Macrowine 2021
IVES 9 IVES Conference Series 9 Wine archeochemistry: a multiplatform analytical approach to chemically profile shipwreck wines

Wine archeochemistry: a multiplatform analytical approach to chemically profile shipwreck wines

Abstract

AIM: The Cape of Storms (also known as Cape of Good Hope) is renowned for harbouring a multitude of shipwrecks due to the inherent treacherous coastline and blistering storms. One such shipwreck is the English East Indiaman Colebrooke, wrecked in False Bay, South Africa, in 1778. A discovery on the shipwreck was a shipment of wine of unknown origin and style, possibly Madeira as it was known that the English East India Company often purchased wine from there but this was not mentioned in the ship’s log. As the wreck was exploited by treasure hunters, very little contextual information is known. To further expand the sample pool with more examples of old wine, we have included another sample recovered from the wreck of the SS Maori sunk in 1909. Additionally, three samples of (old) wines stored in vinotheque conditions were included: a Château d’Yquem (1918 vintage) and two Château Margaux (1984).

METHODS: A minimal volume of wine (<50 mL) was analysed using untargeted analyses (GC-MS, LC-HRMS and NMR spectroscopy), metals (ICP-MS/OES), and sugars and organic acids (HPLC-DAD-RID). Important volatile aroma compounds were identified by HS-SPME-GCMS and their identification confirmed using Wiley/NIST libraries and RI. A screening exercise was performed by experienced researchers to sensorially evaluate the possible wine-like aromas.

RESULTS: Unexpected chemical characteristics regarding the metal concentrations, sugar and acid composition as well as the aroma profile were found. Compared to current export regulations, the levels of heavy metals were considerably higher, possibly due to the bottle glass composition and leaching over time. The untargeted analyses showed various compounds including fermentation-derived products (esters, alcohols, aldehydes and fatty acids), terpenoids (linalool, fenchone) and “woody” compounds (furfural and guaiacol). Incredibly, some of the samples still presented wine-like features related to aroma both in the chemical and the sensory evaluation. 

CONCLUSIONS

Unlike other work where the source and/or type of beverage recovered from shipwrecks were known, and with a limited volume of sample, we could still obtain results providing interesting “chemical snapshots” of old wines using advanced analytical and spectroscopic techniques. Combining new technology platforms in analytical chemistry can provide valuable insight into the composition of wines recovered from shipwrecks with the help of maritime archaeologists. Including analyses such as X-ray diffraction on the bottles can assist in tracing more information about the sources of heavy metal content and possibly even the origin of the wines.

DOI:

Publication date: September 13, 2021

Issue: Macrowine 2021

Type: Article

Authors

Astrid Buica

South African Grape and Wine Research Institute, Department of Viticulture and Oenology, Stellenbosch University, South Africa,Cody, WILLIAMS, Department of Viticulture and Oenology, Stellenbosch University, South Africa Jaco, BOSHOFF, Iziko Museums of South Africa, Maritime Archaeology Unit, Research and Exhibitions, Cape Town, South Africa Wendy, BLACK, Iziko Museums of South Africa, Archaeology Unit, Research & Exhibitions Department, Cape Town, South Africa Valeria, PANZERI, Department of Viticulture and Oenology, Stellenbosch University, South Africa

Contact the author

Keywords

marine archeology, shipwreck, untargeted analyses, metals, sugars and organic acids, sensory screening

Citation

Related articles…

The modification of cultural practices in grapevine cv. Syrah, does it modify the characteristics of the musts?

The work shows the results of a year of experimentation (2020) in a Syrah variety vineyard in La Roda (Castilla-La Mancha, Spain). The trial approach was on a randomized block design with two factors: Irrigation (I) and Pruning (P).
Irrigation schedules were adjusted to apply amounts close to 1,500 m3/ha. With this provision, 2 different irrigation treatments were proposed: I1) Start of irrigation from pea-sized grape to post-harvest (providing at least 20 % of the total amount of irrigation water to be provided post-harvest); I2) Start of irrigation from pea-sized grape to harvest (usual irrigation practice in the study area). Pruning was proposed with two treatments, one at the end of January (P1), which is pruning on a conventional date; and P2) pruning carried out at the beginning of budding. In total, 4 repetitions were designed with 4 elementary plots, each one of them representing one of the proposed treatments (I1P1; I1P2; I2P1; I2P2). In total, 16 plots were worked on and each elementary plot consisted of 30 strains, distributed in 3 lines.
The productive response was evaluated with the yield results of the harvest harvested at 23 ºBrix. The qualitative response was measured in the musts through the indices of technological (acidity, pH and potassium) and phenolic maturity and aromatic compounds in free and glycosylated fractions. The treatments tested had, in general, an effect on the different variables analyzed.

Effect of fertigation strategies to adapt PGI Côtes de Gascogne production to hot vintage

The development of fertigation could be a possible solution to adapt PGI Côtes de Gascogne (south-western France) wine production to climate change. The goal would be to limit the negative effects of water stress on yield performance expectation (around 15 tons per hectare) and to make the use of fertilizers more efficient. This study aimed to compare the effects of three strategies of water and minerals supply on grapes and wines qualities. Two fertigation practices were compared to a rainfed control which is the current standard of the local grape growing production. The fertilizers (nitrogen and potassium) were (i) fully brought by irrigation pipe during the season, (ii) partially brought by irrigation pipe and partially on the soil or (iii) fully brought on the soil at the beginning of the season for the non-irrigated control (local standard). The trial was run on cv. Colombard trained on spur pruned with vertical shoot positioning system on a sandy-silty-clay soil over the 2020 vintage which was particularly hot for the region. Moderate to strong water deficit appeared during the growing period of the berries and held on after veraison. Irrigation strategies allowed for maintaining grapevine without water deficit and being significantly different from the control water status. Grapevine with fully or partial fertigation strategies produced 25% more yield mainly due to the increase of the bunch weight. Also, the fully fertigation showed the best ratio between yield and maturity and brought 30% less of fertilizers (both nitrogen and potassium) than the two other strategies. Finally, the analysis of aromatic compounds in Colombard wines, varietal thiols family, showed the same level of concentrations for the 3 treatments, confirming that the yield performance did not impact the aromatic potential in this trial.

Evaluation of climate change impacts at the Portuguese Dão terroir over the last decades: observed effects on bioclimatic indices and grapevine phenology

In the last decades the growers of the Portuguese Dão winegrowing region (center of Portugal) are experiencing changes in climate that are influencing either grape phenology berry health and ripening. Aiming to study the relationships between climate indices (CI), seasonal weather and grapevine phenology, in this work long-term climate and phenological data collected at the experimental vineyard of the Portuguese Dão research centre between 1958 and 2019 (61 years) for the red variety Touriga Nacional, was analyzed. The trends over time for the classical temperature-based indices (Growing Season Temperature – GST -, Growing Degree Days – GDD, Huglin Index – HI and Cool Night Index – CI) presented a significantly positive slope while the Dryness Index (DI) showed a negative trend over the last 61 years. Regarding grapevine phenology, an average advance of 4.5 days per decade in the harvest day was observed throughout the last 61 years. Consequently, the weather conditions during the ripening period have changed, showing an increasing trend over time in the average temperature (higher magnitude in the maximum than in the minimum temperature) and a decrease in the accumulated rainfall. A regression analysis showed that ~50% of harvest date variability over years was explained by the temperature-based indices variability. These observed effects of climate change on bioclimatic indices and corresponding anticipation of harvest date can still be considered advantageous for the Dão terroir as it allows to achieve an optimal berry ripening before the common equinox rains and, therefore, avoid the potential negative impacts of the rainfall on berry health and composition.

Climate and the evolving mix of grape varieties in Australia’s wine regions

The purpose of this study is to examine the changing mix of winegrape varieties in Australia so as to address the question: In the light of key climate indicators and predictions of further climate change, how appropriate are the grape varieties currently planted in Australia’s wine regions? To achieve this, regions are classified into zones according to each region’s climate variables, particularly average growing season temperature (GST), leaving aside within-region variations in climates. Five different climatic classifications are reported. Using projections of GSTs for the mid- and late 21st century, the extent to which each region is projected to move from its current zone classification to a warmer one is reported. Also shown is the changing proportion of each of 21 key varieties grown in a GST zone considered to be optimal for premium winegrape production. Together these indicators strengthen earlier suggestions that the mix of varieties may be currently less than ideal in many Australian wine regions, and would become even less so in coming decades if that mix was not altered in the anticipation of climate change. That is, grape varieties in many (especially the warmest) regions will have to keep changing, or wineries will have to seek fruit from higher latitudes or elevations if they wish to retain their current mix of varieties and wine styles.

Adapting the vineyard to climate change in warm climate regions with cultural practices

Since the 1980s global regime shift, grape growers have been steadily adapting to a changing climate. These adaptations have preserved the region-climate-cultivar rapports that have established the global trade of wine with lucrative economic benefits since the middle of 17th century. The advent of using fractions of crop and actual evapotranspiration replacement in vineyards with the use of supplemental irrigation has furthered the adaptation of wine grape cultivation. The shift in trellis systems, as well as pruning methods from positioned shoot systems to sprawling canopies, as well as adapting the bearing surface from head-trained, cane-pruned to cordon-trained, spur-pruned systems have also aided in the adaptation of grapevine to warmer temperatures. In warm climates, the use of shade cloth or over-head shade films not only have aided in arresting the damage of heat waves, but also identified opportunities to reduce the evapotranspiration from vineyards, reducing environmental footprint of vineyard. Our increase in knowledge on how best to understand the response of grapevine to climate change was aided with the identification of solar radiation exposure biomarker that is now used for phenotyping cultivars in their adaptability to harsh environments. Using fruit-based metrics such as sugar-flavonoid relationships were shown to be better indicators of losses in berry integrity associated with a warming climate, rather than solely focusing on region-climate-cultivar rapports. The resilience of wine grape was further enhanced by exploitation of rootstock × scion combinations that can resist untoward droughts and warm temperatures by making more resilient grapevine combinations. Our understanding of soil-plant-atmosphere continuum in the vineyard has increased within the last 50 years in such a manner that growers are able to use no-till systems with the aid of arbuscular mycorrhiza fungi inoculation with permanent cover cropping making the vineyard more resilient to droughts and heat waves. In premium wine grape regions viticulture has successfully adapted to a rapidly changing climate thus far, but berry based metrics are raising a concern that we may be approaching a tipping point.