Macrowine 2021
IVES 9 IVES Conference Series 9 Phenolic, antioxidant, and sensory heterogeneity of oenological tannins: what are their possible winemaking applications?

Phenolic, antioxidant, and sensory heterogeneity of oenological tannins: what are their possible winemaking applications?

Abstract

AIM: The aim of this work was to characterize 18 oenological tannins by the polyphenolic, antioxidant, and sensory point of view. These properties have been evaluated in model wine solution as well as in red wine added with these tannins to observe matrix effects and therefore to assess their performances in a real condition.

METHODS: Polyphenolic content (A280, Folin-Ciocalteu, proanthocyanidins assay) and antioxidant properties (ABTS, DPPH, FRAP, CUPRAC) were studied in a model wine solution (12 % ethanol, 4 g/L tartaric acid, pH 3.5). Bitterness and astringency sensory analysis (Descriptive Analysis) of selected formulations (40 g/hL) was performed in water and in red wine. After 1 month, the tannin-added wines were evaluated in terms of polyphenolic content (A280), antioxidant capacity (DPPH, FRAP), total anthocyanins, and polymerized pigments.

RESULTS: Antioxidant properties of oenological tannins and their influence on wine characteristics were strongly affected firstly by their polyphenolic richness, followed by their origin. In particular, the great antioxidant capacity of hydrolysable tannins was evident in both model wine solutions and wines after one month. Ellagitannins, thanks to this property, also led to an increased percentage of wine polymeric pigments with respect to the control whereas gallotannins showed low polymerization ability. Good performances were evidenced also by Acacia tannins additions in terms of increased polymeric pigments ratio. Moreover, quebracho formulations showed the highest perceived astringency and bitterness, but only in water solutions. In the same medium, ellagitannins exhibited a low value of bitterness and astringency but, on the contrary, they were perceived as astringent in red wine highlighting a significant matrix effect.

CONCLUSIONS

Phenolic content and antioxidant properties of tannin formulations in model wines are correlated with the characteristics of wines after one month. Among others, ellagitannins confirmed their potentialities in added wine regarding increased antioxidant capacity and polymeric pigments ratio. Nevertheless, astringency and bitterness are affected in different extent by the matrix, highlighting the influence of wine features on the final product sensory properties

DOI:

Publication date: September 7, 2021

Issue: Macrowine 2021

Type: Article

Authors

Luca Rolle

University of Turin – Department of Agricultural, Forest and Food Sciences,Maria Alessandra PAISSONI, University of Turin, Italy Giovanni BITELLI,  University of Turin, Italy Mar VILANOVA, CSIC- Misión Biológica de Galicia, Spain Carlo MONTANINI, AEB S.p.A., Italy Simone GIACOSA, Università degli Studi di Torino, Italy Luca ROLLE,  University of Turin, Italy Susana RÍO SEGADE,  University of Turin, Italy

Contact the author

Keywords

oenological tannins, phenolic compounds, antioxidant capacity, astringency, descriptive analysis

Citation

Related articles…

Generation and characterization of a training population in Vitis vinifera for enhanced genomic selection

Context and purpose of the study. Modern viticulture is facing significant challenges due to global climate changes, spanning from extreme heat spells and water scarcity to the acceleration of grapevine’s phenological development with important consequences from budbreak to harvest.

Effects of ethanol removal techniques on Nero d’Avola wine

Over the past two decades, climate change has contributed to an increase in sugar content in grape must, and consequently, in the ethanol levels of wines.

Estimating bulk stomatal conductance of grapevine canopies

In response to changes in their environment, grapevines regulate transpiration using various physiological mechanisms that alter conductance of water through the soil-plant-atmosphere continuum. Expressed as bulk stomatal conductance at the canopy scale, it varies diurnally in response to changes in vapor pressure deficit and net radiation, and over the season to changes in soil water deficits and hydraulic conductivity of both soil and plant. It is necessary to characterize the response of conductance to these variables to better model how vine transpiration also responds to these variables. Furthermore, to be relevant for vineyard-scale modeling, conductance is best characterized using data collected in a vineyard setting. Applying a crop canopy energy flux model developed by Shuttleworth and Wallace, bulk stomatal conductance was estimated using measurements of individual vine sap flow, temperature and humidity within the vine canopy, and estimates of net radiation absorbed by the vine canopy. These measurements were taken on several vines in a non-irrigated vineyard in Bordeaux France, using equipment that did not interfere with ongoing vineyard operations. An inverted Penman-Monteith equation was then used to calculate bulk stomatal conductance on 15-minute intervals from July to mid-September 2020. Time-series plots show significant diurnal variation and seasonal decreases in conductance, with overall values similar to those in the literature. Global sensitivity analysis using non-parametric regression found transpiration flux and vapor pressure deficit to be the most important input variables to the calculation of bulk stomatal conductance, with absorbed net radiation and bulk boundary layer conductance being much less important. Conversely, bulk stomatal conductance was one of the most important inputs when calculating vine transpiration, further emphasizing the need for characterizing its response to environmental changes for use in vineyard water use modeling.

Pedological factor influence on the viticultural zoning of the Aljarafe Alto (Seville, Spain)

Aljarafe Alto est une petite zone naturelle dans le département de Séville (Espagne), où le cépage autochtone cultivé est le Palomino Garrido Fino.

Use of artificial intelligence for the prediction of microbial diseases of grapevine and optimisation of fungicide application

Plasmopara viticola, the causal agent of downy mildew (DM), and Uncinula necator, the causal agent of powdery mildew (PM), are two of the main phytopathogenic microorganisms causing major economic losses in the primary sector, especially in the wine sector, by wilting bunches and leaves with a consequent decrease in the photosynthetic rate of the plant and in the annual yield. Currently, the most widespread methods for planning spraying are based on the 3-10 rule, which states that the first application should take place when: (i) the air temperature is greater than 10°C; (ii) shoots are equal or greater than 10 cm; and (iii) a minimum of 10 mm rainfall within 24–48 hours has occurred, or at the beginning of the bud break with periodic applications according to the manufacturer’s instructions.