Macrowine 2021
IVES 9 IVES Conference Series 9 Effect of concentration and competition between different fungicide residues on the adsorption efficiency of activated vegetal fibres for treatment of wine

Effect of concentration and competition between different fungicide residues on the adsorption efficiency of activated vegetal fibres for treatment of wine

Abstract

Vineyards are strongly exposed to fungal diseases, attacks from insects and competition with weeds. Most treatments used on grape vines contain synthetic active substances, which may be transferred to the wine. Such pesticides have a negative image because many active substances are potential health hazards. A specific oenological treatment allowing the reduction of pesticide residues in wine based on activated vegetable fibres (AVF) is under examination by the International Organisation for Vine and Wine. This technique works efficiently and alters the wine only little (Lempereur et al. 2014). The purpose of this study was to investigate the difference in adsorption efficiency of the active substances most used by Swiss winegrowers. Furthermore, effects of concentration and competition between the different active substances in the adsorption efficiency of AVF were investigated. The concentration and competition trials were carried out using white wine without pesticides allowing to artificially spike six active substances. The investigation of the concentration effect led to the Freundlich isotherms allowing the calculation of the adsorption capacities of Fenpropidin k = 1816μg/g fiber and Fluopyram k = 556μg/g of fibre. This showed that the rate of reduction of these active substances is not related to the initial concentration, but remains stable over the tested range. The results of the competition trial indicate no interaction between different active substances present in a solution for the absorption by AVF. Indeed, it was not possible to show significant differences between the reduction rate of pesticides in a wine containing a cocktail of six active substances and wines containing only one of the active substances. Our results also confirm that the reduction rate depends on the active substance. Among the tested substances, there are three different efficiency classes: Mandipropamid, Cyprodinil and Fenpropidin with reduction rates between 80-100%, Fludioxonil and Fluopyram with rates between 50-80% and Iprovalicarb with a rate under 50%. This classification confirms the results of previous pre-industrial trials (Lempereur et al. 2014), except for Fenpropidin and Fluopyram that were never tested before. These experiments show the potential of AVF for active substances untested so far such as Fluopyram and Fenpropidin. Trials are currently under way to compare the efficiency of AVF between laboratory and pre-industrial conditions and to investigate the sensory impact on the wine, particularly the perception threshold of the AVF and their impact on the colloidal balance of the wine.

Publication date: May 17, 2024

Issue: Macrowine 2016

Type: Poster

Authors

Michel Reynolds*, Carole Koestel, Céline Louaisil, Johannes Rösti, Magali Grinbaum, Valérie Lempereur

*Agroscope

Contact the author

Tags

IVES Conference Series | Macrowine | Macrowine 2016

Citation

Related articles…

Interactions of wine polyphenols with dead or living Saccharomyces cerevisiae Yeast Cells and Cell Walls: polyphenol location by microscopy

Tannin, anthocyanins and their reaction products play a major role in the quality of red wines. They contribute to their sensory characteristics, particularly colour and astringency. Grape tannins and anthocyanins are extracted during red wine fermentation. However, their concentration and composition change over time, due to their strong chemical reactivity1. It is also well known that yeasts influence the wine phenolic content, either through the release of metabolites involved in the formation of derived pigments1, or through polyphenol adsorption2,3.

An excessive leaf-fruit ratio reduces the yeast assimilable nitrogen in the must

Yeast assimilable nitrogen (YAN) in the grape must is a key variable for wine quality as a source of aroma precursors. In a situation of YAN deficiency, a foliar urea application upon the vine at veraison enhances YAN concentration and facilitates must fermentation. In 2013, Agroscope investigated the impact of leaf-fruit ratio on the nitrogen (N) assimilation and partitioning in grapevine Vitis vinifera cv. Chasselas following foliar-urea application with the aim of improving its efficiency on the YAN concentration.

New acylated flavonols identified in the grape skin of Vitis vinifera cv. Tannat and their wines

Flavonols are a class of flavonoid compounds derived from plant secondary metabolism. There they play different roles like antioxidants, internal regulators and UV screenings. In red wines, flavonols have increasingly received consideration by part of scientific and winemakers according their properties began to arise known. Among these stand out wine colour stabilization and their value as bioactive compounds. In this work the complete series of the acetylated and p-coumaroylated derivatives of the 3-O-glycosides of methoxylated flavonols, namely isorhamnetin, laricitrin and syringetin, have been identified in grapes and their respective wines from Vitis vinifera cv. Tannat.

Estimation of chemical age of red wines with the use of Fourier transform infrared spectroscopy (FT-IR) and chemometrics

The color of a red wine is one of the most important parameters of its quality, giving much information on its status, such as the grape variety used or the winemaking style. As the result of a complex equilibrium between different forms of anthocyanins and polymerization reactions which occur over the course of time, color can also serve as an indication of a wines’ age. For this purpose the “chemical age” i and ii indexes have been introduced by Somers in 1977. The chemical age index i measures the color absorbance after the addition of acetaldehyde while chemical index ii provides an indication of how much of the total red pigments are resistant to SO2 bleaching.

Development of a new sustainable filtering media for wine and beer clarification and sterilisation

Different separation techniques are frequently used during vinification process. Nowadays, clarification and microbiological stabilization of wine or beer can be done using precoat filters or crossflow filters to remove yeast and bacteria. Kieselguhr powders are the most used filter aids for precoat filtration. Their crystalline structure and their pulverulent nature induce ecotoxicological risks when used. Moreover, regeneration and reuse of these filter aids is not efficient and the filtration waste requires cost effective retreatment.