Macrowine 2021
IVES 9 IVES Conference Series 9 Impact of varying ethanol and carbonation levels on the odor threshold of 1,1,6-trimethyl-1,2-dihydronaphtalene (petrol off-flavor) and role of berry size and Riesling clones

Impact of varying ethanol and carbonation levels on the odor threshold of 1,1,6-trimethyl-1,2-dihydronaphtalene (petrol off-flavor) and role of berry size and Riesling clones

Abstract

1,1,6-trimethyl-1,2-dihydronaphtelene (TDN) evokes the odor of “petrol” in wine, especially in the variety Riesling. Increasing UV-radiation due to climate change intensifies formation of carotenoids in the berry skins and an increase of TDN-precursors1. Exploring new viticultural and oenological strategies to limit TDN formation in the future requires precise knowledge of TDN thresholds in different matrices. Thresholds reported in the literature vary substantially between 2 µg/L up to 20 µg/L2,3,4 due to the use of different methods. As Riesling grapes are used for very different wine styles such as dry, sweet or sparkling wines, it is essential to study the impact of varying ethanol and carbonation levels. Therefore we determined the odor detection threshold (DT) with a three alternatives forced choice (3-AFC) test and calculated the best estimate threshold (BET) for each panelist, followed by the calculation of the BET for the whole panel. Matrices varied from water, a model wine, a dry Riesling wine and sparkling wine; the latter two exceptionally low in TDN. Carbonation in water, model wine and Riesling wine ranged from no addition to 2.5 and 6 bar pressure. Ethanol altered from 8 to 14% alc. in 2% alc. increments. Carbonation yielded an inconsistent effect due to a better volatilization leading to lower thresholds and masking of the TDN perception leading to slightly higher thresholds. Increasing ethanol levels however showed a clear tendency to raise the TDN thresholds, presumably due to better solubility and masking by its own pungent odor. Absolute thresholds varied in water between 2.6 and 4.0 µg/L and in wine between 8.5 and 15.2 µg/L. Since TDN is formed by a breakdown of carotenes, its occurrence correlates positively with the degree of sun exposure. This is partially governed by berry size and cluster density given by clonal differences. Thus we studied free and bound TDN in grapes and wines from 8 different Riesling clones. Furthermore, berries were divided in a two fractions according to a diameter smaller and larger than 13 mm. The berry fractions were separately crushed, pressed and fermented. Preliminary results indicate that the clonal influence on the formation of free TDN in the wines was substantially larger than the impact of berry size.

Literature: 1: Winterhalter, P; Goek, R. 2013; Carotenoid Cleavage Products. ACS Symp. Series 1134, 125-137. 2: Sacks, G. L.; Gates, M. J.; Ferry, F. X.; Lavin, E. H.; Kurtz, A. J.; Acree, T. E. 2012; Journal of Agricultural and Food Chemistry 60(12), 2998-3004 3: Ross, C. F.; Zwink, A. C.; Castro, L.; Harrison, R. 2014; Australian Journal of Grape and Wine Research 20(3), 335-339 4: Simpson, R. F. 1978; Chemistry and Industry 1, 37.

Publication date: May 17, 2024

Issue: Macrowine 2016

Type: Article

Authors

Michael Ziegler*, Hans-Georg Schmarr, Johanna Molenda, Recep Gök, Sandra Klink, Ulrich Fischer

*DLR Rheinpfalz

Contact the author

Tags

IVES Conference Series | Macrowine | Macrowine 2016

Citation

Related articles…

Enological evaluation of the attitude of the grapevine fumin to give varietal wines

Initiatives have been ongoing in recent years to safeguard biodiversity in the oenological sector via a process of enhancement of ancient varieties, under a pressure of a market strongly oriented towards production deriving from native vines of specific geographical zones. In that sense, Aosta Valley
(Italy) has raised the need to preserve and characterize its minority vine varieties which have the potentiality to give varietal wines. Fumin represents the 7% of the production of the region with 16 hectares of vineyards and 753 hectolitres of derived wine. Due to its large phenolic potential, strong astringency and deep colour, it has long been, and is still today, assembled or blended with other varieties as occurs, for example, for the Torrette.

Characterization of commercial enological tannins and its effect on human saliva diffusion

Commercial oenological tannins (TECs) are widely used in the wine industry. TECs are rich in condensed tannins, hydrolyzable tannins or a mixture of both. Wine grapes are a important source of proanthocyanidins or condensed tannins while oak wood possess a high concentration of hydrolyzable tannins (Obreque-Slier et al., 2009). TECs contribute with the antioxidant capacity of wine, catalyze oxide-reduction reactions and participate in the removal of sulfur compounds and metals.

How do different oak treatment affect the sensory composition of Chenin blanc wines over time?

Wooden barrels have been the preferred method for oak maturation for wines, but the use of alternative oak products, such as staves and oak chips have increased in South Africa due to lower production costs. This study investigated the effect of different oak products used during fermentation and ageing on the sensory profile, degree of liking and perceived quality of a South African Chenin blanc wine. The different wine treatments included an unoaked tank control wine, wines matured in 5th fill barrels, wines matured in new barrels from three different cooperages, and wines matured in 5th fill barrels with stave inserts from two different cooperages.

Extraction of pathogenesis-related proteins and phenolics in Sauvignon Blanc as affected by different

The composition of wine is largely determined by the composition of pre-fermentation juice, which is influenced by extraction of grape components. Different grape harvesting and processing conditions could affect the extraction of grape components into juice. Among these grape components, pathogenesis-related (PR) proteins are of great concern for white wine maker as they are the main cause of haze formation in finished white wine. If not removed before bottling, these PR proteins may progress into haze through the formation of complex with phenolics under certain conditions. Thaumatin-like proteins (TLPs) and chitinases are the main constituents of PR proteins found in protein haze.

Anthocyanin accumulation and extractability during the maturation of the grapes of three varieties

Anthocyanin accumulation and extractability were studied in Tannat, Cabernet Sauvignon and Merlot grapes produced in the south of Uruguay in two consecutive seasons. Typical cultivation situations employed in the region for each variety were considered. A follow-up was carried out, considering 60 plants per vineyard, and the harvest was determined according to the technological indices of maturity. Samples of grapes were taken in duplicate in each vineyard periodically along grape maturation. The basic composition, polyphenolic potential and anthocyanin extractability were determined. Also, half of grapes were frozen and later peeled; skin extractions over 24 hs with a solution of 12% ethanol and pH 3.2 were carried out. The anthocyanin contents of the extracts obtained were determined by HPLC-DAD. The levels of anthocyanins reached the highest values before technological maturity. Anthocyanin extractability had a decrease during grape maturation.