Macrowine 2021
IVES 9 IVES Conference Series 9 Phenolic profiles of minor red grape cultivars autochthonous from the Spanish region of La Mancha

Phenolic profiles of minor red grape cultivars autochthonous from the Spanish region of La Mancha

Abstract

The phenolic profiles of little known red grape cultivars, namely Garnacho, Moribel and Tinto Fragoso, which are autochthonous from the Spanish region of La Mancha (ca. 600,000 ha of vineyards) have been studied over the consecutive seasons of years 2013 and 2014. The study was separately performed over the skins, the pulp and the seeds, and comprised the following phenolic types: anthocyanins, flavonols, hydroxycinnamic acid derivatives (HCADs), total proanthocyanidins (PAs) and their structural features. The selected grape cultivars belong to the Vine Germplasm Bank created in this region in order to preserve the great diversity of genotypes grown in La Mancha. This study aims to evaluate the enological potential of these minor grape cultivars. Regarding anthocyanins, the three studied cultivars showed the occurrence of the 3-glucosides of the common grape anthocyanidins, with the prevalence of malvidin-based anthocyanins, followed by peonidin derivatives. However, Garnacho showed a characteristic profile in which anthocyanins based on peonidin and malvidin accounted for similar proportions. Among the acylated anthocyanins, the coumaroyl derivatives dominated over the acetylated ones and some minor caffeoyl derivatives were also found. In addition, minor anthocyanidin 3,5-diglucosides were detected, mainly malvidin 3,5-diglucoside, although its coumaroyl derivative was also found in Tinto Fragoso and peonidin 3,5-diglucoside in the case of Garnacho. Tinto Fragoso showed the highest content of anthocyanins in both years. Flavonol profiles were in agreement with those previously described for V. vinifera grapes: the 3-glucosides, the 3-galactosides and the 3-glucuronides of the six common aglycones, namely kaempferol, quercetin, isorhamnetin, myricetin, laricitrin and syringetin. Moreover, high resolution MS and MS/MS evidence of the occurrence of dihexosides of myricetin was found in grapes. The qualitative content of HCADs showed no differences according to grape cultivar and was dominated by caftaric acid. The pulp accumulated most HCADs. The content of PAs in grape skins does not vary according to grape variety and season year, around 8-13 mg/g skin (as catechin). In contrast, the content of PAs in seeds was lower in Moribel (53-58 mg/g, vs. 75-79 mg/g in Garnacho and 81-86 mg/g in Tinto Fragoso), but no differences were found according to season year. The mean degree of polymerization was similar in the three cultivars and two season years: 9-10 for skin PAs and 6-7 for seed PAs. The percentage of prodelphinidins in skin PAs ranged within 17-18% for the three cultivars, whereas the percentage of galloylation in seed PAs was lower in Moribel (13%, vs. 16-17% in the other two cultivars). Finally, the season year of 2014 was characterized by adverse climatic conditions with regards to the development of grapes and the contents of anthocyanins and flavonols were affected showing lower concentrations for the three grape cultivars.

Publication date: May 17, 2024

Issue: Macrowine 2016

Type: Poster

Authors

Isidro Hermosín-Gutíerrez*, Esteban García-Romero, Jesús Martínez-Gascueña, José Luís Chacón-Vozmedian, José Pérez-Navarro, Pedro Izquierdo-Cañas, Sergio Gómez-Alonso

*Universidad de Castilla-La Mancha

Contact the author

Tags

IVES Conference Series | Macrowine | Macrowine 2016

Citation

Related articles…

Crown procyanidin: a new procyanidin sub-family with unusual cyclic skeleton in wine

Condensed tannins (also called proanthocyanidins) are a widely distributed throughout in plants kingdom and are one of the most important classes of secondary metabolites, in addition, they are part of the human diet. In wine, they are extracted during the winemaking process from grape skins and seeds. These compounds play an important role in red wine organoleptic characteristics such as color, bitterness and astringency. Condensed tannins in red wine are oligomers and polymers of flavan-3-ols unit such as catechin, epicatechin, epigallocatechin and epicatechin-3-O-gallate. The monomeric units can be linked among them with direct interflavanoid linkage or mediated by aldehydes.

Micro-meteorological, compositional and transcriptional study of corvina grape color during ripening

Grape anthocyanin content and composition could affect the quality and the production strategies of red wines. Differences in the pigment composition modify the color properties in terms of hue, extractability and stability. Thus, for the production of a highly qualitative wine such as “Amarone”, variations in the pigment composition are not negligible. The aim of this work was the investigation of the anthocyanin profile changes during ripening in Corvina grapes, the main cultivar for the “Amarone” production. The experiment took place in 2015, in two vineyards located in Valpollicella (Italy).

Trans-resveratrol concentrations in wines Cabernet Sauvignon from Chile

This study evaluated the levels of trans-resveratrol in commercial wines made from Cabernet Sauvignon grapes from different valleys of Chile stilbenes. The Cabernet Sauvignon is the most planted variety in Chile, being 38% of the total vineyard country. Chile is the fourth largest wine exporter in the world, so it is important to evaluate the Cabernet-Sauvignon wines in their concentration levels of trans-resveratrol and its relation to the benefits provided to human health in moderate consumption. Evaluation comprises commercial wines from different valleys of Chile and its relationship with climatic characteristics, soil and vineyard handling.

On the losses of dissolved CO2 from laser-etched champagne glasses under standard tasting conditions

Under standard champagne tasting conditions, the complex interplay between the level of dissolved CO2 found in champagne, its temperature, the glass shape, and the bubbling rate, definitely impacts champagne tasting by modifying the neuro-physico-chemical mechanisms responsible for aroma release and flavor perception. Based on theoretical principles combining heterogeneous bubble nucleation, ascending bubble dynamics and mass transfer equations, a global model is proposed (depending on various parameters of both the wine and the glass itself), which quantitatively provides the progressive losses of dissolved CO2 from laser-etched champagne glasses.

Impact of elemental sulfur (S0) residues in Sauvignon blanc juice on the formation of the varietal thiols 3-mercapto hexanol and 3-mercaptohexyl acetate

Elemental sulfur is a fungicide used by grape growers to control the development of powdery mildew, caused by the fungus Erysiphe necator. This compound is effective, cheap and has a low toxicity with no withholding period recommended. However, high levels of S0 residues in the harvested grapes can lead to the formation of reductive sulfur compounds that can impart taints and faults to the wine. Hydrogen sulphide (H2S) is a very volatile and unpleasant sulfur compound which formation is connected to high residues of S0 in juice (10 – 100 mg/L).