IVAS 2022 banner
IVES 9 IVES Conference Series 9 IVAS 9 IVAS 2022 9 Struck flint aroma in Chardonnay wines: what causes it and how much is too much?

Struck flint aroma in Chardonnay wines: what causes it and how much is too much?

Abstract

Struck flint/struck match/gun smoke/mineral aroma is considered desirable in some styles of wines, with this character sometimes evident in wines such as Burgundian Chablis and cooler climate barrel-fermented Australian Chardonnay. Phenylmethanethiol (benzyl mercaptan) is a potent sulfur-containing volatile aroma compound and is thought to be responsible for struck flint character in wine. However, few studies targeting this character have been done. To address this, over 70 commercially available white wines, mostly Chardonnay, were chemically analysed to establish the variability of phenylmethanethiol, and the wines were assessed by a sensory panel to indicate whether there might be a transition from struck flint aroma to a less pleasant sulfurous/burnt aroma. Interestingly, another potent sulfur-containing aroma compound, 2-furylmethanethiol (furfuryl thiol), was also found in the wines and was at particularly high concentration in wines suggested as having high struck flint aroma. 2-Furylmethanethiol has previously been shown to form in white wines during alcoholic fermentation in the barrel from the furan-2-carbaldehyde (furfural) released by toasted oak staves reacting with the hydrogen sulfide produced by yeast. This survey highlighted that both phenylmethanethiol and 2-furylmethanethiol are linked to struck flint aroma but when higher levels of 2-furylmethanethiol are present, the character might tend toward sulfurous/burnt.

 There was also no information available on the effects of winemaking techniques and commonly used winemaking additives on the formation of phenylmethanethiol. Further investigations in model fermentations of its potential precursors benzaldehyde and hydrogen sulfide were conducted. Wine yeast strains that produced high concentrations of hydrogen sulfide resulted in higher concentrations of phenylmethanethiol during fermentation of a synthetic grape must and increasing concentrations of ammonia (YAN) promoted the formation of phenylmethanethiol by yeast during fermentation. Thus, different winemaking parameters could be used to modulate the concentrations of phenylmethanethiol in wine.

DOI:

Publication date: June 24, 2022

Issue: IVAS 2022

Type: Article

Authors

T. E. Siebert1*, D. Espinase Nandorfy1,2, A. G. Cordente1, L. Pisaniello1, F. T. Watson1, S. R. Barter1, D. Likos1, A. C. Kulcsar1, I. L. Francis1, and M. Z. Bekker1

1The Australian Wine Research Institute, Waite Precinct, Hartley Grove cnr Paratoo Road, Urrbrae 5064, Australia 
CASS Food Research Centre, School of Exercise and Nutrition Sciences, Deakin University 

Contact the author

Keywords

thiols, sensory, fermentation

Tags

IVAS 2022 | IVES Conference Series

Citation

Related articles…

Effect of one-year cover crop and arbuscular mycorrhiza inocululation in the microbial soil community of a vineyard

The microbial composition of the soil is an important factor to consider in viticulture, since its influence on the “terroir” and on the organoleptic properties of the wine have been demonstrated. Different agronomic techniques have the potential to modify the composition and functionality of the soil microbial community. Maintaining green covers is known to increase soil microbial diversity. The direct application of inoculum of beneficial microorganisms to the soil has also been used to increase their abundance. However, the environmental conditions of each site seem to have a determining weight in the result of these practices. In this study, we compared the effect on the microbial community of a cover crop with legumes in autumn and the inoculation of grapevines with commercial inoculum bases on Rhizophagus irregularis and Funeliformis mosseae in the previous spring. The study has been carried out in a vineyard in Binissalem, Mallorca, Spain. After applying the treatments, we will analyze the soil microbial communities using the data obtained from Illumina amplification of soil DNA from the 16S and ITS regions to analyze bacteria and fungi community, respectively. In addition, we will record the physicochemical characteristics of the soil at each sampling point. The result showed that agronomic management, in the short term, has less influence than soil characteristics on the composition of the soil microbiome. With these results, we can conclude that in a vineyard, agricultural techniques should focus on improving the characteristics of the soil to improve the biodiversity of the soil microbiota.

Influence of spraying of copper fungicides on physiological parameters of Vitis vinifera L. Cv. ‘Merlot’

Vine downy mildew is one of the most frequent diseases in intensive vineyards. Bordeaux mixture (B.m.), in order to control the disease has been applied onto vineyards since the end of the 19th century. The intensive use of Cu-fungicides could influence the physiology of grapevine. It is also possible that high amounts of foliar Cu sprays trigger stress responses in vine leaves.

Study of grape plant behaviour (cv. Chasselas) on various “terroirs” of the Vaud county (Switzerland)

L’étude du comportement physiologique et agronomique de la vigne (cv. Chasselas) a été réalisée en 2001 par la Station fédérale de recherches en production végétale de Changins sur divers terroirs viticoles vaudois (Suisse), dans le cadre d’un projet d’étude des terroirs viticoles vaudois en collaboration avec le bureau I LETESSIER (SIGALES) à Grenoble et l’École polytechnique fédérale de Lausanne (EPFL).

Impact of oenological tannins on microvinifications affected by downy mildew

AIM: Vine diseases are still responsible for economic losses. Previous study in our laboratory, have shown effects of oenological tannins against Botrytis cinerea1,2. According to this, the aim was to evaluate the wine protection by oenological tannins against an another disease, the downy mildew. METHODS: During the 2020 vintage, infected grapes by downy mildew (Vitis vinifera cv. Merlot) were collected from the dispositive ResIntBio. The 100 kg were crushed, destemmed and dispatch into 10 aluminium tanks. SO2 was added at 3 g/hL. Oenological tannins (grape, quebracho, ellagitannin or gallotannin) were added at 100 g/hL into eight different tanks (4×2 tanks). The two last tanks were considered as control without addition of oenological tannins. Alcoholic fermentation was achieved with Actiflore 33® at 20 g/hL. Malolactic fermentation was achieved with Lactoenos B7at 1 g/hL. Finished wines were sulfited to obtain 45 mg/L of total SO2.

Anticipating consumer preference for low-alcohol wine: a machine learning analysis based on consumption habits and socio-demographics

The global wine consumption landscape is undergoing a transformation, marked by a growing trend towards reduced consumption and a preference for healthier lifestyles. In line with this shift, european union regulation (regulation eu 2021/2117) has recently redefined dealcoholized or partially dealcoholized wine within the wine category.