Macrowine 2021
IVES 9 IVES Conference Series 9 Oligosaccharides in red wines: could their structure and composition be influenced by the grape-growing

Oligosaccharides in red wines: could their structure and composition be influenced by the grape-growing

Abstract

Oligosaccharides have only recently been characterized in wine, and the information on composition and content is still limited. In wine, these molecules are mainly natural byproducts of the degradation of grape berry cell wall polysaccharides. Wine oligosaccharides present several physicochemical properties, being one relevant factor linked to the astringency perception of wines (1,2). A terroir can be defined as a grouping of homogeneous environmental units based on the typicality of the products obtained. This notion is particularly associated with wine, being the climate and the soil two of the major elements of terroir concept. Monastrell red wines, predominant varietal wines from the Southern of Spain, were elaborated with grapes from four different terroirs: Cañada Judío, Albatana, Bullas and Montealegre. Climate and soil data from different terroirs were gathered to properly distinguish them. Oligosaccharide fractions from wines were isolated, after removal of phenolic compounds, by high resolution size-exclusion chromatography. The glycosyl–linkages composition was determined by GC–MS of the partially methylated alditol acetates. Results show differences in the glycosyl–linkages composition of oligosaccharides from wines, according to their terroir. The molar percentage of glucose, rhamnose, arabinose, xylose and mannose residues exhibit marked differences depending on the terroir. The ratio of the terminal to the branched residues for Cañada Judío, Albatana, Bullas and Montealegre oligosaccharides is, respectively, 0.75, 0.85, 0.99 and 0.89. Proportions of oligosaccharides families have been calculated from glycosyl-linkage data (3,4,5). Montealegre wine clearly presents the lowest relative molar percentage for the oligosaccharides from yeasts (the sum of OligoGlucans and OligoMannans) and also for OligoXyloGlucans, whereas Bullas wine exhibits by far the lowest release of OligoRhamnogalacturonans. OligoArabinans and OligoArabiGalactans type II also show differences according to the terroir. All these data were treated by PCA to permit a best understanding. The projections on the first axis show obvious separation of Montealegre, whereas a clear separation of Albatana is observed in the projections on the second axis. The first and second principal components represent, respectively, 69% and 19% of the variability for samples. In summary, our results suggest the impact of “terroir” on the structure and the composition of wine oligosaccharide fraction, which could affect their physicochemical and sensory properties.

1.Quijada-Morín et al. (2014). Food Chem. 154, 44–51. 2.Boulet et al. (2016). Food Chem. 190, 357–363 3.Ducasse et al. (2011). J Agric Food Chem. 59, 6558–6567. 4.Ballou (1982). In Strathern, Jones & Broach (Eds.), Metabolism and gene expression (335–360), NY. 5.Fry et al. (1983). Plant Physiol. 89, 1–3.

Publication date: May 17, 2024

Issue: Macrowine 2016

Type: Poster

Authors

Rafael Apolinar-Valiente*, Encarna Gómez-Plaza, José María Ros-García, Pascale Williams, Thierry Doco

*INRA Montpellier

Contact the author

Tags

IVES Conference Series | Macrowine | Macrowine 2016

Citation

Related articles…

How pressing techniques affect must composition and wine quality of Pinot blanc

This study investigates how the sensory profile of Pinot Blanc is affected from different maceration and pressing techniques. Grapes were sourced from four vineyards in the village Tramin in South Tyrol. For the experiment 200 kg of grapes from each vineyard site were hand picked the day before harvest for the commercial winery took place. Grapes were stored over night at 4°C, homogenized and processed in the experimental winery at Laimburg research centre the day after harvest. Four different pressing techniques were applied in duplicates of 100kg each.

Sensory and nephelometric analysis of tannin fractions obtained by ultrafiltration of red wines

The assessment of red wine mouthfeel relies primarily on the sensory description of its tannic properties. This evaluation could be improved by gaining a better understanding of the physicochemical properties of these tannins. Hence, the objectives of the present study were threefold: (1) to gain an insight into the sensory properties of subpopulations of proanthocyanidic tannins of different molecular sizes obtained through several ultrafiltration steps, (2) to quantify the kinetics of haze formation of these proanthocyanidic tannins in a dynamic polyvinylpyrrolidone (PVP) precipitation test, (3) to determine whether a correlation exists between the sensory and the precipitation data.

Enological evaluation of the attitude of the grapevine fumin to give varietal wines

Initiatives have been ongoing in recent years to safeguard biodiversity in the oenological sector via a process of enhancement of ancient varieties, under a pressure of a market strongly oriented towards production deriving from native vines of specific geographical zones. In that sense, Aosta Valley
(Italy) has raised the need to preserve and characterize its minority vine varieties which have the potentiality to give varietal wines. Fumin represents the 7% of the production of the region with 16 hectares of vineyards and 753 hectolitres of derived wine. Due to its large phenolic potential, strong astringency and deep colour, it has long been, and is still today, assembled or blended with other varieties as occurs, for example, for the Torrette.

What about oxygen transfer during wine aging in barrels?

During wine aging, several complex phenomena of gas transfer take place in barrels due to the wine/oak contact. The efficiency of this gas transfer varies according to oak wood’s intrinsic physical properties. This research aims to better understand oxygen transfer phenomena through dry oak staves and especially through stave gaps, in order to reevaluate the importance of barrel-making on a barrel’s supply of oxygen. Experimentation was based on the development of an innovative permeameter of laboratory scale, for which the principal operating conditions concerning applied pressure, the choice of liquid phase/gas phase, and the grain type of oak are taken into account and investigated. With a specially developed tightening system, the existing pressure at stave gaps in a barrel could be reproduced on a laboratory scale in order to estimate its influence on oxygen transfer efficiency.

Effect of concentration and competition between different fungicide residues on the adsorption efficiency of activated vegetal fibres for treatment of wine

Vineyards are strongly exposed to fungal diseases, attacks from insects and competition with weeds. Most treatments used on grape vines contain synthetic active substances, which may be transferred to the wine. Such pesticides have a negative image because many active substances are potential health hazards. A specific oenological treatment allowing the reduction of pesticide residues in wine based on activated vegetable fibres (AVF) is under examination by the International Organisation for Vine and Wine. This technique works efficiently and alters the wine only little (Lempereur et al. 2014).