OENO IVAS 2019 banner
IVES 9 IVES Conference Series 9 OENO IVAS 9 OENO IVAS 2019 9 Analysis and composition of grapes, wines, wine spirits 9 Hplc-ms analysis of carotenoids as potential precursors for 1,1,6-trimethyl-1,2-dihydronaphthalene (TDN) in riesling grapes

Hplc-ms analysis of carotenoids as potential precursors for 1,1,6-trimethyl-1,2-dihydronaphthalene (TDN) in riesling grapes

Abstract

In recent years, an undesirable premature “aged” character has been noticed in a growing number of young Riesling wines, associated with extreme weather conditions leading to increased radiation intensity and/ or sun exposure of grapes. One of the compounds responsible for rapid aging is 1,1,6-trimethyl-1,2-dihydronaphthalene (TDN), a grape derived C13-norisoprenoid formed as biodegradation product of carotenoids that participate in light harvesting and are essential for photoprotection against excess light in the blue and green wavelength region (350–550 nm). 

Our interest in carotenoids as aroma precursors led us to examine the effect of qualitative light manipulation in the vineyard by coloured shade cloth (green, red and black) on carotenoid profile and accumulation in grapes during the ripening season. Through wavelength modulation of the radiation reaching the vines and therefore regulate the key absorbance maxima of the carotenoids, it was possible to reduce TDN concentrations in finished wines. 

This presentation describes HPLC-MS analysis of carotenoids in grapes and will focus on selected carotenoids potentially associated with the formation of TDN.

DOI:

Publication date: June 10, 2020

Issue: OENO IVAS 2019

Type: Article

Authors

Yevgeniya Grebneva, Josh Hixson, Kathrin Vollmer, Cory Black, Markus Herderich

The Australian Wine Research Institute PO Box 197 Glen Osmond SA 5064, Australia

Contact the author

Keywords

Carotenoids, TDN, Riesling, HPLC-MS 

Tags

IVES Conference Series | OENO IVAS 2019

Citation

Related articles…

Effect of the shade generated by simulated solar panels in two row orientation on the physiology and productivity of Vitis vinifera L. cv. Malbec

Context and purpose of the study. In regions where grapevines are grown under irrigation, like most regions in Argentina, the wine industry should adopt more sustainable strategies and production systems towards a higher water use efficiency and a reduction in no-renewable energy consumption.

The informative potential of remote and proximal sensing application on vertical- and overhead-trained vineyards in Northeast Italy

The application of remote and proximal sensing in viticulture have been demonstrated as a fast and efficient method to monitor vegetative and physiological parameters of grapevines. The collection of these parameters could be highly valuable to derive information on associated yield and quality traits in the vineyard. However, to leverage the informative potential of the sensing systems, a series of preliminary evaluations should be carried out to standardize working protocols for the specific features of a winegrowing area (e.g., pedoclimate, topography, cultivar, training system). This work aims at evaluating remote and proximal sensing systems for their performance and suitability to provide information on the vegetative, physiological, yield and qualitative aspects of vines and grapes as a function of different training systems in the Valpolicella wine region (Verona, Italy).

Evaluation of new fem grapevine varieties resistant to the main fungal diseases

Context and purpose of the study. The genetic improvement of grapevines at the Edmund Mach Foundation (FEM) has evolved significantly since its inception, and its philosophy on sustainable viticulture through crossbreeding techniques aligns with the urgent need to reduce chemical use in agriculture.

Effect of vigour and number of clusters on eonological parameters and metabolic profile of Cabernet Sauvignon red wines

Vegetative growth and yield are reported to affect grape and wine quality. They can be controlled through different techniques linked to vine management. The objective of this research was to determine the effect of vine vigour and number of clusters per vine on physicochemical composition and phenolic profile of red wines. The experiment was carried out during two vegetative cycles, with cv. Cabernet Sauvignon grafted onto Paulsen 1103. Three vine vigour were defined, according to shoot weight at previous harvests, being low, medium and high. Five treatments of number of clusters were used for each vigour, with 15, 22, 29, 36, and 45 clusters per vine. Grapes from all treatments were harvested in the same day from Brix and total acidity criteria. Thirty days after bottling, classical analyzes and phenolic compounds were performed. As results, different responses were obtained from each vintage. In 2020, a dry season from veraison to harvest, grapes and wines obtained from low vigour treatment and 45 clusters per vine was the highest in sugar and alcohol content respectively, while grapes and wines from high vigour and 15 clusters presented the lowest sugar and alcohol content. Total anthocyanins were higher in treatment with low vigour and 15 clusters, while the lowest amounts were found in low vigour with 45 clusters, as well as medium and high vigour with 36 clusters per vine. Total tannins were higher in high vigour with 22 clusters and medium vigour with 29 clusters, while were lower in low vigour with 36 clusters. In 2021, a wet season at harvest, responses were different, and great variations were observed between treatments. As conclusions, yield and vine vigour had strong influence on grape and wine quality, promoting different enological potentials on which can be indicated/used for aging strategies of red and even rosé wines.

HPLC-based quantification of elemental sulfur in grape juice

Elemental sulfur is commonly used in vineyards as a fungicide to prevent diseases and protect grapevines.1 The challenges of climate change are intensifying disease pressure, further increasing the reliance on sulfur use. Understanding the range of potential impacts of residual sulfur during the winemaking process is becoming increasingly important.