Macrowine 2021
IVES 9 IVES Conference Series 9 Impact of varying ethanol and carbonation levels on the odor threshold of 1,1,6-trimethyl-1,2-dihydronaphtalene (petrol off-flavor) and role of berry size and Riesling clones

Impact of varying ethanol and carbonation levels on the odor threshold of 1,1,6-trimethyl-1,2-dihydronaphtalene (petrol off-flavor) and role of berry size and Riesling clones

Abstract

1,1,6-trimethyl-1,2-dihydronaphtelene (TDN) evokes the odor of “petrol” in wine, especially in the variety Riesling. Increasing UV-radiation due to climate change intensifies formation of carotenoids in the berry skins and an increase of TDN-precursors1. Exploring new viticultural and oenological strategies to limit TDN formation in the future requires precise knowledge of TDN thresholds in different matrices. Thresholds reported in the literature vary substantially between 2 µg/L up to 20 µg/L2,3,4 due to the use of different methods. As Riesling grapes are used for very different wine styles such as dry, sweet or sparkling wines, it is essential to study the impact of varying ethanol and carbonation levels. Therefore we determined the odor detection threshold (DT) with a three alternatives forced choice (3-AFC) test and calculated the best estimate threshold (BET) for each panelist, followed by the calculation of the BET for the whole panel. Matrices varied from water, a model wine, a dry Riesling wine and sparkling wine; the latter two exceptionally low in TDN. Carbonation in water, model wine and Riesling wine ranged from no addition to 2.5 and 6 bar pressure. Ethanol altered from 8 to 14% alc. in 2% alc. increments. Carbonation yielded an inconsistent effect due to a better volatilization leading to lower thresholds and masking of the TDN perception leading to slightly higher thresholds. Increasing ethanol levels however showed a clear tendency to raise the TDN thresholds, presumably due to better solubility and masking by its own pungent odor. Absolute thresholds varied in water between 2.6 and 4.0 µg/L and in wine between 8.5 and 15.2 µg/L. Since TDN is formed by a breakdown of carotenes, its occurrence correlates positively with the degree of sun exposure. This is partially governed by berry size and cluster density given by clonal differences. Thus we studied free and bound TDN in grapes and wines from 8 different Riesling clones. Furthermore, berries were divided in a two fractions according to a diameter smaller and larger than 13 mm. The berry fractions were separately crushed, pressed and fermented. Preliminary results indicate that the clonal influence on the formation of free TDN in the wines was substantially larger than the impact of berry size.

Literature: 1: Winterhalter, P; Goek, R. 2013; Carotenoid Cleavage Products. ACS Symp. Series 1134, 125-137. 2: Sacks, G. L.; Gates, M. J.; Ferry, F. X.; Lavin, E. H.; Kurtz, A. J.; Acree, T. E. 2012; Journal of Agricultural and Food Chemistry 60(12), 2998-3004 3: Ross, C. F.; Zwink, A. C.; Castro, L.; Harrison, R. 2014; Australian Journal of Grape and Wine Research 20(3), 335-339 4: Simpson, R. F. 1978; Chemistry and Industry 1, 37.

Publication date: May 17, 2024

Issue: Macrowine 2016

Type: Article

Authors

Michael Ziegler*, Hans-Georg Schmarr, Johanna Molenda, Recep Gök, Sandra Klink, Ulrich Fischer

*DLR Rheinpfalz

Contact the author

Tags

IVES Conference Series | Macrowine | Macrowine 2016

Citation

Related articles…

Characterization of Glycosidically Bound Aroma Compounds of País cv. grapes of different Chilean zones

País grape has been estimated to arrive to Chile almost 500 years ago, being the first strain grown in this country. Traditionally, this grape has been used to mix with other varieties, to produce poor quality wines, but today is beginning to be used in the production of high quality wines. However, very little is known about the chemical characteristics of this variety. The aroma is one of the most important quality attributes of wine. Volatile compounds of this beverage may come from the grape (varietal aromas), from the fermentation process, from the ageing. The aromatic compounds are found in the grape in two forms: as free volatile compounds and as non-volatile compounds. The last ones, are aroma precursors present mainly as glycoconjugates formed by a sugar and an aglycone…

Technological possibilities of grape marc cell walls as wine fining agent. Effect on wine phenolic composition

Fining is a technique that is used to remove unwanted wine components that affect clarification, astringency, color, bitterness, and aroma. Fining involves the addition of adsorptive or reactive material in order to reduce or eliminate the presence of certain less desirable wine components and to ensure that a wine remains in a particular stable state for a given period of time Recently concerns have been raised about the addition of animal proteins, such as gelatin, to wine due to the disease known as bovine spongiform encephalopathy (Mad Cow disease). Although the origin of gelatins has been moved to porcine, winemakers are asking for substitute products with properties and application protocols similar to the traditional animal-derived ones, making the use of plant-derived proteins in fining a practically viable possibility. As a consequence, various fining agents derived from plants have been proposed, including proteins from cereals, legumes, and potato.

Dissecting the polysaccharide‐rich grape cell wall matrix during the red winemaking process, using high‐throughput and fractionation methods

Limited information is available on grape wall-derived polymeric structure/composition and how this changes during fermentation. Commercial winemaking operations use enzymes that target the polysaccharide-rich polymers of the cell walls of grape tissues to clarify musts and extract pigments during the fermentations. In this study we have assessed changes in polysaccharide composition/ turnover throughout the winemaking process by applying recently developed cell wall profiling approaches to both wine and pomace polysaccharides. The methods included gas chromatography for monosaccharide composition (GC-MS), infra-red (IR) spectroscopy and comprehensive microarray polymer profiling
(CoMPP) using cell wall probes.

Directed Evolution of Oenococcus oeni: optimising yeast-bacteria interactions for improved malolactic fermentation

Malolactic fermentation (MLF) is a secondary step in the vinification process and it follows alcoholic fermentation (AF) which is predominantly carried out by Saccharomyces cerevisiae. These two processes result in the degradation of metabolites to produce secondary metabolites which also contribute to the final wine flavour and quality. AF results in the production of ethanol and carbon dioxide from sugars and MLF stems from the degradation of L-malic acid (a dicarboxylic acid) to L-lactic acid (a monocarboxylic acid). The latter process results in a smoother texture as the acidity of the wine is reduced by the process, it also adds to the flavour complexity of the wine.

Analysis of voltammetric fingerprints of different white grape musts reveals genotype-related oxidation patterns

Must oxidation is a complex process involving multiple enzymatic transformations, including the oxidation of phenolics containing an ortho-diphenol function. The latter process has a primary influence on wine aroma characteristics and stability, due to the central role of ortho-diphenols in the non-enzymatic oxidative reactions taking place during winemaking and in finished wine. Although oxidation of must is traditionally avoided, in recent years its contribution to wine quality has been revisited, and in some cases improvements to wine aroma have been observed with the application of controlled must oxidation. Nowadays there is a great interest in the wine industry towards the identification of specific markers or patterns to characterize and classify the response of grape must to oxidation.