IVAS 2022 banner
IVES 9 IVES Conference Series 9 IVAS 9 IVAS 2022 9 Effect Of Grape Polysaccharides On The Volatile Composition Of Red Wines

Effect Of Grape Polysaccharides On The Volatile Composition Of Red Wines

Abstract

Yeast mannoproteins and derivates are polysaccharides produced from the cell walls of different yeast strains widely used in the winemaking and finning of wines to improve their overall stability and sensory properties. Some studies reported that mannoproteins maintain the wine aroma tending to be more appealing. On the contrary, grape polysaccharides are not commercially available, and the recovery of these compounds from grape by-products is nowadays a great challenge for the oenological research. These polysaccharides have a great potential in organoleptic finning since they have been reported to modulate the wine quality, as arabinogalactans which interacts with wine aroma compounds and increase their volatility (Ribeiro et al., 2014; Rinaldi et al., 2021).
In this study grape polysaccharide extracts obtained from different sources were used as finning agents at bottling in three wines from Vitis vinifera L. cv. Tempranillo and Graciano. Their effect on the volatile composition and profile was analyzed. Polysaccharides extracts were obtained from white pomace by-products (WP), red pomace by-products (RP), white must (WM), red must (RM), red wine (RW), and lees recovered after the winemaking (RL). Two more extracts with higher purification degrees were used (PE1 and PE2). The results were compared with a control (C) wine sample and with mannoproteins commercially available (CM).
The analysis of volatile compounds was performed using a GC-MS after a liquid-liquid extraction as described by Oliveira et al., 2006. Discriminant analyses were performed to differentiate the red wines by the fining extract used. WM, RM and CM wines were characterized by high contents of alcohols, C6 alcohols, some esters as ethyl isovalerate, acetates, acids, and terpenes. On the other hand, RW, RP, and RL wines were characterized by high contents of ethyl esters as ethyl lactate, ethyl hexanoate and ethyl octanoate, and volatile phenols, specially 4-vinylguaiacol and 4-ethylguaiacol. The wines treated with PE1 and PE2 were those which presented the lowest concentrations on most of the volatile compounds detected. Discriminant analyses showed that the use of the polysaccharide extracts modified the volatile composition of the wines.

Acknowledgements:

The authors would like to thank the Instituto Nacional de Investigación y Tecnología Agraria y Alimentaria (INIA) for the funding provided for this study through the project RTA2017-00005-C02-02.

References

Oliveira, J. M., Faria, M., Sá, F., Barros, F., & Araújo, I. M. (2006). C6-alcohols as varietal markers for assessment of wine origin. Analytica Chimica Acta, 563(1-2 SPEC. ISS.), 300–309. https://doi.org/10.1016/j.aca.2005.12.029
Rinaldi, A., Gonzalez, A., Moio, L., & Gambuti, A. (2021). Commercial mannoproteins improve the mouthfeel and colour of wines obtained by excessive tannin extraction. Molecules, 26(14). https://doi.org/10.3390/molecules26144133
Ribeiro, T., Fernandes, C., Nunes, F. M., Filipe-Ribeiro, L., & Cosme, F. (2014). Influence of the structural features of commercial mannoproteins in white wine protein stabilization and chemical and sensory properties. Food Chemistry, 159, 47–54. https://doi.org/10.1016/j.foodchem.2014.02.149

DOI:

Publication date: June 23, 2022

Issue: IVAS 2022

Type: Poster

Authors

Curiel-Fernández María1,2, Canalejo Diego1,2, Zhao Feng1,2, Martínez-Lapuente Leticia1,2, Ayestarán Belén1,2, Cano-Mozo Estela1,2, Pérez-Magariño Silvia1,2, Guadalupe Zenaida1,2

1Instituto Tecnológico Agrario de Castilla y León
2Consejería de Agricultura y Ganadería 

Contact the author

Keywords

By-product valorization, grape pomace, lees, organoleptic modulation, grape polysaccharides

Tags

IVAS 2022 | IVES Conference Series

Citation

Related articles…

Mesoclimate impact on Tannat in the Atlantic terroir of Uruguay

The study of climate is relevant as an element conditioning the typicity of a product, its quality and sustainability over the years. The grapevine development and growth and the final grape and wine composition are closely related to temperature, while climate components vary at mesoscale according to topography and/or proximity to large bodies of water. The objective of this work is to assess the mesoclimate of the Atlantic region of Uruguay and to determine the effect of topography and the ocean on temperature and consequently on Tannat grapevine behavior.

Climate projections over France wine-growing region and its potential impact on phenology

Climate change represents a major challenge for the French wine industry. Climatic conditions in French vineyards have already changed and will continue to evolve. One of the notable effects on grapevine is the advancing growing season. The aim of this study is to characterise the evolution of agroclimatic indicators (Huglin index, number of hot days, mean temperature, cumulative rainfall and number of rainy days during the growing season) at French wine-growing regions scale between 1980 and 2019 using gridded data (8 km resolution, SAFRAN) and for the middle of the 21th century (2046-2065) with 21 GCMs statistically debiased and downscaled at 8 km. A set of three phenological models were used to simulate the budburst (BRIN, Smoothed-Utah), flowering, veraison and theoretical maturity (GFV and GSR) stages for two grape varieties (Chardonnay and Cabernet-Sauvignon) over the whole period studied. All the French wine-growing regions show an increase in both temperatures during the growing season and Huglin index. This increase is accompanied by an advance in the simulated flowering (+3 to +9 days), veraison (+6 to +13 days) and theoretical maturity (+6 to +16 days) stages, which are more noticeable in the north-eastern part of France. The climate projections unanimously show, for all the GCMs considered, a clear increase in the Huglin index (+662 to 771 °C.days compared to the 1980-1999 period) and in the number of hot days (+5.6 to 22.6 days) in all the wine regions studied. Regarding rainfall, the expected evolution remains very uncertain due to the heterogeneity of the climates simulated by the 21 models. Only 4 regions out of 21 have a significant decrease in the number of rainy days during the growing season. The two budburst models show a strong divergence in the evolution of this stage with an average difference of 18 days between the two models on all grapevine regions. The theoretical maturity is the most impacted stage with a potential advance between 40 and 23 days according to wine-growing regions.

Mechanisms involved in the heating of the environment by the aerodynamic action of a wind machine to protect a vineyard against spring frost

One of the main consequences of global warming is the rise of the mean temperature. Thus, the heat summation by the plants begins sooner in the early spring, and by cumulating growing degree-days, phenological development tends to happen earlier. However, spring frost is still a recurrent phenomenon causing serious damages to buds and therefore, threatening the harvests of the winegrowers. The wind machine is a solution to protect fruit crops against spring frost that is increasingly used. It is composed of a 10-m mast with a blowing fan at its peak. By tapping into the strength of the nocturnal thermal inversion, it sweeps the crop by propelling warm air above to the ground. Thus, stratification is momentarily suppressed. Furthermore, the continuous action of the machine, alone or in synergy, or the addition of a heater allow the bud to be bathed in a warmer environment. Also, the punctual action of the tower’s warm gust reaches the bud directly at each rotation period. All these actions allow the bud to continuously warm up, but with different intensities and over a different period. Although there is evidence of the effectiveness of the wind machines, the thermal transfers involved in those mechanisms raise questions about their true nature. Field measurements based on ultrasonic anemometers and fast responding thermocouples complemented by laboratory measurements on a reduced scale model allow to characterize both the airflow produced by the wind machine and the local temperature in its vicinity. Those experiments were realized in the vineyard of Quincy, in the framework of the SICTAG project. In the future paper, we will detail the aeraulic characterization of the wind machine and the thermal effects resulting from it and we will focus on how the wind machine warms up the local atmosphere and enables to reduce the freezing risk.

Traditional agroforestry vineyards, sources of inspiration for the agroecological transition of viticulture

A unique “terroir” can be found in southern Bolivia, which combines the specific features of climate, topography and altitude of high valleys, with the management of grapevines staked on trees. It is one of the rare remnants of agroforestry viticulture. A survey was carried out among 29 grapegrowers in three valleys, to characterize the structure and management of these vineyards, and identify the services they expect from trees. Farms were small (2.2 ha on average) and 85% of vineyards were less than 1 ha. Viticulture was associated with vegetable, fruit and fodder production, sometimes in the same fields. Molle trees were found in all plots, together with one or two other native tree species. Traditional grapevine varieties such as Negra Criolla, Moscatel de Alejandría and Vicchoqueña were grown with a large range of densities from 1550 to 9500 vines ha-1. From 18 to 30% of them were staked on trees, with 1.2 to 4.9 vines per tree. The management of these vineyards (irrigation, fertilization and grapevine protection) was described, the most particular technical operation being the coordinated pruning of trees and grapevines. Three types of management could be identified in the three valleys. Grapegrowers had a clear idea of the ecosystem services they expected from trees in their vineyards. The main one was protection against climate hazards (hail, frost, flood). Then they expected benefits in terms of pest and disease control, improvement of soil fertility and resulting yield. At last, some producers claimed that tree-staking was quicker and cheaper than conventional trellising. It can be hypothesized then that agroforestry is a promising technique for the agroecological transition of viticulture. Its contribution to the “terroir” of the high valleys of southern Bolivia and its link with the specificities of the wines and spirits produced there remain to be explored.

Grapevine sugar concentration model in the Douro Superior, Portugal

Increasingly warm and dry climate conditions are challenging the viticulture and winemaking sector. Digital technologies and crop modelling bear the promise to provide practical answers to those challenges. As viticultural activities strongly depend on harvest date, its early prediction is particularly important, since the success of winemaking practices largely depends upon this key event, which should be based on an accurate and advanced plan of the annual cycle. Herein, we demonstrate the creation of modelling tools to assess grape ripeness, through sugar concentration monitoring. The study area, the Portuguese Côa valley wine region, represents an important terroir in the “Douro Superior” subregion. Two varieties (cv. Touriga Nacional and Touriga Franca) grown in five locations across the Côa Region were considered. Sugar accumulation in grapes, with concentrations between 170 and 230 g l-1, was used from 2014 to 2020 as an indicator of technological maturity conditioned by meteorological factors. The climatic time series were retrieved from the EU Copernicus Service, while sugar data were collected by a non-profit organization, ADVID, and by Sogrape, a leading wine company. The software for calibrating and validating this model framework was the Phenology Modeling Platform (PMP), version 5.5, using Sigmoid and growing degree-day (GDD) models for predictions. The performance was assessed through two metrics: Roots Mean Square Error (RMSE) and efficiency coefficient (EFF), while validation was undertaken using leave-one-out cross-validation. Our findings demonstrate that sugar content is mainly dependent on temperature and air humidity. The models achieved a performance of 0.65