Macrowine 2021
IVES 9 IVES Conference Series 9 Identification of green, aggressive and hard character of wines by a chemo-sensory directed methodology

Identification of green, aggressive and hard character of wines by a chemo-sensory directed methodology

Abstract

With climate change, it is progressively more often to obtain grapes with an acceptable content in sugars or acids but with immature tannins described as green, aggressive or hard (noted as GAH onwards). During winemaking, the oenologist has to make decisions related to the elaboration of such grapes based mainly on empirical experience, given the lack of objective criteria to this concern. An increase in the chemical and sensory knowledge of immature tannins would allow managing this GAH character of grapes with the maximum possible efficiency during winemaking processes. The present work aims at isolating and identifying the group of compounds responsible for the GAH character present in wines. Thirty-eight wines with a priori different levels of GAH were submitted to sensory analysis by a panel of 25 wine experts. Thirteen attributes and two multidimensional terms (preference and GAH) were rated. Results showed that GAH concept was negatively correlated to preference and positively to aroma (vegetal) and in-mouth terms (astringency). Four wines with different levels of GAH were fractionated by solid-phase extraction and semipreparative liquid chromatography. Six odorless fractions (F1-F6) were isolated for each wine and further submitted to sensory characterization. Results showed that all fractions, except for F3 shared sensory properties for the four wines. F1 and F2 were characterized by attributes such as burning, hot and bitter. F4 and F6 were mainly sweet, watery, silky, fleshy, oily and greasy and F5 dry, coarse and granular. Differently, fraction F3 obtained from wines with high GAH was significantly different from wines with low GAH. Wines with high score for GAH was mainly dry, burning, sour and bitter, while for wines low in GAH was dusty and watery. These results are promising and would suggest that the developed methodology have succeed in isolating the group of compounds potentially involved in the green, aggressive and hard character of wines.

Publication date: May 17, 2024

Issue: Macrowine 2016

Type: Poster

Authors

Purificación Fernández-Zurba*, Blanca Lacau, Cristina Barón, Dominique Valentin, Jesús Astrain, Jose Avizcuri, Maria Pilar Saenz-Navaja, Vicente Ferreira

*Universidad de La Rioja

Contact the author

Tags

IVES Conference Series | Macrowine | Macrowine 2016

Citation

Related articles…

Effect of mixed Torulaspora delbrueckii-Saccharomyces cerevisiae culture on rose quality wine

Alcoholic fermentation using no Saccharomyces wine is an effective means of modulating wine aroma. This study investigated the impact of coinoculating Torulaspora delbruecki with two Saccharomyces cerevisiae commercial yeast (QA23, Lallemand; Red Fruit, Sepsa-Enartis) on enological quality parameters, volatile composition and sensory analysis. The following assays were performed on Tempranillo variety: Saccharomyces QA23 (CTQA), Saccharomyces Red Fruit (CTRF), coinoculated T. delbrueckii + S.cerevisiae QA23 (CIQA) and coinoculated T. delbrueckii + S.cerevisiae (CIRF).

Characterization of commercial enological tannins and its effect on human saliva diffusion

Commercial oenological tannins (TECs) are widely used in the wine industry. TECs are rich in condensed tannins, hydrolyzable tannins or a mixture of both. Wine grapes are a important source of proanthocyanidins or condensed tannins while oak wood possess a high concentration of hydrolyzable tannins (Obreque-Slier et al., 2009). TECs contribute with the antioxidant capacity of wine, catalyze oxide-reduction reactions and participate in the removal of sulfur compounds and metals.

Development and validation of a standardized oxidation assay for the accurate measurement of the ability of different wines to form “de novo” oxidation-related aldehydes

From the standpoint of wine aroma oxidation there are two effects observed: aroma degradation of oxygen sensitive compounds (polyfunctional mercaptans) and the appearance of new substances with high aromatic power (acetaldehyde, methional, phenylacetaldehyde, sotolon, alkenals, isobutanal and 2, 3-metylbutanals) (1-5). According to our experience, Strecker aldehydes are compounds with highest sensory relevance in the oxidative degradation of many wines (5-7).

Comparison of various storage conditions to preserve polyphenols in red-grape pomace

Red grape pomace, a waste from wine production, can be valorised by extracting polyphenols, high-added value compounds used in cosmetics or oenology. For use at an industrial level, using green extraction techniques, pomace need to be stored before being processed. The aim of this study is to test various storage conditions in order to maintain high level of polyphenols over 180 days, while keeping storage cost economically interesting. In a first step, different storage conditions (ambient temperature or cooled (4°C) temperature, anaerobic (saturation with N2) or aerobic conditions, and addition of sulphur dioxide (SO2)) were compared on small samples (1 kg) packed in plastic pockets. The quality of storage was assessed by following the optical density of the pomace extract at 280 nm (DO 280 expressed as mg/l eq gallic acid), which is an indication of the amount of remaining extractable polyphenols.

Influence of toasting oak wood on ellagitannin structures

Ellagitannins (ETs) have been reported to be the main phenolic compounds found in oak wood. These compounds, belonging to the hydrolysable tannin class of polyphenols, are esters of hexahydroxydiphenic acid (HHDP) and a polyol, usually glucose or quinic acid. They own their name to their capacity to be hydrolysed and liberate ellagic acid and they have an impact on astringency and bitterness sensation, which is strongly dependant on their structure. The toasting phase is particularly crucial in barrels fabrication and influences wood composition.