Macrowine 2021
IVES 9 IVES Conference Series 9 Phenolic, antioxidant, and sensory heterogeneity of oenological tannins: what are their possible winemaking applications?

Phenolic, antioxidant, and sensory heterogeneity of oenological tannins: what are their possible winemaking applications?

Abstract

AIM: The aim of this work was to characterize 18 oenological tannins by the polyphenolic, antioxidant, and sensory point of view. These properties have been evaluated in model wine solution as well as in red wine added with these tannins to observe matrix effects and therefore to assess their performances in a real condition.

METHODS: Polyphenolic content (A280, Folin-Ciocalteu, proanthocyanidins assay) and antioxidant properties (ABTS, DPPH, FRAP, CUPRAC) were studied in a model wine solution (12 % ethanol, 4 g/L tartaric acid, pH 3.5). Bitterness and astringency sensory analysis (Descriptive Analysis) of selected formulations (40 g/hL) was performed in water and in red wine. After 1 month, the tannin-added wines were evaluated in terms of polyphenolic content (A280), antioxidant capacity (DPPH, FRAP), total anthocyanins, and polymerized pigments.

RESULTS: Antioxidant properties of oenological tannins and their influence on wine characteristics were strongly affected firstly by their polyphenolic richness, followed by their origin. In particular, the great antioxidant capacity of hydrolysable tannins was evident in both model wine solutions and wines after one month. Ellagitannins, thanks to this property, also led to an increased percentage of wine polymeric pigments with respect to the control whereas gallotannins showed low polymerization ability. Good performances were evidenced also by Acacia tannins additions in terms of increased polymeric pigments ratio. Moreover, quebracho formulations showed the highest perceived astringency and bitterness, but only in water solutions. In the same medium, ellagitannins exhibited a low value of bitterness and astringency but, on the contrary, they were perceived as astringent in red wine highlighting a significant matrix effect.

CONCLUSIONS

Phenolic content and antioxidant properties of tannin formulations in model wines are correlated with the characteristics of wines after one month. Among others, ellagitannins confirmed their potentialities in added wine regarding increased antioxidant capacity and polymeric pigments ratio. Nevertheless, astringency and bitterness are affected in different extent by the matrix, highlighting the influence of wine features on the final product sensory properties

DOI:

Publication date: September 7, 2021

Issue: Macrowine 2021

Type: Article

Authors

Luca Rolle

University of Turin – Department of Agricultural, Forest and Food Sciences,Maria Alessandra PAISSONI, University of Turin, Italy Giovanni BITELLI,  University of Turin, Italy Mar VILANOVA, CSIC- Misión Biológica de Galicia, Spain Carlo MONTANINI, AEB S.p.A., Italy Simone GIACOSA, Università degli Studi di Torino, Italy Luca ROLLE,  University of Turin, Italy Susana RÍO SEGADE,  University of Turin, Italy

Contact the author

Keywords

oenological tannins, phenolic compounds, antioxidant capacity, astringency, descriptive analysis

Citation

Related articles…

Teasing apart terroir: the influence of management style on native yeast communities within Oregon wineries and vineyards

Newer sequencing technologies have allowed for the addition of microbes to the story of terroir. The same environmental factors that influence the phenotypic expression of a crop also shape the composition of the microbial communities found on that crop. For fermented goods, such as wine, that microbial community ultimately influences the organoleptic properties of the final product that is delivered to customers. Recent studies have begun to study the biogeography of wine-associated microbes within different growing regions, finding that communities are distinct across landscapes. Despite this new knowledge, there are still many questions about what factors drive these differences. Our goal was to quantify differences in yeast communities due to management style between seven pairs of conventional and biodynamic vineyards (14 in total) throughout Oregon, USA. We wanted to answer the following questions: 1) are yeast communities distinct between biodynamic vineyards and conventional vineyards? 2) are these differences consistent across a large geographic region? 3) can differences in yeast communities be tied to differences in metabolite profiles of the bottled wine? To collect our data we took soil, bark, leaf, and grape samples from within each vineyard from five different vines of pinot noir. We also collected must and a 10º brix sample from each winery. Using these samples, we performed 18S amplicon sequencing to identify the yeast present. We then used metabolomics to characterize the organoleptic compounds present in the bottled wine from the blocks the year that we sampled. We are actively in the process of analysing our data from this study.

Extreme canopy management for vineyard adaptation to climate change: is it a good idea?

Climate change constitutes an enormous challenge for humankind and for all human activities, viticulture not being an exception. Long-term strategic changes are probably needed the most, but growers also need to deal with short-term changes: summers that are getting progressively warmer, earlier harvest dates and higher pH in musts and wines. In the last 10-15 years, a relevant corpus of research is being developed worldwide in order to evaluate to which extent extreme canopy management operations, aimed at reducing leaf area and, thus, limiting the source to sink ratio, could be useful to delay ripening. Although extreme canopy management can result in relevant delays in harvest dates, longer term studies, as well as detailed analysis of their implications on carbohydrate reserves, bud fertility and future yield are desirable before these practices can be recommended.

Grapevine varietal diversity as mitigation tool for climate change: Agronomic and oenologic potential of 14 foreign varieties grown in Languedoc region (France)

Climate change effects in Languedoc include an expected rise in temperatures, increased evapotranspiration as well as more severe and frequent climatic hazards, such as frost, drought periods and heat waves. For winegrowers theses phenomena impact both yield and quality, resulting in more frequent unbalanced wines. Research on identified mitigation tools for vineyard management is necessary to improve resilience of grapevine agrosystems. Varietal assortment is one of them. This study focuses on agronomic and oenologic potential of 14 foreign varieties grown in Languedoc French region. Fourteen grapevine varieties were monitored during 2021 from June until harvest on eight different sites, some of which occurring on more than one site adding up to 21 different modalities: 7 white varieties Alvarinho B, Assyrtiko B (2), Malvasia Istriana B, Parellada B, Verdejo B, Verdelho B, Xarello B, and 7 black varieties Saperavi N (2), Touriga nacional N, Baga N, Aleatico N, Montepulciano N (2), Primitivo N (3), Calabrese N (3). Varietals were compared through the following parameters: phenology was assessed by using the information collected in the Database Network of French Vine Conservatories (INRAE-SupAgro-IFV, 2005-2015). The number of inflorescences for shoots from secondary buds and bourillons and suckers were observed to assess post-bud break frost tolerance potential. Grapevine water status was studied through stem water potential measurement, observation of foliage symptoms of drought, and 𝛿13C on must. Frequencies and intensities of downy mildew, powdery mildew, and black rot attacks were estimated before harvest on leaves and clusters and botrytis at harvest to assess disease susceptibilities. Berry composition was monitored from end of veraison until harvest. Yield and mean bunch weight were also calculated. Varieties were then ranked on a 1-4 scale for each parameter and compared through PCA. Forty two stations of the Mediterranean basin were compared by PCA with the Multicriteria Climatic Classification indicators in order to confront the collected information during 2021 campaign to the hypothesis that plants coming from dry and hot regions are genetically adapted to such climatic conditions.

Optimizing stomatal traits for future climates

Stomatal traits determine grapevine water use, carbon supply, and water stress, which directly impact yield and berry chemistry. Breeding for stomatal traits has the strong potential to improve grapevine performance under future, drier conditions, but the trait values that breeders should target are unknown. We used a functional-structural plant model developed for grapevine (HydroShoot) to determine how stomatal traits impact canopy gas exchange, water potential, and temperature under historical and future conditions in high-quality and hot-climate California wine regions (Napa and the Central Valley). Historical climate (1990-2010) was collected from weather stations and future climate (2079-99) was projected from 4 representative climate models for California, assuming medium- and high-emissions (RCP 4.5 and 8.5). Five trait parameterizations, representing mean and extreme values for the maximum stomatal conductance (gmax) and leaf water potential threshold for stomatal closure (Ψsc), were defined from meta-analyses. Compared to mean trait values, the water-spending extremes (highest gmax or most negative Ysc) had negligible benefits for carbon gain and canopy cooling, but exacerbated vine water use and stress, for both sites and climate scenarios. These traits increased cumulative transpiration by 8 – 17%, changed cumulative carbon gain by -4 – 3%, and reduced minimum water potentials by 10 – 18%. Conversely, the water-saving extremes (lowest gmax or least negative Ψsc) strongly reduced water use and stress, but potentially compromised the carbon supply for ripening. Under RCP 8.5 conditions, these traits reduced transpiration by 22 – 35% and carbon gain by 9 – 16% and increased minimum water potentials by 20 – 28%, compared to mean values. Overall, selecting for more water-saving stomatal traits could improve water-use efficiency and avoid the detrimental effects of highly negative canopy water potentials on yield and quality, but more work is needed to evaluate whether these benefits outweigh the consequences of minor declines in carbon gain for fruit production.

Bioclimatic shifts and land use options for Viticulture in Portugal

Land use, plays a relevant role in the climatic system. It endows means for agriculture practices thus contributing to the food supply. Since climate and land are closely intertwined through multiple interface processes, climate change may lead to significant impacts in land use. In this study, 1-km observational gridded datasets are used to assess changes in the Köppen–Geiger and Worldwide Bioclimatic (WBCS)