Macrowine 2021
IVES 9 IVES Conference Series 9 Identification, quantification and organoleptic impact of « dried fruit » molecular markers in Merlot and Cabernet Sauvignon grapes and in red wines

Identification, quantification and organoleptic impact of « dried fruit » molecular markers in Merlot and Cabernet Sauvignon grapes and in red wines

Abstract

The aromas found in young Bordeaux red wines made with Merlot and Cabernet Sauvignon suggest a complex mixture of aromas of fresh red fruits such as cherry or blackberry for Merlot, and strawberry or blackcurrant for Cabernet Sauvignon. The aromas of these wines are closely linked with the maturity of the grapes. The climate change that has occurred during the last decade in Bordeaux has induced changes in the ripening conditions of grape berries. It is now widely admitted that over-ripening of the berries during hot and dry summers results in the development of characteristic flavors reminiscent of cooked fruits (fig, prune). The presence of these overriding odors found in both musts and young wines affects the quality and subtlety of the wine flavor and may shorten its shelf life. The main goal of this research was to identify key aroma compounds involved in “overripened” red wines with an intense prune, cooked fruit aroma. Gas chromatography coupled with olfactometry and mass spectrometry (GC-O-MS) was used in order to find odorant zones (OZ) and identify volatile compounds responsible for the cooked fruit aroma in Merlot and Cabernet Sauvignon (CS) grapes. As a result, several OZ of cooked fruits were highlighted and identified by GC-MS. The analysis of many musts and wines marked or not by dried fruit flavors showed that furaneol (caramel), γ-nonalactone (coconut, cooked peach) and (Z)-1,5-octadien-3-one (geranium) play a role in this aroma. Furaneol and γ-nonalactone are well-known compounds in wines. On the contrary, the influence of (Z)-1,5-octadien-3-one is reported for the first time in musts from healthy grapes. A first quantification method of this ketone using SPME-GC-CI-MS was also validated in terms of repeatability, linearity and limits of detection. Perception thresholds in model solution were determined: 0.0022 ng/L in model solution of must, 9 ng/L in Merlot must and 1.2 ng/L in wine model solution. This compound, which is reminiscent of geranium, is extremely intense. Its quantification was performed in musts marked or not by dried fruit flavors. Its concentration in musts marked by these flavors can reach 80 ng/L. The correlation between the concentration of these compounds including (Z)-1,5-octadien-3-one, furaneol and γ-nonalactone and their sensory analysis is described. The details of this study and the consequences of the level and distribution of these compounds in musts and wines on the determination of factors (harvest date, light, vine) associated with their formation are also presented.

Publication date: May 17, 2024

Issue: Macrowine 2016

Type: Article

Authors

Allamy Lucile*, Darriet Philippe, Pons Alexandre

*ISVV

Contact the author

Tags

IVES Conference Series | Macrowine | Macrowine 2016

Citation

Related articles…

Comparison of aroma-related compounds of carbonic maceration and traditional young red winemaking in case of Merlot by means of targeted metabolomic approach

Winemaking decisions and techniques are known to affect the final aromatic composition of red wines. Winemakers put a constant effort into the improved controlling of vinification procedures to achieve better quality. Anyway an increased customer’s demand for uniqueness is often forcing them to adjust and offer new and new interesting products. To support the producers, an improved knowledge on aromatic potential as affected by classical and alternative strategies is needed.

Improving the phenolic composition of cv tempranillo wines by blending grapes of different ripening state

The aim of this work was to reduce the alcohol content of Tempranillo wine. Tempranillo wines were produced by grapes harvested at different ripening dates (August 11 which was 21 oBrix and September 28 with 25 oBrix). At the second date, the Tempranillo wines were elaborated as follows: grapes were destemmed, crushed and collected into 50 L stainless-steel vats. Before preferementative maceration in cold, 50 % (M1) and 70 % (M2) of the must have been replaced by the same percentage of must from the first harvest. In addition, a control wine (C) was performed with only grapes from the second harvest.

Identification of caffeic acid as a major component of Moscatel wine protein sediment

Proteins play a significant role in the colloidal stability and clarity of white wines [1]. However, under conditions of high temperatures during storage or transportation, the proteins themselves can self-aggregate into light-dispersing particles causing the so-called protein haze [2]. Formation of these unattractive precipitates in bottled wine is a common defect of commercial wines, making them unacceptable for sale [3]. Previous studies identified the presence of phenolic compounds in the natural precipitate of white wine [4], contributing to the hypothesis that these compounds could be involved in the mechanism of protein haze formation.

Grape metabolites, aroma precursors and the complexities of wine flavour

A critical aspect of wine quality from a consumer perspective is the overall impression of wine flavour, which is formed by the interplay of volatile aroma compounds, their precursors, and taste and matrix components. Grapes contribute some potent aroma compounds, together with a large pool of non-volatile precursors (e.g. glycoconjugates and amino acid conjugates). Aroma precursors can break down through chemical hydrolysis reactions, or through the action of yeast or enzymes, significantly changing the aroma profile of a wine during winemaking and storage. In addition, glycoconjugates of monoterpenes, norisoprenoids and volatile phenols, together with sulfur-conjugates in wine, provide a reservoir of additional flavour through the in-mouth release of volatiles which may be perceived retro-nasally.

Influence of preflowering basal leaf removal on aromatic composition of cv. Tempranillo wine from semiarid climate (Extremadura Western Spain)

Abstract In this work the effects of early leaf removal performed manually at preflowering phenological stage, on the volatile composition of Tempranillo (Vitis vinifera L.) wines were studied. From 2009-2011 vintages 34 wine volatile compounds were identified and quantified by gas chromatography-mass spectrometry (GC-MS) where early leaf removal only modified 25 of them. The total C6 compounds, acetates and volatiles acids (with exception of isobutyric acid) were affected by defoliation, whereas alcohols and esters showed a minor effect. Furthermore the vintage effect also was shown.