Terroir 1996 banner
IVES 9 IVES Conference Series 9 La vinificación de las uvas aromáticas: Moscateles y Malvasías

La vinificación de las uvas aromáticas: Moscateles y Malvasías

Abstract

Las uvas aromáticas se pueden dividir en dos clases, Moscateles y Malvasías, dependiendo del hecho de que el linalol o el geraniol, respectivamente, sean los alcoholes terpénicos monohidroxilados que predominan en el jugo de la uva. Dentro de cada clase existen numerosas subclases que se diferencian por las relaciones entre los otros alcoholes terpénicos mono y dihidroxilados, en forma libre y glicosilada. Otra diferencia entre los Moscateles y las Malvasías es la cantidad de compuestos terpénicos libres del mosto, (los terpenos del hollejo, en las dos clases, se encuentran casi en su totalidad como formas glicosiladas) que puede ser alto como en el caso del Moscatel (linalol, óxido trans piránico del linalol, 2,6-dimetil-3,7-octadien-2,6-diol) o mas bién bajo como en el caso de las Malvasías (geraniol, 2,6-dimetil-3,7-octadien-2,6-diol), mientras que en los hollejos es una característica común a las dos clases la presencia de elevadas cantidades de nerol y de geraniol en forma glicosilada. La composición terpénica de las dos variedades condiciona, además del aroma del vino final, la tecnología de producción.En Italia con el “Moscato bianco” y con las Malvasías (“Malvasia di Casorzo”, “Malvasia di Castelnuovo don Bosco”, esta última en muchos aspectos parecida a los Moscateles, “Brachetto d’Acqui”, que son todas variedades tintas) se preparan dos tipos de vino: uno espumoso y uno no espumoso. El primero se caracteriza por un contenido alcohólico de aproximadamente un 7%y una concentración de azúcares de aproximadamente 70 g/L y el segundo por un grado alcohólico del 5 % y una cantidad de azúcares variable dependiendo de los gustos del productor.En la vinificación del “Moscato bianco” se utiliza solo el mosto (una eventual criomaceración no conlleva un aumento sensible en compuestos terpénicos), que es rico de linalol que no resulta ni absorbido ni metabolizado por las levaduras, mientras que en el caso de las Malvasías tintas, para cuya vinificación se utilizan también los hollejos, el geraniol, practicamente el único alcohol terpénico monohidroxilado presente en el mosto, es metabolizado parcialmente por las levaduras y en parte reducido a citronellol y estos dos compuestos, además del nerol, son transformados en derivados acetilados. Además, a causa de las elevadas cantidades de glucosa que se encuentran en el mosto durante toda la fase de preparación de los vinos de estas variedades, los enzimas glicosidásicos, del mosto o de las levaduras, no pueden transformar en los respectivos aglicones los glicósidos del nerol y del geraniol presentes en el mosto, que quedan, por lo tanto, en forma glicosilada, es decir, no aromática, en el vino final. Las técnicas tradicionales de vinificación establecen, para la extracción del color y de los compuestos terpénicos de los hollejos de las Malvasías tintas, continuos remontados cuando la fermentación todavía no ha empezado, o una fermentación parcial en presencia de los hollejos. Estas dos técnicas son insuficientes sea para extraer la gran cantidad de glicósidos del nerol y del geraniol de los hollejos, sea para hidrolizar los glicósidos terpénicos. En este trabajo se presenta una nueva técnica de vinificación, que favorece la extracción y la hidrólisis de los compuestos terpénicos de los hollejos de las Malvasías tintas y que incrementa sensiblemente la intensidad del aroma y la calidad de los vinos que se obtienen con esta variedad.

DOI:

Publication date: February 24, 2022

Issue: Terroir 2000 

Type: Article

Authors

Rocco Di Stefano*, Emilia García Moruno* and Monica Ribaldone**

*Istituto Sperimentale per l’Enologia, via P. Micca 35 — 14100 Asti (Italia)
**Consorzio per la tutela del Brachetto

Tags

IVES Conference Series | Terroir 2000

Citation

Related articles…

The plantation frame as a measure of adaptation to climate change

The mechanization of vineyard work originally led to a reduction in planting densities due to the lack of machinery adapted to the vineyard. The current availability of specific machinery makes it possible to establish higher planting densities. In this work, three planting densities (1.40×0.80 m, 1.80×1 m and 2.20×1.20 m, corresponding to 8928, 5555 and 3787 plants/ha respectively) were studied with four varieties autochthonous of Galicia (northwestern Spain): Albariño and Treixadura (white), Sousón and Mencía (red). The vines were trained in a vertical shoot positioning system using a single Royat cordon, and pruned to spurs with two buds each. Agronomic data (yield, pruning wood weight, Ravaz index) and oenological data in must were collected. The higher planting density (1.40×0.80 m) had no significant effect on grape yield per vine in white varieties, although production per hectare was much higher due to the greater number of plants. In red varieties, this planting density resulted in a significantly lower production per vine, compensated by the greater number of plants. In addition, it significantly reduced the Brix degree in the must of the Albariño, Treixadura and Sousón varieties, and increased the total acidity in the latter two and Mencía. It also caused an increase in extractable and total anthocyanins and IPT in red grapes. The effects of high planting density on grapes are of great interest for the adaptation of varieties in the context of climate change. In the future, it could be advisable to modify the limits imposed by the appellations of origin on the planting density of these varieties in order to obtain more balanced wines.

Terroir analysis and its complexity

Terroir is not only a geographical site, but it is a more complex concept able to express the “collective knowledge of the interactions” between the environment and the vines mediated through human action and “providing distinctive characteristics” to the final product (OIV 2010). It is often treated and accepted as a “black box”, in which the relationships between wine and its origin have not been clearly explained. Nevertheless, it is well known that terroir expression is strongly dependent on the physical environment, and in particular on the interaction between soil-plant and atmosphere system, which influences the grapevine responses, grapes composition and wine quality. The Terroir studying and mapping are based on viticultural zoning procedures, obtained with different levels of know-how, at different spatial and temporal scales, empiricism and complexity in the description of involved bio-physical processes, and integrating or not the multidisciplinary nature of the terroir. The scientific understanding of the mechanisms ruling both the vineyard variability and the quality of grapes is one of the most important scientific focuses of terroir research. In fact, this know-how is crucial for supporting the analysis of climate change impacts on terroir resilience, identifying new promised lands for viticulture, and driving vineyard management toward a target oenological goal. In this contribution, an overview of the last findings in terroir studies and approaches will be shown with special attention to the terroir resilience analysis to climate change, facing the use and abuse of terroir concept and new technology able to support it and identifying the terroir zones.

Using δ13C and hydroscapes as a tool for discriminating cultivar specific drought response

Measurement of carbon isotope discrimination in berry juice sugars at maturity (δ13C) provides an integrated assessment of water use efficiency (WUE) during the period of berry ripening, and when collected over multiple seasons can be used as an indication of drought stress response. Berry juice δ13C measurements were carried out on 48 different varieties planted in a common garden experiment in Bordeaux, France from 2014 through 2021 and were paired with midday and predawn leaf water potential measurements on the same vines in a subset of six varieties. The aim was to discriminate a large panel of varieties based on their stomatal behaviour and potentially identify hydraulic traits characterizing drought tolerance by comparing δ13C and hydroscapes (the visualisation of plant stomatal behaviour as a response to predawn water potential). Cluster analysis found that δ13C values are likely affected by the differing phenology of each variety, resulting in berry ripening of different varieties taking place under different stress conditions within the same year. We accounted for these phenological differences and found that cluster analysis based on specific δ13C metrics created a classification of varieties that corresponds well to our current empirical understanding of their relative drought tolerances. In addition, we analysed the water potential regulation of the subset of six varieties (using the hydroscape approach) and found that it was well correlated with some δ13C metrics. Surprisingly, a variety’s water potential regulation (specifically its minimum critical leaf water potential under water deficit) was strongly correlated to δ13C values under well-watered conditions, suggesting that base WUE may have a stronger impact on drought tolerance than WUE under water deficit. These results give strong insights on the innate WUE of a very large panel of varieties and suggest that studies of drought tolerance should include traits expressed under non-limiting conditions.

Sustainable fertilisation of the vineyard in Galicia (Spain)

Excessive fertilization of the vineyard leads to low quality grapes, increased costs and a negative impact on the environment. In order to establish an integrated management system aimed at a sustainable fertilization of the vineyards, nutritional reference levels were established. For this purpose, 30 representative vineyards of the Albariño variety were studied, in which soil and petiole analyses were carried out for two years and grape yield and quality at harvest were measured. In both years of study, soil pH, calcium, sodium and cation exchange capacity were positively correlated with calcium content and negatively correlated with manganese in grapes. Irrigated vineyards had higher levels of aluminium in soil and lower levels of calcium in petiole. Climatic conditions were very different in the years of the study. The year 2019 was colder than usual, in 2020 there was a marked water stress with high summer temperatures. This resulted in medium-high acidity in grapes in 2019 and low acidity in 2020, with sugar levels being similar both years. A very marked decrease in must amino nitrogen was observed in 2020, with ammonia nitrogen remaining stable. The correlation of acidity and sugar values in grapes with soil and petiole analysis data made it possible to establish reference levels for the nutritional diagnosis of the Albariño variety in this region. Based on these results, an easy-to-use TIC application is currently being created for grapegrowers, aimed at improving the sustainability of the vineyard through reasoned fertilization. This study has now been extended to other Galician vine varieties.

Drought effect on aromatic and phenolic potential of seven recovered grapevine varieties in Castilla-La Mancha region (Spain)

The effects of climate change are seriously affecting the quality of wine grapes. High temperatures and drought cause imbalances in the chemical composition of grapes. The result is overripe grapes with low acidity and high sugar content, which produce wines with excessive alcohol content, lacking in freshness and not very aromatic. As a consequence, the search of varieties with capacity of produce quality grapes in adverse climate conditions is a good alternative to preserve the sustainability of vineyards. In this work, quality parameters of seven Vitis vinifera L. cultivars (five whites and two reds) recently recovered from extinction and grown under two different hydric regimes (rainfed and irrigated) were analyzed during the 2020 vintage. At harvest time, weight of 100 berries, must physicochemical parameters (brix degree, total acidity, malic acid, pH), and carbon and oxygen isotope ratios (δ13C, δ18O) were determined. Subsequently, varietal aroma potential index (IPAv) and total polyphenol index (TPI) were analyzed. Quality parameters, IPAv and TPI, showed significant differences between varieties and water regimes. Both red varieties, Moribel and Tinto Fragoso, stood out for their high aromatic and phenolic potential, which was higher under rainfed regime. Regarding to white varieties, Montonera del Casar and Jarrosuelto stood out in terms of varietal aroma potential. Montonera del Casar high acidity in its musts and Jarrosuelto showed the highest berry weights.