IVAS 2022 banner
IVES 9 IVES Conference Series 9 IVAS 9 IVAS 2022 9 Kinetic investigations of the Gewürztraminer volatile organic compounds and color at different temperatures and pHs

Kinetic investigations of the Gewürztraminer volatile organic compounds and color at different temperatures and pHs

Abstract

Gewürztraminer is a well-known wine famous for its aroma profile, which is characterized by rose petals, cloves, lychees, and other tropical fruit notes. It is cultivated worldwide, including the Trentino Alto Adige region located in northern Italy, especially in the Tramin zone, and it has long been studied trying to understand what the most characterizing volatile aroma components are [1-4]. The terpenes (geraniol, cis rose oxide, citronellol, and linalool) are between the major responsible for the characteristic floral aroma of this cultivar’s grapes and wines. Throughout the winemaking and storage, acid-catalysed rearrangements take place producing cyclic and hydroxylated forms of the above terpenes, which generally have minor perception thresholds and so the wine’s floral aroma character decreases [5]. It has been demonstrated that the temperature and pH strongly influence these reactions, however their kinetics are not studied in detail.

The first aim of this work was to develop and validate a fast, modern, sensitive, selective, robust, and comprehensive protocol for the quantification of primary, secondary, and tertiary wine volatile compounds by using solid-phase extraction (SPE) cartridges for the sample preparation and a fast GC-MS/MS for analysis [1]. Second aim was to apply this protocol and study the kinetics of the reactions occurring on the Gewürztraminer wine volatile compounds during its storage at various temperatures and pHs. In parallel also
the colour of the wines was monitored by using the CIELAB method. The produced method gave us the possibility to measure 64 aroma compounds, with big importance in wine science, by using fewer organic solvents, having short chromatographic run, and increasing specificity and sensitivity due to the MRM MS-mode used.

The results of the second part of the study, demonstrated the behaviour of volatile aroma compounds, with their absolute concentrations. The investigated reactions included the degradation of the linear terpenes (linalool, geraniol, nerol, etc), the ethyl esters of fatty
acids and volatile phenols on the one hand; and the formation of the cyclic terpenes (1,4-cineole, 1,8-cineole, terpineol, etc), the norisoprenoids (e.g. TDN and safranal) and the diprotic organic acids esters on the other hand.

In conclusion, we developed a modern protocol for the analysis of the wine aroma compounds and we underlined some key characteristics that a winemaker should take in consideration in the Gewürztraminer production and aging/storage. 

References

1. Carlin, S.; Lotti, C.; Correggi, L.; Mattivi, F.; Arapitsas, P.; Vrhovsek, U. “Measurement of the effect of accelerated aging on the aromatic compounds of Gewürztraminer and Teroldego wines, using a new SPE-GC-MS /MS protocol” Metabolites 2022, 12(2), 180.
2. Versini, G. Sull’aroma Del Vino “Traminer Aromatico” o “Gewürztraminer.” VIGNEVINI 1985, 12, 57–65.
3. Guth, H. Identification of Character Impact Odorants of Different White Wine Varieties. J. Agric. Food Chem. 1997, 45, 3022–3026. 
4. Román, T.; Tonidandel, T.; Larcher, R.; Celotti, E.; Nicolini, G. Importance of Polyfunctional Thiols on Semi-Industrial Gewürztraminer Wines and the Correlation to Technological Treatments. Eur. Food Res. Technol. 2018, 244, 379–386. 
5. Slaghenaufi, D.; Ugliano, M. “Norisoprenoids, Sesquiterpenes and Terpenoids Content of Valpolicella Wines During Aging: Investigating Aroma Potential in Relationship to Evolution of Tobacco and Balsamic Aroma in Aged Wine.” Front. Chem. 2018, 6.

DOI:

Publication date: June 23, 2022

Issue: IVAS 2022

Type: Article

Authors

Carlin Silvia1, Lotti Cesare1, Rapaccioli Attilio1, Mattivi, Fulvio1,2, Trenti Gianmaria3, Vrhovsek Urska1 and Arapitsas Panagiotis1,4

1Metabolomics Unit, Research and Innovation Centre Edmund Mach Foundation, Via Edmund Mach 1, 38010 San Michele all’ Adige, Italy
2Department of Cellular Computational and Integrative Biology, University of Trento, Via Sommarive 9, 38123 Povo, Trento, Italy
3Winery, Edmund Mach Foundation, Via Edmund Mach 1, 38010 San Michele all’Adige, Italy
4Department of Wine, Vine and Beverage Sciences, School of Food Science, University of West Attica, Ag. Spyridonos str, Egaleo, 12243 Athens, Greece.

Contact the author

Keywords

fastGC, accelerated aging, storage, terpenes, Cielab

Tags

IVAS 2022 | IVES Conference Series

Citation

Related articles…

Exploring resilience and competitiveness of wine estates in Languedoc-Roussillon in the recent past: a multi-level perspective

The Languedoc-Roussillon wineries are facing a decline in wine yields particularly PGI yields due to many factors. Climate change is just ones, but is expected to increase in the future. There is also structurally a large heterogeneity of yield profiles among terroirs, varieties and strategies. This work investigates the link between yield, competitiveness and resilience to explore how resilient winegrowers have been in the recent past. To this end two approaches have been combined; (i) an accountancy database analysis at estate scale and (ii) municipality level competitiveness analysis. A new resilience indicator that characterizes the capacity of an estate to absorb yield variation is also defined. The FADN database between 2000 and 2018 of ex-Languedoc-Roussillon (France) and other data are used to analyse the current situation and the past evolution of competitiveness and resilience by type of estate (type of farm: PGI and/or PDO & type of commercialization: bulk and/or bottles). The net margin, which defines competitiveness, is not correlated to yield for all types but depends on the type of commercialization and the level of specialisation. The resilience indicator shows that the net margin of estates specialized in PGI is particularly sensitive to yield declines. We also show that price evolutions seem to compensate the effect of yield losses for the majority of types. Municipality scale analysis shows the links between local pedoclimate, yield, commercialization strategies and price. Overlapping a PDO with a PGI does not always increase a municipality’s PGI competitiveness. It is difficult to make links between causes and effects due to the complexity of the wine production system. Production diversification may be a solution. Resorting to the two level of analysis helps resolving the data gap that is necessary to explore the links between yield and economic performance of the wine estates in the long term.

Climate ethnography and wine environmental futures

Globalisation and climate change have radically transformed world wine production upsetting the established order of wine ecologies. Ecological risks and the future of traditional agricultural systems are widely debated in anthropology, but very little is understood of the particular challenges posed by climate change to viticulture which is seen by many as the canary in the coalmine of global agriculture. Moreover, wine as a globalised embedded commodity provides a particularly telling example for the study of climate change having already attracted early scientific attention. Studies of climate change in viticulture have focused primarily on the production of systematic models of adaptation and vulnerability, while the human and cultural factors, which are key to adaptation and sustainable futures, are largely missing. Climate experts have been unanimous in recognising the urgent need for a better understanding of the complex dynamics that shape how climate change is experienced and responded to by human systems. Yet this call has not yet been addressed. Climate ethnography, coined by the anthropologist Susan Crate (2011), aims to bridge this growing disjuncture between climate science and everyday life through the exploration of the social meaning of climate change. It seeks to investigate the confrontation of its social salience in different locations and under different environmental guises (Goodman 2018: 340). By understanding how wine producers make sense of the world (and the environment) and act in it, it proposes to focus on the co-production of interdisciplinary knowledge by identifying and foreshadowing problems (Goodman 2018: 342; Goodman & Marshall 2018). It seeks to offer an original, transformative and contrasted perspective to climate change scenarios by investigating human agency -individual or collective- in all its social, political and cultural diversity. An anthropological approach founded on detailed ethnographies of wine production is ideally placed to address economic, social and cultural disruptions caused by the emergence of these new environmental challenges. Indeed, the community of experts in environmental change have recently called for research that will encompass the human dimension and for more broad-based, integrated through interdisciplinarity, useful knowledge (Castree & al 2014). My paper seeks to engage with climate ethnography and discuss what it brings to the study of wine environmental futures while exploring the limitations of the anthropological environmental approach.

Climate, Viticulture, and Wine … my how things have changed!

The planet is warmer than at any time in our recorded past and increasing greenhouse emissions and persistence in the climate system means that continued warming is highly likely. Climate change has already altered the basic framework of growing grapes for wine production worldwide and will likely continue to do so for years to come. The wine sector can continue to play an important role in leading the agricultural sector in addressing climate change. From developing on…

Adaptability of grapevines to climate change: characterization of phenology and sugar accumulation of 50 varieties, under hot climate conditions

Climate is the major factor influencing the dynamics of the vegetative cycle and can determine the timing of phenological periods. Knowledge of the phenology of varieties, their chronological duration, and thermal requirements, allows not only for the better management of interventions in the vineyard, but also to predict the varieties’ behaviour in a scenario of climate change, giving the wine producer the possibility of selecting the grape varieties that are best adapted to the climatic conditions of a certain terroir. In 2014, Symington Family Estates, Vinhos, established two grape variety libraries in two different places with distinctive climate conditions (Douro Superior, and Cima Corgo), with the commitment of contributing to a deeper agronomic and oenological understanding of some grape varieties, in hot climate conditions. In these research vineyards are represented local varieties that are important in the regional and national viticulture, but also others that have over time been forgotten — as well as five international reference cultivars. From 2017 to 2021, phenological observations have been made three times a week, following a defined protocol, to determine the average dates of budbreak, flowering and veraison. With the climate data of each location, the thermal requirements of each variety and the chronological duration of each phase have been calculated. During maturation, berry samples have been gathered weekly to study the dynamics of sugar accumulation, between other parameters. The data was analysed applying phenological and sugar accumulation models available in literature. The results obtained show significant differences between the varieties over several parameters, from the chronological duration and thermal requirements to complete the various stages of development, to the differences between the two locations, confirming the influence of the climate on phenology and the stages of maturation, in these specific conditions.

Effect of vigour and number of clusters on eonological parameters and metabolic profile of Cabernet Sauvignon red wines

Vegetative growth and yield are reported to affect grape and wine quality. They can be controlled through different techniques linked to vine management. The objective of this research was to determine the effect of vine vigour and number of clusters per vine on physicochemical composition and phenolic profile of red wines. The experiment was carried out during two vegetative cycles, with cv. Cabernet Sauvignon grafted onto Paulsen 1103. Three vine vigour were defined, according to shoot weight at previous harvests, being low, medium and high. Five treatments of number of clusters were used for each vigour, with 15, 22, 29, 36, and 45 clusters per vine. Grapes from all treatments were harvested in the same day from Brix and total acidity criteria. Thirty days after bottling, classical analyzes and phenolic compounds were performed. As results, different responses were obtained from each vintage. In 2020, a dry season from veraison to harvest, grapes and wines obtained from low vigour treatment and 45 clusters per vine was the highest in sugar and alcohol content respectively, while grapes and wines from high vigour and 15 clusters presented the lowest sugar and alcohol content. Total anthocyanins were higher in treatment with low vigour and 15 clusters, while the lowest amounts were found in low vigour with 45 clusters, as well as medium and high vigour with 36 clusters per vine. Total tannins were higher in high vigour with 22 clusters and medium vigour with 29 clusters, while were lower in low vigour with 36 clusters. In 2021, a wet season at harvest, responses were different, and great variations were observed between treatments. As conclusions, yield and vine vigour had strong influence on grape and wine quality, promoting different enological potentials on which can be indicated/used for aging strategies of red and even rosé wines.