Macrowine 2021
IVES 9 IVES Conference Series 9 Anthocyanin accumulation and extractability during the maturation of the grapes of three varieties

Anthocyanin accumulation and extractability during the maturation of the grapes of three varieties

Abstract

Anthocyanin accumulation and extractability were studied in Tannat, Cabernet Sauvignon and Merlot grapes produced in the south of Uruguay in two consecutive seasons. Typical cultivation situations employed in the region for each variety were considered. A follow-up was carried out, considering 60 plants per vineyard, and the harvest was determined according to the technological indices of maturity. Samples of grapes were taken in duplicate in each vineyard periodically along grape maturation. The basic composition, polyphenolic potential and anthocyanin extractability were determined. Also, half of grapes were frozen and later peeled; skin extractions over 24 hs with a solution of 12% ethanol and pH 3.2 were carried out. The anthocyanin contents of the extracts obtained were determined by HPLC-DAD. The levels of anthocyanins reached the highest values before technological maturity. Anthocyanin extractability had a decrease during grape maturation. The highest levels of anthocyanins were found in Tannat skins altough those of Cabernet Sauvignon were higher than those of Merlot grapes. Anthocyanin profiles of skins changing significantly after veraison but these changes were very lower just before maturity, found the typical values of each variety The prevalent anthocyanin derivatives at the start of the maturation showed a decrease during the process. Malvidin proportions increased and cyanidin proportions decreased along the first stages of maturation, in agree with the biosynthesis of anthocyanins. Malvidin derivatives showed the fastest accumulation. At harvest, Tannat berries presented the highest sugar contents, total acidity, total polyphenol richness, total potential in anthocyanins and potential in extractable anthocyanins, and the lowest pH values. Tannat had the highest values of EA%, corresponding to the lowest extractability of anthocyanins. Significant differences among the anthocyanin profiles and contents of the grapes of each variety were found. The tri-hydroxylated molecules were prevalent respect to the di-hydroxylated anthocyanins in the three varieties. Tannat skins had the highest proportion of non-acylated glucosides, petunidin and delphinidin derivatives. Cabernet Sauvignon skins had the highest proportions of acetylated glucosides and malvidin derivatives. Merlot skins presented the highest proportions of coumaroyl glucosides and peonidin derivatives. It can be concluded that the grape variety and the environmental conditions determined important differences in the anthocyanin composition of grapes and the extractability of these compounds from the skins. The anthocyanin contents and profiles of the grapes of each variety presented high differences that might determine important variations in the colour and composition of the respective wines.

Publication date: May 17, 2024

Issue: Macrowine 2016

Type: Poster

Authors

Gustavo González Neves*, Diego Piccardo, Graciela Gil, Guzmán Favre, Laura Barreiro, Milka Ferrer

*Universidad de la república

Contact the author

Tags

IVES Conference Series | Macrowine | Macrowine 2016

Citation

Related articles…

Testing the effectiveness of Cell-Wall material from grape pomace as fining agent for red wines

Lately several works highlighted the capacity of grape cell-wall material (CWM) to interact with proanthocyanidins (PA), indicating its potential use as fining agent for red wines.1–4 However, those studies were performed by using purified PAs and very high doses of CWM (almost ten-fold higher than those used in wine industry for other commercial fining agents). The present study focuses on the applicability of CWM from Cabernet sauvignon pomace as fining agent for red wines under real winery conditions. Grapes of cultivar Cabernet sauvignon were harvested at three different maturity levels
(unripe, mature, and overripe) and used for red winemaking. The pomace of such vinifications were used as source of CWM, and applied into red wines at two different concentrations: 0.2 g/L and 2.5 g/L.

Determination of metallic elements in Chilean wines by atomic absorption spectroscopy and inductively coupled plasma–mass spectrometry

The chemical composition of wines depends on series of variables such as the type of grape, edaphoclimatic conditions, and viticulture and winemaking practices employed during production. Metallic elements play a significant role during winemaking (e.g. as catalysts of oxidation reactions) and have been previously employed for the classification of wines according to provenance. In this work, we focused on the analysis of metallic elements (K, Na, Ca, Zn, Cu, Fe, Mg, Mn, Ni, Cr, Al, Pb, Cd, Hg, Se, Co, Sn and As) in 145 Chilean wine samples (102 reds and 43 white wines), of seven grape varieties, and five of the major wine producing regions in Chile.

How small amounts of oxygen introduced during bottling and storage can influence the metabolic fingerprint and SO2 content of white wines

The impact of minute amounts of headspace oxygen on the post-bottling development of wine is generally considered to be very important, since oxygen, packaging and storage conditions can either damage or improve wine quality. This is reflected in the generalised use of inert bottling lines, where the headspace between the white wine and the stopper is filled with an inert gas. This experiment aimed to address some open questions about the chemistry of the interaction between wine and oxygen, crucial for decisions regarding optimal closure. While it is known that similar amounts of oxygen affect different wines to a variable extent, our knowledge of chemistry is not sufficient to construct a predictive method.

Sensory impacts of the obturator used for the Chasselas: study over the time

Many parameters affect the organoleptic characteristics of wine: internal parameters like the chemical composition or polyphenol content and external as for example storage conditions or the type of obturator. The aim of this study was to characterize sensorally the impacts of several type of obturator on a white wine: Chasselas. To determine the organoleptic characteristics of this wine, a quantitative descriptive analysis could be used. But rapid sensory methods were preferred in this project. Indeed these methods are an appropriate alternative to conventional descriptive methods for quickly assessing sensory product discrimination.

Prediction of the production kinetics of the main fermentative aromas in alcoholic fermentation

Fermentative aromas (especially esters and higher alcohols) highly impact the organoleptic profile of young and white wines. The production of these volatile compounds depends mainly on temperature and Yeast Available Nitrogen (YAN) content in the must. Available dynamic models predict the main reaction
(bioconversion of sugar into ethanol and CO2 production) but none of them considers the production kinetics of fermentative aroma compounds during the process of fermentation. We determined the production kinetics of the main esters and higher alcohols for different values of initial YAN content and temperature, using an innovative online monitoring Gas Chromatography device.