Macrowine 2021
IVES 9 IVES Conference Series 9 WineMetrics: A new approach to unveil the “wine-like aroma” chemical feature

WineMetrics: A new approach to unveil the “wine-like aroma” chemical feature

Abstract

“The Human being has an excellent ability to detect and discriminate odors but typically has great difficulty in identifying specific odorants”(1). Furthermore, “from a cognitive point of view the mechanism used to judge wines is closer to pattern recognition than descriptive analysis.” Therefore, when one wants to reveal the volatile “wine-like feature” pattern recognition techniques are required. Sensomics is one of the most recent “omics”, i.e. a holistic perspective of a complex system, which deals with the description of substances originated from microorganism metabolism that are “active” to human senses (2). Depicting the relevant volatile fraction in wines has been an ongoing task in recent decades to which several research groups have allocated important resources. The most common strategy has been the “target approach” in order to identify the “key odorants” for a given wine varietal. That process produced an extensive list of substances that play, at least individually, a role on the perceived quality of the wine. However, the combined effect of volatiles responsible for triggering the mechanism of wine-like perception is less explored. A few works address that issue, using omission tests or tentative reconstruction of the wine aroma (3). While accepting that chemical reconstruction of the volatile ‘sensometabolome’ is an important branch of research in this area, our vision is that the reconstruction work should be transferred to “those who know better” i.e. the yeast. The absence of the impression substances feature description constitute an obstacle to define the role of the “aroma quality drivers” on a global market perspective, therefore we will attempt to reconstruct the chemical feature “driven” by the yeast. The objective of the present work was to perform comparative sensorial and metabolomics analysis with four yeast strains from different origins and/or technological applications (cachaça, wine and laboratory), during a fermentative process, in order to characterize their aroma profile and the ability to produce the “wine-like” aroma. Fermentations were analyzed daily by HS-SPME-GC-MS and submitted to sensory analysis. Multivariate tools such as principal component analysis (PCA) and partial least squares regression (PLS-R) were used in order to extract the compounds related with the “wine-like” aroma, by fusion of chemical with sensory data. This approach demonstrates that acetaldehyde; ethyl esters of fatty acids were related with “wine-like” aroma. With PLS-R we were able to develop a model capable to predict “wine-like” with a correlation of 0.8. With this methodology we were capable to create a pipeline that can be used in the future for strains selection which regards the ability to produce compounds related with the “wine-like” aroma.

Publication date: May 17, 2024

Issue: Macrowine 2016

Type: Poster

Authors

António César Silva Ferreira*, Ana Rita Monforte

*ESB-UCP and IWBT-DVO

Contact the author

Tags

IVES Conference Series | Macrowine | Macrowine 2016

Citation

Related articles…

Effects of a new vacuum evaporation method on chemical and sensory properties of must and wine

A new process for vacuum evaporation was developed where evaporation takes place near the inner surface of a vortex produced by a rotor submerged in the liquid. Contrary to the state of the art the Vortex rotor process does not need a vacuum vessel but the rotating liquid creates a geometrically stable low pressure void surrounded by a vortex stabilized by the equilibrium between centrifugal forces and the pressure difference. First tests with water and sugar solutions at concentrations similar to grape must were conducted to verify the theoretical predictions, test the performance under different conditions and study the effect of various process parameters (Rösti et al 2015).

Reduction of herbaceous aromas by wine lactic acid bacteria mediated degradation of volatile aldehydes

Consumers typically prefer wines with floral and fruity aromas over those presenting green-pepper, vegetal or herbaceous notes. Pyrazines have been identified as causatives for herbaceous notes in wines, especially Bordeaux reds. However, pyrazines are not universally responsible for herbaceousness, and several other wine volatile compounds are known to produce distinct vegetal/herbaceous aromas in wines. Specifically, volatile aldehydes elicit sensations of herbaceousness or grassiness and have been described in wines well above their perception thresholds.

Chemical markers in wine related to low levels of yeast available nitrogen in the grape

Nitrogen is an important nutrient of yeast and its low content in grape must is a major cause for sluggish fermentations. To prevent problems during fermentation, a supplementation of the must with ammonium salts or more complex nitrogen mixtures is practiced in the cellar. However this correction seems to improve only partially the quality of wine [1]. In fact, yeast is using nitrogen in many of its metabolic pathways and depending of the sort of the nitrogen source (ammonium or amino acids) it produces different flavor active compounds. A limitation in amino acids can lead to a change in the metabolic pathways of yeast and consequently alter wine quality.

Study of the volatil profile of minority white varieties

The genetic material preservation is a priority issue in winemaking research. The recovery of minority grape varieties can control the genetic erosion, contributing also to preserve wine typical characteristics. In D.O.Ca. Rioja (Spain) the number of grown white varieties has been very limited, representing Viura the 91% of the cultivated white grape area in 2005, while the others, Garnacha Blanca and Malvasía riojana, hardly were grown. For this reason, a recovery and characterization study of plant material was carried out in this region. In 2008, the results obtained allowed the authorization of three minority white varieties: Tempranillo Blanco, Maturana Blanca and Turruntés.

Crown procyanidin: a new procyanidin sub-family with unusual cyclic skeleton in wine

Condensed tannins (also called proanthocyanidins) are a widely distributed throughout in plants kingdom and are one of the most important classes of secondary metabolites, in addition, they are part of the human diet. In wine, they are extracted during the winemaking process from grape skins and seeds. These compounds play an important role in red wine organoleptic characteristics such as color, bitterness and astringency. Condensed tannins in red wine are oligomers and polymers of flavan-3-ols unit such as catechin, epicatechin, epigallocatechin and epicatechin-3-O-gallate. The monomeric units can be linked among them with direct interflavanoid linkage or mediated by aldehydes.