IVAS 2022 banner
IVES 9 IVES Conference Series 9 IVAS 9 IVAS 2022 9 Transition metals and light-dependent reactions: application of a response surface methodology approach

Transition metals and light-dependent reactions: application of a response surface methodology approach

Abstract

Light-induced reactions can be responsible for detrimental changes of white and rosé wines. This is associated to the photo-degradation of riboflavin (RF) and of methionine (Met) causing the appearance of light-struck taste (LST). The fault is associated to the formation of volatile sulfur compounds (VSCs), namely methanethiol (MeSH) and dimethyl disulfide (DMDS), leading to cooked cabbage, onion and garlic odours-like [1]. Aside these pathways, other oxidative reactions can occur involving iron and copper that can generate quinones. Moreover, the ability of copper in binding the compounds containing a free thiol group is well known. 
This study aimed to evaluate for the first time the combined effect of iron, copper, and oxygen on LST formation in model wine.
A Surface Response Methodology approach was used considering 3 variables, as iron, copper and oxygen. Based on the experimental design, 15 runs (light-exposed and kept in the dark) were performed in model wine. Furthermore, to better understand the influence of phenolics, the same experimental design was applied in the presence of catechin and caffeic acid, used as model phenols. RF, Met, VSCs, and sensory were determined.
No RF was found in any light-exposed sample analysed. The major decrease of Met was revealed in model solution in which MeSH and DMDS were the highest. The presence of phenolics limited the degradation of Met and, consequently, the formation of MeSH and DMDS. In particular, in most of the runs where caffeic acid was added, VSCs were lower than in the runs in model wine and in the presence of catechin. The presence of iron (10 mg/L and 5 mg/L with oxygen 3 mg/L) led to a higher content of mercaptans in model wine as well as in the presence of catechin and caffeic acid. Our findings suggest that besides RF and Met, the susceptibility of a wine in developing LST appeared to be related to the presence of transition metals as well as to the different phenols that would ordinarily be present in wine. 
This study represents a further step for the deeper comprehension of the photo-induced reactions allowing to pursue the LST prevention in white wine.

DOI:

Publication date: June 23, 2022

Issue: IVAS 2022

Type: Article

Authors

Fracassetti Daniela1, Jeffery David2, Ballabio Davide3 and Tirelli Antonio1

1Department of Food, Environmental and Nutritional Sciences (DeFENS), Università degli Studi di Milano, Via G. Celoria 2, 20133 Milan, Italy
2Department of Wine Science and Waite Research Institute, The University of Adelaide
3Department of Earth and Environmental Sciences, University of Milano-Bicocca

Contact the author

Keywords

riboflavin, methionine, catechin, caffeic acid, volatile sulfur compounds

Tags

IVAS 2022 | IVES Conference Series

Citation

Related articles…

Impact of mycorrhizal inoculation of ‘Monastrell’ grapevines grafted onto different conventional vs. newly breed rootstocks 

Grafting Vitis vinifera L. (wine traditional cultivars) onto North American grapevine species or hybrids is a common practice in viticulture given their tolerance against phylloxera (Daktulosphaira vitifoliae). However, rootstock genetic background affects the response of grapevines to environmental stresses and their ability for establishing a symbiotic relationship with the microbial communities, and more specifically with arbuscular mycorrhizal fungi (AMF).
The aim of this study was to evaluate Monastrell variety (clone ENTAV 369) grafted onto three rootstocks (140Ru, 110R and RG8) characterized by a different genetic background, in combination with AMF inoculation (Rhizophagus irregularis) vs. a non-inoculated control with regards to vegetative growth, leaf gas exchange parameters, and mycorrhization.

Terroir zoning in appellation campo de borja (northeast Spain): Preliminary results

The components and methodology for characterization of the terroir have been described by Gómez-Miguel & Sotés (1993-2014, 2003) and Gómez-Miguel (2011) taking into account the full range of environmental factors (i.e: climate, lithology, vegetation, topography, soils, altitude, etc.), landscape variables (derived from photo-interpretation and a digital elevation model), and specific variables to the country’s viticulture (i.e: size and distribution of the vineyards, varieties, phenology, productivity, quality, designation regulations, etc.).

The evaluation of tannin activity in south african red wines

Astringency is an important red wine quality attribute, which can be measured both chemically and sensorially. The use of tannin activity shows potential as a valuable chemical measurement in understanding red wine mouthfeel properties such as astringency and bitterness, which is also affected by tannin structural factors, in addition to matrix effects. Tannin activity is defined as the enthalpy of interaction between tannins and a hydrophobic surface. Studies involving tannin activity have been performed since the early 2010’s, but chemosensory studies used to evaluate how structure-activity relationships change across multiple, consecutive vintages are limited. The aim of this study is to investigate how tannin activity may be linked to red wine mouthfeel, and how all these variables may change according to wine age.

The role of NAC61 transcription factor in the regulation of berry ripening progression 

The undergoing global warming scenario is affecting grapevines phenology, including the timing of berry ripening and harvest date, negatively impacting production and quality. This work reports the crucial role of NAC61, a grapevine NAC transcription factor, in regulating metabolic processes occurring from the onset of ripening onwards. NAC61 high confidence targets mainly represent genes acting on stilbene biosynthesis and regulation, and in osmotic and oxidative/biotic stress-related responses. The direct regulation of the stilbene synthase regulator MYB14, the osmotic stress-related gene DHN1b, and the Botrytis cinerea susceptibility gene WRKY52, were all further validated.

A zoning study of the viticultural territory of a cooperative winery in Valpolicella

The Valpolicella hilly area, north of Verona, is highly vocated for viticulture but its vineyards are sometimes characterized by very different soil and microclimate conditions which can greatly affect their oenological potential.