atina dal 1850 al giorni nostri: un esempio di valorizzazione del territorio

In the province of Frosinone from 1850 they are cultivated in some zones wine grape of French origin like Merlot, Cabernet franc Cabernet sauvignon, Sirah, Pinot noir. The insertion of these varieties was the work of Pasquale Visocchi in the great company of family “Fratelli Visocchi Proprietari” (F. V.P.).