IVAS 2022 banner
IVES 9 IVES Conference Series 9 IVAS 9 IVAS 2022 9 Comparative study of the volatile substances and ellagitannins released to wine by barrels of Quercus pyrenaica, Quercus petraea and Quercus alba

Comparative study of the volatile substances and ellagitannins released to wine by barrels of Quercus pyrenaica, Quercus petraea and Quercus alba

Abstract

Aim: The aim of the study was to study the volatile substances and ellagitannins released to wine by barrels of Quercus pyrenaica (Spanish Oak) in comparison with barrels of Quercus petraea (French Oak) and Quercus alba (American Oak) as well as to determine their sensory impact. 

Materials and methods: For that purpose, a red wine of Cabernet Sauvignon from 2016 vintage was aged for 12 months in new barrels of these three oak species. A similar wine from the following vintage (2017) was aged in the same barrels for knowing how the use of the barrels affects their capacity to release volatile substances and its organoleptic impact. The volatile compounds released from the oak wood were analyzed by GC/MS according with the procedure described by Ibarz et al. (2006). The ellagitannins were analyzed by HPLC-DADESI-MS/MS according with the method reported by Navarro et al. (2017). Dscriptive sensory analysis was performed by a trained panel. This panel was made up of 16 students (10 males and 6 females) aged between 21 and 25, who had been training together for 3 years while studying sensory analysis as part of the enology degree.

Results and discussion: As expected, the wine aged in new Q. alba barrels presented the highest concentration in β-methyl-γ-octalactones and the lowest concentration of ellagitannins whereas the wine aged in new Q. petraea barrels presented much higher concentration of ellagitannins and much lower concentration of β-methyl-γ-octalactones. In contrast, the wine aged in new Q. pyrenaica barrels presented a concentration of ellagitannins even higher than the wine aged in new Q. petraea barrels and an intermediate concentration of β-methyl-γ-octalactones. No significant differences were found in vanillin and other volatile substances. Finally, ellagitannins and all volatile substances concentration decreased drastically the wines aged in all the one year used barrels. In general, the results of sensory analysis showed that wines aged in Q. pyrenaica barrels were somewhat less appreciated than those aged in barrels of Q, petraea but better than those aged in barrels of Q. alba.

Conclusions: The main conclusion is that Q. pyrenaica has a great interest as a source of wood for cooperage.

References

Ibarz M., Ferreira V., Hernández-Orte P., Loscos N. and Cacho J., 2006. Optimization and evaluation of a procedure for the gas chromatographic-mass spectrometric analysis of the aromas generated by fast acid hydrolysis of flavors precursors extracted from grapes. Journal of Chromatography A, 1116, 217–229. doi:10.1016/j.chroma.2006.03.020
Navarro M., Kontoudakis N., Canals J.M., García- Romero E., Gómez-Alonso S., Zamora F., and Hermosín-Gutíerrez I., 2017. Improved method for the extraction and chromatographic analysis on fused-core columns of occurring ellagitannins in oak-aged wine. Food Chemistry, 226, 23–31. doi:10.1016/j. foodchem.2017.01.043

DOI:

Publication date: June 24, 2022

Issue: IVAS 2022

Type: Poster

Authors

Zamora Fernando1, Gombau Jordi1, Cabanillas Pedro1, Mena Adela2, Gómez-Alonso Sergio3, García-Romero Esteban2 and Canals Joan Miquel1

1Departament de Bioquímica i Biotecnologia, Facultat d’Enologia de Tarragona, Universitat Rovira i Virgili 
2Instituto Regional de Investigación y Desarrollo Agroalimentario y Forestal de Castilla-La Mancha (IRIAF), IVICAM, Tomelloso, Ciudad Real, Spain 
3Universidad de Castilla-La Mancha, Instituto Regional de Investigación Científica Aplicada. Universidad de Castilla-La Mancha 

Contact the author

Keywords

Oak; Q. pyrenaica; Barrels; Volatile substances; Ellagitannins

Tags

IVAS 2022 | IVES Conference Series

Citation

Related articles…

Grapevine sugar concentration model in the Douro Superior, Portugal

Increasingly warm and dry climate conditions are challenging the viticulture and winemaking sector. Digital technologies and crop modelling bear the promise to provide practical answers to those challenges. As viticultural activities strongly depend on harvest date, its early prediction is particularly important, since the success of winemaking practices largely depends upon this key event, which should be based on an accurate and advanced plan of the annual cycle. Herein, we demonstrate the creation of modelling tools to assess grape ripeness, through sugar concentration monitoring. The study area, the Portuguese Côa valley wine region, represents an important terroir in the “Douro Superior” subregion. Two varieties (cv. Touriga Nacional and Touriga Franca) grown in five locations across the Côa Region were considered. Sugar accumulation in grapes, with concentrations between 170 and 230 g l-1, was used from 2014 to 2020 as an indicator of technological maturity conditioned by meteorological factors. The climatic time series were retrieved from the EU Copernicus Service, while sugar data were collected by a non-profit organization, ADVID, and by Sogrape, a leading wine company. The software for calibrating and validating this model framework was the Phenology Modeling Platform (PMP), version 5.5, using Sigmoid and growing degree-day (GDD) models for predictions. The performance was assessed through two metrics: Roots Mean Square Error (RMSE) and efficiency coefficient (EFF), while validation was undertaken using leave-one-out cross-validation. Our findings demonstrate that sugar content is mainly dependent on temperature and air humidity. The models achieved a performance of 0.65

Modeling island and coastal vineyards potential in the context of climate change

Climate change impacts regional and local climates, which in turn affects the world’s wine regions. In the short term, these modifications rises issues about maintaining quality and style of wine, and in a longer term about the suitability of grape varieties and the sustainability of traditional wine regions. Thus, adaptation to climate change represents a major challenge for viticulture. In this context, island and coastal vineyards could become coveted areas due to their specific climatic conditions. In regions subject to warming, the proximity of the sea can moderate extremes temperatures, which could be an advantage for wine. However, coastal and island areas are particular prized spaces and subject to multiple pressures that make the establishment or extension of viticulture complex.
In this perspective, it seems relevant to assess the potentialities of coastal and island areas for viticulture. This contribution will present a spatial optimization model that tends to characterize most suitable agroclimatic patterns in historical or emerging vineyards according to different scenarios. Thanks to an in-depth bibliography a global inventory of coastal and insular vineyards on a worldwide scale has been realized. Relevant criteria have been identified to describe the specificities of these vineyards. They are used as input data in the optimization process, which will optimize some objectives and spatial aspects. According to a predefined scenario, the objectives are set in three main categories associated with climatic characteristics, vineyards characteristics and management strategies. At the end of this optimization process, a series of maps presents the different spatial configurations that maximize the scenario objectives.

Sustainable fertilisation of the vineyard in Galicia (Spain)

Excessive fertilization of the vineyard leads to low quality grapes, increased costs and a negative impact on the environment. In order to establish an integrated management system aimed at a sustainable fertilization of the vineyards, nutritional reference levels were established. For this purpose, 30 representative vineyards of the Albariño variety were studied, in which soil and petiole analyses were carried out for two years and grape yield and quality at harvest were measured. In both years of study, soil pH, calcium, sodium and cation exchange capacity were positively correlated with calcium content and negatively correlated with manganese in grapes. Irrigated vineyards had higher levels of aluminium in soil and lower levels of calcium in petiole. Climatic conditions were very different in the years of the study. The year 2019 was colder than usual, in 2020 there was a marked water stress with high summer temperatures. This resulted in medium-high acidity in grapes in 2019 and low acidity in 2020, with sugar levels being similar both years. A very marked decrease in must amino nitrogen was observed in 2020, with ammonia nitrogen remaining stable. The correlation of acidity and sugar values in grapes with soil and petiole analysis data made it possible to establish reference levels for the nutritional diagnosis of the Albariño variety in this region. Based on these results, an easy-to-use TIC application is currently being created for grapegrowers, aimed at improving the sustainability of the vineyard through reasoned fertilization. This study has now been extended to other Galician vine varieties.

Impact of climate change on the viticultural climate of the Protected Designation of Origin “Jumilla” (SE Spain)

Protected Designation of Origin “Jumilla” (PDO Jumilla) is located in the Spanish provinces of Albacete and Murcia, in the South-eastern part of the Iberian Peninsula, where most of the models predict a severe impact of climate change in next decades. PDO Jumilla covers an area of 247,054 hectares, of which more than 22,000 hectares

Spatial variability of temperature is linked to grape composition variability in the Saint-Emilion winegrowing area

Elevated temperature during the grape maturation period is a major threat for grape quality and thus wine quality. Therefore, characterizing the grape composition response to temperature at a larger scale would represent a crucial step towards adaptation to climate change. In response to changes in temperature, various physiological mechanisms regulate grape composition. Primary and secondary metabolisms are both involved in this response, with well-known effects, for example on anthocyanins, and lesser known effects, for example on aromas or aroma precursors. At the field scale or at the regional scale, however, numerous environmental or plant-specific factors intervene to make the effects of temperature difficult to distinguish from overall variability. In this study, it was attempted to overcome this difficulty by selecting well-characterized situations with differing temperatures.
A long-term study of air temperature variability across several Merlot vineyards in the Saint-Emilion and Pomerol wine producing area found significant temperature differences and gradients at various time scales linked to environmental factors. From this study area, a few sites were selected with similar age, soil and training system conditions, and with repeated and contrasted temperature differences during the maturation period. The average temperature difference during the maturation period was about 2°C between cooler and warmer sites, a difference similar to that expected under future climate change scenarios. In close vicinity to the temperature sensors at each site, grape berries were sampled at different times until full maturity during 2019 and 2020. Also, berries from bunches on either side of the row were analyzed separately, allowing an investigation of bunch exposure effect associated with the coupling of berry temperature and solar radiation. Four replicates of pooled berries for each time – site – bunch exposure combination were obtained and analyzed for biochemical composition. Analyses of variance of the biochemical composition data collected at different sampling times reveal significant effects associated with temperature, site, and bunch azimuth. For instance, anthocyanins in grape skins are clearly influenced by temperature and solar radiation exposure, with up to 30% reduction in warmer conditions.