Macrowine 2021
IVES 9 IVES Conference Series 9 Evaluation of Polarized Projective Mapping as a possible tool for attributing South African Chenin blanc dry wine styles

Evaluation of Polarized Projective Mapping as a possible tool for attributing South African Chenin blanc dry wine styles

Abstract

Multiple Factor Analysis (MFA) According to the Chenin blanc Association of South Africa, there are three recognized dry wine styles, Fresh and Fruity (FF), Rich and Ripe Unwooded (RRU), and Rich and Ripe Wooded (RRW), classically attributed with the help of sensory evaluation. One of the “rapid methods” has drawn our attention for the purpose of simplifying and making style attribution for large sample sets, evaluated during different sessions, more robust. Polarized Projective Mapping (PPM) is a hybrid of Projective Mapping (PM) and Polarised Sensory Positioning (PSP). It is a reference-based method in which poles (references) are used for the evaluation of similarities and dissimilarities between samples. Panelists are presented with “free-moving” products to arrange around the poles, according to similarities and dissimilarities, to create a 2D product map. Additionally, the judges give a description of the samples, generating a short list of attributes. Our approach to testing this method was to first establish the poles using PM, then test the model using PPM with samples that were either known (used in the PM session and that contributed to the choice of poles) or unknown. The sample set consisted of 18 commercial Chenin blanc wines, vintages 2013 and 2014, from the three representative styles, chosen according to the tasting notes description. Four PPM experiments were performed. The poles were kept constant among the PPM experiments, while different combinations of “free-moving” wines were evaluated to test the consistency of product groupings. In all tasks sensory descriptors were generated. For each session 15 judges were recruited. Each judge repeated the exercise after a 15 minute break. For PM the sample set consisted of 12 samples (9 wines, 3 of them duplicates). For PPM, the sample sets also had 12 samples, with one of the poles and one other sample duplicated. The PPM sessions were organized as follows: PPM1 same samples as PM, PPM2 and PPM3 half known and half unknown samples, and PPM4 only unknown samples. The data generated was evaluated statistically by means of multiple factor analysis (MFA). Multiple factor analysis (MFA) on the individual tasks showed in the PM and all four PPM tasks, the RRW group separated most clearly from other wines and blind duplicates of this style grouped well together. The FF and RRU styles grouped less consistently from one task to another and blind duplicates were not grouped as closely to one another. MFA results comparing all four PPM experiments showed good repeatability in grouping of wines among the separate sessions, especially for wooded wines. New rapid methods provide significant cost benefits for the wine industry and researchers. PPM may be a useful tool for researchers to apply in the analysis of large sample sets of wines.

Publication date: May 17, 2024

Issue: Macrowine 2016

Type: Poster

Authors

Astrid Buica*, Christine Wilson, Jeanne Brand

*Stellenbosch University

Contact the author

Tags

IVES Conference Series | Macrowine | Macrowine 2016

Citation

Related articles…

Impact of industrial-scale serial filtration on macromolecules in red wines

Filtration is a critical step in ensuring the clarity and microbial stability of wine prior to bottling. However the process of filtering potentially reduces red wine quality by removing some of the macromolecules that contribute to the texture of the wine. Commercial red wines, Cabernet Sauvignon (CAS) and Shiraz (SHZ), of two vintages and two grades (premium grade wines from the older vintage: CAS13 and SHZ13; and standard grade wines from a younger vintage: CAS14 and SHZ14) were filtered through industrial-scale commercial filtration units prior to bottling. Samples were taken before and after cross-flow filtration, lenticular filters, 0.65 µm and 0.45 µm pore size nylon membrane filters. The concentration and composition of macromolecules, including tannins and polysaccharides, were measured in all samples as well as particle size distribution and wine colour.

Removal of Fumonisin B1 and B2 from red wine using polymeric substances

The Ability of PVPP (Polyvinylpolypyrrolidone), PVP-DEGMA-TAIC (copolimerization of N-vinyl-2-pyrrolidinone with ethylene glycol dimethacrylate and triallyl isocyanurate) and PAEGDMA
(poly(acrylamide-co-ethylene glycol dimethacrylate)) polymers was tested as removal agents for Fumonisin B1 (FB1) and Fumonisin B2 (FB2) from model solutions and red wine. The polymers removal capacity was checked at three different resident times (2, 8 and 24 hours of contact time between the polymer and the sample), showing no differences in the percentage of FB1 and FB2 removal. Then, different polymer concentrations (1, 5 and 10 mg mL-1) were tested in model solution with and without phenolics (i.e. gallic acid and 4-methylcatechol).

A multivariate approach using attenuated total reflectance mid-infrared spectroscopy to measure the surface mannoproteins and β-glucans of yeast cell walls during wine fermentations

Yeast cells possess a cell wall comprising primarily glycoproteins, mannans, and glucan polymers. Several yeast phenotypes relevant for fermentation, wine processing, and wine quality are correlated with cell wall properties. To investigate the effect of wine fermentation on cell wall composition, a study was performed using mid-infrared (MIR) spectroscopy coupled with multivariate methods (i.e., PCA and OPLS-DA). A total of 40 yeast strains were evaluated, including Saccharomyces strains (laboratory and industrial) and non-Saccharomyces species. Cells were fermented in both synthetic MS300 and Chardonnay grape must to stationery phase, processed, and scanned in the MIR spectrum.

Analysis of peptide fraction from white wines

Among nitrogen compounds included in white wines, the peptide fraction is certainly the least studied, however this fraction is quantitatively the most important (Feuillat, 1974). Existing studies concern the fraction below 1 kDa and only for white and sparkling wines (Bartolomé et al, 1997, Desportes et al 2000). In this report, we have developed methods to isolate peptides from reference white wines. Then, we have applied this methodology with bitter wine to answer a research question: is there a relation between peptides and the bitterness of white wine as for some cheese for example (Furtado, 1984)?

Impact of sulfur compounds to the antioxidant stability of white wines

The chemical mechanisms involved in oxidation/reduction potential of wine during winemaking and aging are affecting its color, aroma and taste. Chemical oxidation is one of the major causes of development of off-flavors during ageing1. Thus, the chemical changes in wine during storage should be controlled to ensure the sensory quality of the product and avoid consumer rejection that will compromise the economic value of the product. The 1-hydroxyethyl radical has been recognized as the key radical intermediate in the oxidative reactions in wine2. Based on the kinetic study of POBN-1-hydroxyethyl spin adduct formation in wines initiated via the Fenton reaction, a novel tool was recently developed in our laboratory to quantify the resistance of wines against oxidation3.