terclim by ICS banner
IVES 9 IVES Conference Series 9 International Congress on Grapevine and Wine Sciences 9 2ICGWS-2023 9 Plastic debris at vines: carriers of pollutants in the environment?

Plastic debris at vines: carriers of pollutants in the environment?

Abstract

Modern agriculture employs large amounts of plastics, such as mulching and greenhouse films, thermal covers, plant protection tubes and tying tape. The latter two types are very common in viticulture. Guard tubes are employed to protect young vines from mechanic and atmospheric damage, whilst polymeric tying tape has replaced natural-origin materials to hold the canopy of vines. Both materials are made on synthetic polymers, which include a range of additives to improve their environmental stability remaining in the environment of vineyards for years. During this time, they are exposed to the range of pesticides (fungicides, insecticides and in a lesser extend herbicides) applied to vines. Tying tape fits within the category of meso-plastics, difficult to recover due to their abundance and limited size. After pruning, most of the tying tapes end in the soil of vineyards. Both types of materials are potential sources of microplastics during aging.

Depending on the affinity between pesticides and plastics, the latter can act as reservoirs of this kind of pollutants, contributing to their delayed release in the environment of vineyards, and/or serving as carriers of pesticides into the trophic web, and/or into surface waters due to wind and run-off transport. This presentation deals with the characterization of plastic debris collected from vineyards. Thus, the presence of pesticides residues in this matrix were determined, including a comparison with their levels in soil, and the study of the sorption/desorption processes of pesticides in new and aged samples of different types of vineyard plastics.

Residues of pesticides in plastic litter, collected from conventionally managed vineyards, varied from 100 ng g-1 to more than 10000 ng g-1. The range of compounds remaining in this matrix included not only moderately lipophilic pesticides, but also medium polarity species, i.e. metalaxyl, carbendazim and dimethomorph. The strength of interaction between pesticides and the two main types of plastic residues identified in vineyards (PE and PP) was mostly controlled by the degree of polymer weathering, which was characterized by FTIR in the total attenuated reflectance mode (ATR).

Acknowledgements: M.C. acknowledges a FPI contract to the Spanish Ministry of Science and Innovation. Funds received from Xunta de Galicia (project ED431C2021/06) are acknowledged.

DOI:

Publication date: October 5, 2023

Issue: ICGWS 2023

Type: Article

Authors

I. Rodríguez1*, M. Cobo-Golpe1, G.R. Gutierrez1, J. Álvarez1, V. Fernández1, P. Blanco2, M. Ramil1

1 Department of Analytical Chemistry, Nutrition and Food Sciences, IAQBUS – Institute of Research on Chemical and Biological Analysis, Universidade de Santiago de Compostela, R/Constantino Candeira SN, 15782 Santiago de Compostela, Spain
2 Estación de Viticultura e Enoloxía de Galicia (EVEGA-AGACAL), Ponte San Clodio s/n, 32428, Leiro-Ourense

Contact the author*

Keywords

plastic litter, vineyards, pesticides, occurrence, desorption

Tags

2ICGWS | ICGWS | ICGWS 2023 | IVES Conference Series

Citation

Related articles…

The interplay between water deficit and nitrogen and potassium nutrition in Vitis vinifera L.

Climate change is expected to provoke an increase in the frequency and intensity of drought events and water scarcity that will have detrimental effects on photosynthesis and plant yield. To sustain an appropriate plant yield under sub-optimal conditions, a common practice is the application of high amounts of fertilizers with negative environmental consequences. The present study aims at evaluating the interplay between water and nutrient availability, namely nitrogen (N) and potassium (K), in two grapevine cultivars with a different sensitivity to water shortage stress. Two-year-old Vitis Vinifera cv. Cabernet Sauvignon and Grenache grapevine plants grafted on SO4 rootstock have been transferred in pots under semi-environmental conditions.

Agronomic and oenological behavior of the minority Mandón variety on two rootstocks in the D.O. Arribes

A large population of vines of the Mandón minority red variety (synonymous with Garró) has been located in old vineyards of the D.O. Arribes (Zamora and Salamanca) to conserve and recover this minority variety. The wines made with this variety are characterized by their good structure and color, interesting harmony, an excellently low pH, with high acidity, as well as complex aromas of blue fruits and a marked and expressive minerality.

Impact of toasting and botanical origin on oak wood (Q. sp.) volatilome using untargeted GCxGC-ToFMS analysis

Many works have been carried out to identify the key aroma volatile compounds of oak wood (e.g., whisky-lactone, furfural, maltol, eugenol, guaiacol, vanillin) using conventional gas chromatography coupled with olfactometry and mass spectrometry (GC-O-MS). Inspired by recent untargeted approaches in the field of food “omics”, this work aims to extend our knowledge on the impact of cooperage process on the volatile composition of oak wood using two-dimensional comprehensive gas chromatography coupled with time of flight mass spectrometry (GCxGC-ToFMS).

Early defoliation positively enhances bioactive composition of berries with no effect on cuticle characteristics

Leaf removal in the fruit-zone has been employed to improve cluster light exposure and ventilation and therefore increase metabolite accumulation and reduce botrytis incidence in berries. When applied before flowering (early defoliation – ED), it can also decrease cluster compactness and regulate yield in high-yielding varieties. This study aimed to evaluate the impact of ED on the physiology and metabolism of Aragonez (syn. Tempranillo) berries along the ripening period. The experiment was set up in 2013 at a commercial vineyard located in the Lisbon winegrowing region.

Influence of p-Coumaric Acid and Micronutrients on Growth and 4-Ethylphenol Production by Brettanomyces bruxellensis

The wine spoilage caused by Brettanomyces bruxellensis is one of the global concerns for winemakers. Detecting the presence of B. bruxellensis using routine laboratory culture techniques becomes challenging when cells enter the viable but not culturable (VBNC) state. This study aims to investigate the impact of p-coumaric acid (a volatile phenol precursor) and micronutrients on B. bruxellensis’ culturability, viability, and volatile phenol production under sulfite stress. In red wine, exposure to a high sulfite dose (100.00 mg L-1 potassium metabisulfite) resulted in immediate cell death, followed by a recovery of culturability after two weeks.