OENO IVAS 2019 banner
IVES 9 IVES Conference Series 9 OENO IVAS 9 OENO IVAS 2019 9 Analysis and composition of grapes, wines, wine spirits 9 Hplc-ms analysis of carotenoids as potential precursors for 1,1,6-trimethyl-1,2-dihydronaphthalene (TDN) in riesling grapes

Hplc-ms analysis of carotenoids as potential precursors for 1,1,6-trimethyl-1,2-dihydronaphthalene (TDN) in riesling grapes

Abstract

In recent years, an undesirable premature “aged” character has been noticed in a growing number of young Riesling wines, associated with extreme weather conditions leading to increased radiation intensity and/ or sun exposure of grapes. One of the compounds responsible for rapid aging is 1,1,6-trimethyl-1,2-dihydronaphthalene (TDN), a grape derived C13-norisoprenoid formed as biodegradation product of carotenoids that participate in light harvesting and are essential for photoprotection against excess light in the blue and green wavelength region (350–550 nm). 

Our interest in carotenoids as aroma precursors led us to examine the effect of qualitative light manipulation in the vineyard by coloured shade cloth (green, red and black) on carotenoid profile and accumulation in grapes during the ripening season. Through wavelength modulation of the radiation reaching the vines and therefore regulate the key absorbance maxima of the carotenoids, it was possible to reduce TDN concentrations in finished wines. 

This presentation describes HPLC-MS analysis of carotenoids in grapes and will focus on selected carotenoids potentially associated with the formation of TDN.

DOI:

Publication date: June 10, 2020

Issue: OENO IVAS 2019

Type: Article

Authors

Yevgeniya Grebneva, Josh Hixson, Kathrin Vollmer, Cory Black, Markus Herderich

The Australian Wine Research Institute PO Box 197 Glen Osmond SA 5064, Australia

Contact the author

Keywords

Carotenoids, TDN, Riesling, HPLC-MS 

Tags

IVES Conference Series | OENO IVAS 2019

Citation

Related articles…

Is complex nutrition more advantageous than mineral nitrogen for the fermentative capacities of S. cerevisiae?

During alcoholic fermentation, nitrogen is an essential nutrient for yeast as it plays a key role in sugar transport and biosynthesis of wine aromatic compounds (thiols, esters, higher alcohols). The main issue of a lack in yeast assimilable nitrogen (yan) in winemaking is sluggish or stuck fermentations promoting the growth of alteration species which may lead to economic losses. However, correcting this nitrogen deficiency is sometimes not enough to restore proper fermentation performance. This suggests the existence of other nutritional shortages.

Caracterización de las tierras de viña de Navarra

Este programa se enmarca dentro de las líneas de trabajo del Departamento de Agricultura, Ganadería y Alimentación del Gobiemo de Navarra y su objetivo general es conocer adecuadamente las

Light-struck taste in white wine: enological approach for its prevention

Light-struck taste is a defect prevalent in white wines bottled in clear glass light-exposed for a considerable amount of time leading to a loss of color and appearance of sulfur-like odors. The reaction involves riboflavin (RF), a highly photosensitive compound that undergoes to intermolecular photoreduction by the uptake of two electron equivalents from an external donor, the methionine. The reaction includes different steps forming methional which is extremely unstable and decomposes to methane thiol and acrolein. The reaction of two molecules of methane thiol yields dimethyl disulfide. Methane thiol is highly volatile, has a low perception threshold (2 to 10 µg/L in wine) and confers aroma-like rotten eggs or cabbage.

Application de l’Analyse du Cycle de Vie (ACV) à un domaine viticole

Since 1980, Château de l’Éclair has belonged to SICAREX Beaujolais and has been involved in experimentation for the Beaujolais vineyards. However, it is a commercial estate with profitability and quality constraints, which means that it has to meet the growing environmental expectations of consumers. Given the number of practices claimed to be environment-friendly, it is sometimes difficult to prioritize actions.

The effects of calcite silicon-mediated particle film application on leaf temperature and grape composition of Merlot (Vitis vinifera L.) vines under different irrigation conditions

This study examined whether the application of calcite-silicon mediated particle film (CaPF) at veraison can mitigate a drought-induced increase in leaf temperature on grapevine, thus contributing to improved leaf functionality, yield and grape composition traits. A total of 48 five-year-old Merlot (Vitis vinifera L.)