GiESCO 2019 banner
IVES 9 IVES Conference Series 9 GiESCO 9 Analysis of primary, secondary and tertiary aromas in Vitis vinifera L. Syrah wines with an extemporaneous production cycle in two regions of São Paulo – Brazil, using GC-MS

Analysis of primary, secondary and tertiary aromas in Vitis vinifera L. Syrah wines with an extemporaneous production cycle in two regions of São Paulo – Brazil, using GC-MS

Abstract

Context and purpose of the study – The aromatic perception is one of the main factors that influence the consumer when determining the wine’s quality and acceptance. Numerous factors (soil, climate, winemaking style, cultivar) can influence the volatile compounds. Some of these compounds are released directly from the grape berries while others are formed during the fermentation and aging processes. However, little is known about the quality and aromatic formation of Syrah variety in the winter cycle cultivated in São Paulo. This study aimed to characterize the primary (originated from the grape), secondary (fermentation) and tertiary aromas (evolution) of these wines, showing the wine potential from new producing regions in São Paulo state.

Material and methods – The microvinifications were made using the traditional method. The Syrah variety (clone 174 ENTAV – INRA ® on rootstock 1103P – clone 768 ENTAV – INRA ®) was conducted in double cordon VSP system, with winter harvest in Indaiatuba (low altitude and hot climate) and São Bento do Sapucaí (high altitude and cold) – Brazil. The analyses of volatile compounds were carried out in the main stages of the vinification process (must extraction, after alcoholic fermentation, after malolatic fermentation, before packaging and after 6 months in bottle). The samples were collected and frozen at -80 ° C until analysis. An Agilent 7890 GC system coupled to 5977 MS detector equipped with a Supelcowax column (30m x 0.25mm x 0.25μm film thickness) was used.

Results – Vines from the Indaiatuba region presented an average production of 7 bunches per plant. The bunches showed average weight of 76.5 g and size of 10.9 cm. Berries had 11 mm diameter and weighed 1.5 g. Must presented total soluble solids of 20ºBrix, total acidity of 105 meq.L-1, pH 3 and 1084 density. 24 primary aromas were found, such as lavender and apricot, 42 secondary aromas such as cooked apple and roses, and 17 tertiary aromas such as butter and honey. The vines of São Bento do Sapucaí presented an average of 9 bunches per plant. Bunches with an average weight of 101.8 g and length of 13 cm. Berries had a diameter of 12.5 mm and a weight of 1.5 g. Must presented total soluble solids of 21.5ºBrix, total acidity of 100 meq.L-1, pH 3 and 1090 density. The must had 29 primary aromas, such as mint and pear, 36 secondary aromas, such as honey and rose-orange, and 20 tertiary aromas such as wintergreen and mint.

DOI:

Publication date: September 27, 2023

Issue: GiESCO 2019

Type: Poster

Authors

Lucas AMARAL1,2*, Luísa TANNURE3, Marite DAL’OSTO3, Florença BORGES1,2 and Eduardo PURGATTO1,2

1 Dept. of Food Science and Exp. Nutrition, School of Pharmaceutical Sciences USP– 05508-000 São Paulo –Brazil
2 Food Research Center (FoRC), CEPID-FAPESP – USP– 05508-000 São Paulo – Brazil
3 Instituto Federal de São Paulo- IFSP – 18145-090, São Paulo – Brazil

Contact the author

Keywords

grapevine, Syrah, grapevine cycle modification, aroma, cromatography, Brazil

Tags

GiESCO | GiESCO 2019 | IVES Conference Series

Citation

Related articles…

Under-vine management effects on grapevine production, soil properties and plant communities in South Australia

Under-vine (UV) management has traditionally consisted of synthetic herbicide use to limit competition between weeds and grapevines. With growing global interest towards non-synthetic chemical use, this study aimed to capture the effects of alternative UV management at two commercial Shiraz vineyards in South Australia, where the sole management variables were UV management since 2016. In adjacent treatment blocks, cultivation (CU) was compared to spontaneous vegetation (SV) in McLaren Vale (MV), and herbicide was compared to SV in Eden Valley (EV). Soil water infiltration rates were slower and grapevine stem water potential was lower in CU compared to SV in MV, with the latter having a plant community dominated by soursob (Oxalis pes-caprae) during winter; while in EV, there was little separation between the treatments. Yields were affected at both sites, with SV being higher in MV and HE being higher in EV. In MV, the only effect on grape must was a lower 13C:12C isotope ratio in CU, indicating greater grapevine water stress. In the grape must at EV, SV had higher total soluble solids, total phenolics, anthocyanins, and yeast available nitrogen; and lower pH and titratable acidity. Pruning weights were not affected by the treatments in MV, while they were higher in HE at EV. Assessments revealed that the differing soil types at the two sites were likely the main determinants of the opposing production outcomes associated with UV management. In the silty loam soil of MV, the higher yields in SV were likely due to more plant-available water, as a potential result of the continuous soil bio-pores formed by winter UV vegetation. Conversely, in the loamy sand soils of EV with a lower cation exchange capacity, the lower yields and pruning weights in SV suggest the UV vegetation competed significantly with the grapevines for available water and nutrients.

Bioclimatic shifts and land use options for Viticulture in Portugal

Land use, plays a relevant role in the climatic system. It endows means for agriculture practices thus contributing to the food supply. Since climate and land are closely intertwined through multiple interface processes, climate change may lead to significant impacts in land use. In this study, 1-km observational gridded datasets are used to assess changes in the Köppen–Geiger and Worldwide Bioclimatic (WBCS)

Anthocyanin profile is differentially affected by high temperature, elevated CO2 and water deficit in Tempranillo (Vitis vinifera L.) clones

Anthocyanin potential of grape berries is an important quality factor in wine production. Anthocyanin concentration and profile differ among varieties but it also depends on the environmental conditions, which are expected to be greatly modified by climate change in the future. These modifications may significantly modify the biochemical composition of berries at harvest, and thus wine typicity. Among the diverse approaches proposed to reduce the potential negative effects that climate change may have on grape quality, genetic diversity among clones can represent a source of potential candidates to select better adapted plant material for future climatic conditions. The effects of individual and combined factors associated to climate change (increase of temperature, rise of air CO2 concentration and water deficit) on the anthocyanin profile of different clones of Tempranillo that differ in the length of their reproductive cycle were studied. The aim was to highlight those clones more adapted to maintain specific Tempranillo typicity in the future. Fruit-bearing cuttings were grown in controlled conditions under two temperatures (ambient temperature versus ambient temperature + 4ºC), two CO2 levels (400 ppm versus 700 ppm) and two water regimes (well-watered versus water deficit), both in combination or independently, in order to simulate future climate change scenarios. Elevated temperature increased anthocyanin acylation, whereas elevated CO2 and water deficit favoured the accumulation of malvidin derivatives, as well as the acylation and tri-hydroxylation level of anthocyanins. Although the changes in anthocyanin profile observed followed a common pattern among clones, such impact of environmental conditions was especially noticeable in one of the most widely distributed Tempranillo clones, the accession RJ43.

Low-cost sensors as a support tool to monitor soil-plant heat exchanges in a Mediterranean vineyard

Mediterranean viticulture is increasingly exposed to more frequent extreme conditions such as heat waves. These extreme events co-occur with low soil water content, high air vapor pressure deficit and high solar radiant energy fluxes and result in leaf and berry sunburn, lower yield, and berry quality, which is a major constraint for the sustainability of the sector. Grape growers must find ways to proper and effectively manage heat waves and extreme canopy and berry temperatures. Irrigation to keep soil moisture levels and enable adequate plant turgor, and convective and evaporative cooling emerged as a key tool to overcome this major challenge. The effects of irrigation on soil and plant water status are easily quantifiable but the impact of irrigation on soil and canopy temperature and on heat convection from soil to cluster zone remain less characterized. Therefore, a more detailed quantification of vineyard heat fluxes is highly relevant to better understand and implement strategies to limit the effects of extreme weather events on grapevine leaf and berry physiology and vineyards performance. Low-cost sensor technologies emerge as an opportunity to improve monitoring and support decision making in viticulture. However, validation of low-cost sensors is mandatory for practical applicability. A two-year study was carried in a vineyard in Alentejo, south of Portugal, using low-cost thermal cameras (FLIR One, 80×60 pixels and FLIR C5, 160×120 pixels, 8-14 µm, FLIR systems, USA) and pocket thermohygrometers (Extech RHT30, EXTECH instruments, USA) to monitor grapevine and soil temperatures. Preliminary results show that low-cost cameras can detect severe water stress and support the evaluation of vertical canopy temperature variability, providing information on soil surface temperature. All these thermal parameters can be relevant for soil and crop management and be used in decision support systems.

Grapevine sugar concentration model in the Douro Superior, Portugal

Increasingly warm and dry climate conditions are challenging the viticulture and winemaking sector. Digital technologies and crop modelling bear the promise to provide practical answers to those challenges. As viticultural activities strongly depend on harvest date, its early prediction is particularly important, since the success of winemaking practices largely depends upon this key event, which should be based on an accurate and advanced plan of the annual cycle. Herein, we demonstrate the creation of modelling tools to assess grape ripeness, through sugar concentration monitoring. The study area, the Portuguese Côa valley wine region, represents an important terroir in the “Douro Superior” subregion. Two varieties (cv. Touriga Nacional and Touriga Franca) grown in five locations across the Côa Region were considered. Sugar accumulation in grapes, with concentrations between 170 and 230 g l-1, was used from 2014 to 2020 as an indicator of technological maturity conditioned by meteorological factors. The climatic time series were retrieved from the EU Copernicus Service, while sugar data were collected by a non-profit organization, ADVID, and by Sogrape, a leading wine company. The software for calibrating and validating this model framework was the Phenology Modeling Platform (PMP), version 5.5, using Sigmoid and growing degree-day (GDD) models for predictions. The performance was assessed through two metrics: Roots Mean Square Error (RMSE) and efficiency coefficient (EFF), while validation was undertaken using leave-one-out cross-validation. Our findings demonstrate that sugar content is mainly dependent on temperature and air humidity. The models achieved a performance of 0.65