Macrowine 2021
IVES 9 IVES Conference Series 9 Characterization of Glycosidically Bound Aroma Compounds of País cv. grapes of different Chilean zones

Characterization of Glycosidically Bound Aroma Compounds of País cv. grapes of different Chilean zones

Abstract

País grape has been estimated to arrive to Chile almost 500 years ago, being the first strain grown in this country. Traditionally, this grape has been used to mix with other varieties, to produce poor quality wines, but today is beginning to be used in the production of high quality wines. However, very little is known about the chemical characteristics of this variety. The aroma is one of the most important quality attributes of wine. Volatile compounds of this beverage may come from the grape (varietal aromas), from the fermentation process, from the ageing. The aromatic compounds are found in the grape in two forms: as free volatile compounds and as non-volatile compounds. The last ones, are aroma precursors present mainly as glycoconjugates formed by a sugar and an aglycone. They are potential natural sources of aroma because the hydrolysis of the bonds between the sugar and the aglycone, for example during the ripening of the fruit or the fermentation by the yeast, turns this molecule into an aromatic compound. These non-volatile compounds have been extensively studied in grapes due to their importance in the wine aroma. The aims of this work were to study glycosidic aroma precursors of País grapes from three Chilean zones from the Maule Region and determine where these compounds are mainly located in the grape (pulp or skin). For this purpose, grapes from three zones, Hualañé, Cauquenes and Itata were harvested post veraison and analyzed. The glycosides were extracted by passing the samples through the solid-phase extraction medium, and the aglycone was released by acid hydrolysis as described by Loscos et al. (2009). The extract was analyzed by gas chromatography mass spectrometry. The results showed that the principal groups of aroma precursors in País grapes were alcohols, aldehydes and terpenes. Among them, the most abundant was 2-ethyl-1-hexanol followed by benzaldehyde. In reference with the location of the aromatic precursors, the biggest amounts were found in the skins of all the samples. Among all the chemical groups, terpenes accounted the biggest amount differences between the skin and the pulp.

Loscos, N.; Hernández-Orte, P.; Cacho, J.; Ferreira, V. Comparison of the suitability of different hydrolytic strategies to predict aroma potential of different grape varieties. J. Agric. Food Chem. 2009, 57, 2468-80.

Acknowledgements: This study was supported by FONDECYT N°11140275.

Publication date: May 17, 2024

Issue: Macrowine 2016

Type: Poster

Authors

Cristina Ubeda*, Álvaro Peña-Neira, Raquel Callejón

*Universidad Autónoma de Chile

Contact the author

Tags

IVES Conference Series | Macrowine | Macrowine 2016

Citation

Related articles…

Efficiency of alternative chemical and physical treatments in reducing Brettanomyces Bruxellensis from oak wood

Oak barrels form an integral part of wine production, especially that of high quality wines. However, due to its porosity, wood presents an ecological niche for microbial proliferation and is highly susceptible to microbial spoilage which could cause considerable economic losses. Brettanomyces bruxellensis, the most commonly encountered microorganism responsible for spoilage during barrel ageing, can remain in barrels after barrel sanitation to contaminate new batches of wine after refilling. Therefore, effective sanitation treatments are of utmost importance to prevent recurring wine spoilage.

Attractiveness and sweetness of red wines: Synergies between American oak barrels and mannoproteins

In partnership with a Bordeaux property wanting to improve the quality of its second wine, the effects of two factors, American oak barrels and mannoproteins were studied. Their impact on the attractiveness and sweetness of wines were characterized during two successive vintages (2012 and 2013). Vinification took place with a homogeneous batch of Cabernet Sauvignon. The wine was then divided up into various groups of five barrels of French and American oak, new or reused. Analyses of volatile and non-volatile wood compounds were undertaken at four months and eight months of wood ageing, by LC-MS and GC-MS.

Screening sensory-directed methodology for the selection of non-saccharomyces wine yeasts based on perceived aroma quality

The present work contributes by developing a rapid sensory-directed methodology for the screening and selection of high quality wines with different sensory profiles Therefore, Verdejo and Tempranillo musts were fermented with 50 different yeasts each under controlled laboratory conditions. Resulting samples were firstly categorized according to five levels of quality by a panel of wine professionals (Sáenz-Navajas, Ballester et al. 2013). Higher quality samples were described by flash profiling by a semi-trained panel
(Valentin, Chollet et al. 2012) and most distinctive samples were screened by gas chromatography-olfactometry (GC-O) (López, Aznar et al. 2002).

Estimation of chemical age of red wines with the use of Fourier transform infrared spectroscopy (FT-IR) and chemometrics

The color of a red wine is one of the most important parameters of its quality, giving much information on its status, such as the grape variety used or the winemaking style. As the result of a complex equilibrium between different forms of anthocyanins and polymerization reactions which occur over the course of time, color can also serve as an indication of a wines’ age. For this purpose the “chemical age” i and ii indexes have been introduced by Somers in 1977. The chemical age index i measures the color absorbance after the addition of acetaldehyde while chemical index ii provides an indication of how much of the total red pigments are resistant to SO2 bleaching.

How do different oak treatment affect the sensory composition of Chenin blanc wines over time?

Wooden barrels have been the preferred method for oak maturation for wines, but the use of alternative oak products, such as staves and oak chips have increased in South Africa due to lower production costs. This study investigated the effect of different oak products used during fermentation and ageing on the sensory profile, degree of liking and perceived quality of a South African Chenin blanc wine. The different wine treatments included an unoaked tank control wine, wines matured in 5th fill barrels, wines matured in new barrels from three different cooperages, and wines matured in 5th fill barrels with stave inserts from two different cooperages.