Macrowine 2021
IVES 9 IVES Conference Series 9 Oligosaccharides in red wines: could their structure and composition be influenced by the grape-growing

Oligosaccharides in red wines: could their structure and composition be influenced by the grape-growing

Abstract

Oligosaccharides have only recently been characterized in wine, and the information on composition and content is still limited. In wine, these molecules are mainly natural byproducts of the degradation of grape berry cell wall polysaccharides. Wine oligosaccharides present several physicochemical properties, being one relevant factor linked to the astringency perception of wines (1,2). A terroir can be defined as a grouping of homogeneous environmental units based on the typicality of the products obtained. This notion is particularly associated with wine, being the climate and the soil two of the major elements of terroir concept. Monastrell red wines, predominant varietal wines from the Southern of Spain, were elaborated with grapes from four different terroirs: Cañada Judío, Albatana, Bullas and Montealegre. Climate and soil data from different terroirs were gathered to properly distinguish them. Oligosaccharide fractions from wines were isolated, after removal of phenolic compounds, by high resolution size-exclusion chromatography. The glycosyl–linkages composition was determined by GC–MS of the partially methylated alditol acetates. Results show differences in the glycosyl–linkages composition of oligosaccharides from wines, according to their terroir. The molar percentage of glucose, rhamnose, arabinose, xylose and mannose residues exhibit marked differences depending on the terroir. The ratio of the terminal to the branched residues for Cañada Judío, Albatana, Bullas and Montealegre oligosaccharides is, respectively, 0.75, 0.85, 0.99 and 0.89. Proportions of oligosaccharides families have been calculated from glycosyl-linkage data (3,4,5). Montealegre wine clearly presents the lowest relative molar percentage for the oligosaccharides from yeasts (the sum of OligoGlucans and OligoMannans) and also for OligoXyloGlucans, whereas Bullas wine exhibits by far the lowest release of OligoRhamnogalacturonans. OligoArabinans and OligoArabiGalactans type II also show differences according to the terroir. All these data were treated by PCA to permit a best understanding. The projections on the first axis show obvious separation of Montealegre, whereas a clear separation of Albatana is observed in the projections on the second axis. The first and second principal components represent, respectively, 69% and 19% of the variability for samples. In summary, our results suggest the impact of “terroir” on the structure and the composition of wine oligosaccharide fraction, which could affect their physicochemical and sensory properties.

1.Quijada-Morín et al. (2014). Food Chem. 154, 44–51. 2.Boulet et al. (2016). Food Chem. 190, 357–363 3.Ducasse et al. (2011). J Agric Food Chem. 59, 6558–6567. 4.Ballou (1982). In Strathern, Jones & Broach (Eds.), Metabolism and gene expression (335–360), NY. 5.Fry et al. (1983). Plant Physiol. 89, 1–3.

Publication date: May 17, 2024

Issue: Macrowine 2016

Type: Poster

Authors

Rafael Apolinar-Valiente*, Encarna Gómez-Plaza, José María Ros-García, Pascale Williams, Thierry Doco

*INRA Montpellier

Contact the author

Tags

IVES Conference Series | Macrowine | Macrowine 2016

Citation

Related articles…

The impact of different yeasts and harvest time on the wine quality of Beihong and Beimei (<I>V. vinifera x V. amurensis</I>)

Beihong and Beimei are two wine cultivars from ‘Muscat Hamberg’ (V. vinifera L.) and wild V. amurensis Rupr., which were released in China in 2008. Here,two enology practices were reported. Firstly, the impact of different yeasts including D254, GRE, K1, D21 and BDX on dry wine quality of Beihong and Beimei was investigated. For Beihong, among wines fermented by all yeasts, residual sugar content was the lowest, total anthocyanin and resveratrol contents were the highest in the wine by D254. However, the wine by D254 had lower titrable acid than those by the other yeasts except BDX.

Use of computational modelling for selecting adsorbents for improved fining of wine

The occurrence of faults and taints in wine, such as those caused by microbial spoilage or various taints, have resulted in significant financial losses to wine producers. The wine industry commits significant financial resources towards fining and taint removal processes each year. Fining involves the addition of one or more adsorptive substrates to juice or wine to bind certain components, thus reducing their concentration [1]. However, these processes are often not selective and can also remove desirable flavour and aroma compounds.

The impact of branched chain and aromatic amino acids on fermentation kinetics and aroma biosynthesis by wine yeast Saccharomyces cerevisiae

One of the major determinants of wine quality is the aroma. Wine aroma is the human perception of the matrix of grape and yeast derived volatiles and their interaction that contribute to flavour wine. Most common are higher alcohols, ester and aldehydes. In previous studies the formation of characteristic volatile compounds have been linked to the metabolism of branched-chain and aromatic amino acids
(BCAAs) in synthetic grape must. Here we report on an investigation to assess the impact of the initial amino acid concentration on the production of aroma compounds by the industrial yeast VIN13 grown in both synthetic and real grape musts.

Analysis of the oenological potentials of different oak forests in Hungary

Like France, Hungary has many oak forests used for making barrels since many years. But if the differences between the woods of the North, the East and the South-West forests of France are well known, this is probably not the case of Hungarian forests. However taking into account the essential differences of climates and soils, differences must be significant and the general name “Hungarian oak” must not have any real meaning. We have studied precisely (determination of concentrations of volatile and non-volatile wood compounds, anatomical criteria, measurement of antioxidant capacity) of oaks collected from northeastern Hungary and others collected from the Danube valley in the northwest of the country.

Impact of drought stress on concentration and composition of wine proteins in Riesling

Protein haze in white wines is a major technological and economic problem of the wine industry. Field tests were carried out in steep slope vineyards planted with Riesling grapes over 3 dry growing seasons to study the effect of drought stress on the concentration of proteins in the resulting wines. Plots suffering from drought stress were compared with surrounding drip irrigated plots. Riesling grapes were processed into wines by conventional procedures. Protein amounts of the isolated wine colloids of the stressed samples were always higher than those of the watered samples(mean watered 13.8 ± 0.44, mean stressed 17.4 ± 0.40 g 100 g-1). As a consequence, higher bentonite doses were needed to achieve protein haze stability of the drought stressed treatments.