GiESCO 2019 banner
IVES 9 IVES Conference Series 9 GiESCO 9 Analysis of primary, secondary and tertiary aromas in Vitis vinifera L. Syrah wines with an extemporaneous production cycle in two regions of São Paulo – Brazil, using GC-MS

Analysis of primary, secondary and tertiary aromas in Vitis vinifera L. Syrah wines with an extemporaneous production cycle in two regions of São Paulo – Brazil, using GC-MS

Abstract

Context and purpose of the study – The aromatic perception is one of the main factors that influence the consumer when determining the wine’s quality and acceptance. Numerous factors (soil, climate, winemaking style, cultivar) can influence the volatile compounds. Some of these compounds are released directly from the grape berries while others are formed during the fermentation and aging processes. However, little is known about the quality and aromatic formation of Syrah variety in the winter cycle cultivated in São Paulo. This study aimed to characterize the primary (originated from the grape), secondary (fermentation) and tertiary aromas (evolution) of these wines, showing the wine potential from new producing regions in São Paulo state.

Material and methods – The microvinifications were made using the traditional method. The Syrah variety (clone 174 ENTAV – INRA ® on rootstock 1103P – clone 768 ENTAV – INRA ®) was conducted in double cordon VSP system, with winter harvest in Indaiatuba (low altitude and hot climate) and São Bento do Sapucaí (high altitude and cold) – Brazil. The analyses of volatile compounds were carried out in the main stages of the vinification process (must extraction, after alcoholic fermentation, after malolatic fermentation, before packaging and after 6 months in bottle). The samples were collected and frozen at -80 ° C until analysis. An Agilent 7890 GC system coupled to 5977 MS detector equipped with a Supelcowax column (30m x 0.25mm x 0.25μm film thickness) was used.

Results – Vines from the Indaiatuba region presented an average production of 7 bunches per plant. The bunches showed average weight of 76.5 g and size of 10.9 cm. Berries had 11 mm diameter and weighed 1.5 g. Must presented total soluble solids of 20ºBrix, total acidity of 105 meq.L-1, pH 3 and 1084 density. 24 primary aromas were found, such as lavender and apricot, 42 secondary aromas such as cooked apple and roses, and 17 tertiary aromas such as butter and honey. The vines of São Bento do Sapucaí presented an average of 9 bunches per plant. Bunches with an average weight of 101.8 g and length of 13 cm. Berries had a diameter of 12.5 mm and a weight of 1.5 g. Must presented total soluble solids of 21.5ºBrix, total acidity of 100 meq.L-1, pH 3 and 1090 density. The must had 29 primary aromas, such as mint and pear, 36 secondary aromas, such as honey and rose-orange, and 20 tertiary aromas such as wintergreen and mint.

DOI:

Publication date: September 27, 2023

Issue: GiESCO 2019

Type: Poster

Authors

Lucas AMARAL1,2*, Luísa TANNURE3, Marite DAL’OSTO3, Florença BORGES1,2 and Eduardo PURGATTO1,2

1 Dept. of Food Science and Exp. Nutrition, School of Pharmaceutical Sciences USP– 05508-000 São Paulo –Brazil
2 Food Research Center (FoRC), CEPID-FAPESP – USP– 05508-000 São Paulo – Brazil
3 Instituto Federal de São Paulo- IFSP – 18145-090, São Paulo – Brazil

Contact the author

Keywords

grapevine, Syrah, grapevine cycle modification, aroma, cromatography, Brazil

Tags

GiESCO | GiESCO 2019 | IVES Conference Series

Citation

Related articles…

Photoselective shade films affect grapevine berry secondary metabolism and wine composition

Grapevine physiology and production are challenged by forecasted increases in temperature and water deficits. Within this scenario, photoselective overhead shade films are promising tools in warm viticulture areas to overcome climate change related factors. The aim of this study was to evaluate the vulnerability of ‘Cabernet Sauvignon’ grape berry to solar radiation overexposure and optimize shade film use for berry integrity. A randomized complete block design field study was conducted across two years (2020-2021) in Oakville, Napa Valley, CA, with four shade films (D1, D3, D4, D5) differing in the percent of radiation spectra transmitted and compared to an uncovered control (C0). Integrals for gas exchange parameters and mid-day stem water potential were unaffected by the shade films in 2020 and 2021. By harvest, berries from uncovered and shaded vines did not differ in their size or primary metabolism in either year. Despite precipitation exclusion during the dormant season in the shaded treatments, yield did not differ between them and the control in either season. In 2020, total skin anthocyanins (mg/g fresh mass) in the shaded treatments was greater than C0 during berry ripening and at harvest. Conversely, flavonol concentrations in 2020 were reduced in shaded vines compared to C0. The 2020 growing season highlighted the impact of heat degradation on flavonoids. Flavonoid concentrations in 2021 increased until harvest while flavonoid degradation was apparent from veraison to harvest in 2020 across shaded and control vines. Wine analyses highlighted the importance of light spectra to modify wine composition. Wine color intensity, tonality and anthocyanin values were enhanced in D4 whereas antioxidant properties were enhanced in C0 and D5 wines. Altogether, our results highlighted the need of new approaches in warm viticulture areas given the impact that composition of light has on berry and wine quality.

Anthocyanin profile is differentially affected by high temperature, elevated CO2 and water deficit in Tempranillo (Vitis vinifera L.) clones

Anthocyanin potential of grape berries is an important quality factor in wine production. Anthocyanin concentration and profile differ among varieties but it also depends on the environmental conditions, which are expected to be greatly modified by climate change in the future. These modifications may significantly modify the biochemical composition of berries at harvest, and thus wine typicity. Among the diverse approaches proposed to reduce the potential negative effects that climate change may have on grape quality, genetic diversity among clones can represent a source of potential candidates to select better adapted plant material for future climatic conditions. The effects of individual and combined factors associated to climate change (increase of temperature, rise of air CO2 concentration and water deficit) on the anthocyanin profile of different clones of Tempranillo that differ in the length of their reproductive cycle were studied. The aim was to highlight those clones more adapted to maintain specific Tempranillo typicity in the future. Fruit-bearing cuttings were grown in controlled conditions under two temperatures (ambient temperature versus ambient temperature + 4ºC), two CO2 levels (400 ppm versus 700 ppm) and two water regimes (well-watered versus water deficit), both in combination or independently, in order to simulate future climate change scenarios. Elevated temperature increased anthocyanin acylation, whereas elevated CO2 and water deficit favoured the accumulation of malvidin derivatives, as well as the acylation and tri-hydroxylation level of anthocyanins. Although the changes in anthocyanin profile observed followed a common pattern among clones, such impact of environmental conditions was especially noticeable in one of the most widely distributed Tempranillo clones, the accession RJ43.

Different soil types and relief influence the quality of Merlot grapes in a relatively small area in the Vipava Valley (Slovenia) in relation to the vine water status

Besides location and microclimatic conditions, soil plays an important role in the quality of grapes and wine. Soil properties influence…

Frost risk projections in a changing climate are highly sensitive in time and space to frost modelling approaches

Late spring frost is a major challenge for various winegrowing regions across the world, its occurrence often leading to important yield losses and/or plant failure. Despite a significant increase in minimum temperatures worldwide, the spatial and temporal evolution of spring frost risk under a warmer climate remains largely uncertain. Recent projections of spring frost risk for viticulture in Europe throughout the 21st century show that its evolution strongly depends on the model approach used to simulate budburst. Furthermore, the frost damage modelling methods used in these projections are usually not assessed through comparison to field observations and/or frost damage reports.
The present study aims at comparing frost risk projections simulated using six spring frost models based on two approaches: a) models considering a fixed damage threshold after the predicted budburst date (e.g BRIN, Smoothed-Utah, Growing Degree Days, Fenovitis) and b) models considering a dynamic frost sensitivity threshold based on the predicted grapevine winter/spring dehardening process (e.g. Ferguson model). The capability of each model to simulate an actual frost event for the Vitis vinifera cv. Chadonnay B was previously assessed by comparing simulated cold thermal stress to reports of events with frost damage in Chablis, the northernmost winegrowing region of Burgundy. Models exhibited scores of κ > 0.65 when reproducing the frost/non-frost damage years and an accuracy ranging from 0.82 to 0.90.
Spring frost risk projections throughout the 21st century were performed for all winegrowing subregions of Bourgogne-Franche-Comté under two CMIP5 concentration pathways (4.5 and 8.5) using statistically downscaled 8×8 km daily air temperature and humidity of 13 climate models. Contrasting results with region-specific spring frost risk trends were observed. Three out of five models show a decrease in the frequency of frost years across the whole study area while the other two show an increase that is more or less pronounced depending on winegrowing subregion. Our findings indicate that the lack of accuracy in grapevine budburst and dehardening models makes climate projections of spring frost risk highly uncertain for grapevine cultivation regions.

A spatial explicit inventory of EU wine protected designation of origin to support decision making in a changing climate

Winemaking areas recognized as protected designations of origin (PDOs) shape important economic, environmental and cultural values that are tied to closely defined geographic locations. To preserve wine products and wine-growing practices adopted in different PDOs these areas are strictly regulated by legal specifications. However, quality viticulture is increasingly under pressure from climate change, which is altering the local conditions of many winegrowing areas. Therefore, maintaining traditional wine products will require the adoption of tailored adaptation strategies, including possible changes in the legal regulation of protected wines. To this end, it is necessary to have a comprehensive knowledge on PDOs including their extension, products and allowed practices. While there have been efforts to build databases that summarize the characteristics for individual wine PDO areas and to quantify the related effects of climate change, much information is still included only in the official documentation of the EU geographical indication register and has never been collected in a comprehensive manner. With this study we aim at filling this gap by building a spatial inventory of European wine PDOs that supports decision making in viticulture in the context of climate change. To map and characterize European wine PDOs, we analysed their legal documents and extracted relevant information useful for climate change adaptation. The output consists of a comprehensive geographical dataset that identifies the boundaries of all 1200 European wine PDOs at unprecedented spatial resolution and includes a set of legally binding regulations, such as authorized vine varieties, maximum yields and planting density. The inventory will allow researchers to analyse the impacts of climate change on European wine PDOs and support decision makers in developing tailored adaptation strategies. This includes, among others, the evaluation of new vineyard site selection, the expansion of cultivated varieties or the authorization of irrigation in vineyards.