terclim by ICS banner
IVES 9 IVES Conference Series 9 International Congress on Grapevine and Wine Sciences 9 2ICGWS-2023 9 Adsorption of tetraconazole by organic residues and vineyard organically-amended soils 

Adsorption of tetraconazole by organic residues and vineyard organically-amended soils 

Abstract

Spain is the country with the largest wine-producing area in the EU and its productivity is largely controlled applying fungicides. However, residues of these compounds can move and contaminate surface and groundwater. The objective of this work was to evaluate the capacity of bioadsorbents from different origin to adsorb and immobilize tetraconazole by themselves or when applied as organic soil amendment, and to prevent soil and water contamination by this fungicide. The adsorption of tetraconazole by 3 organic residues: spent mushroom substrate (SMS), green compost (GC) and vine pruning sawdust (VP), as well as by vineyard soils unamended and amended individually with these residues at 1.5% (w/w) was evaluated using the batch equilibrium technique. Two vineyard soils from La Rioja were selected (S1-sandy loam, 0.26% OC; and S2-clay loam, 0.69% OC). Freundlich Kf adsorption constants of tetraconazole (3.6-19.2) by unamended and amended soils increased in the order: S1 < S2 < S2+GC < S2+VP < S1+VP ≈ S1+GC < S2+SMS < S1+SMS; and for the residues in the order: GC < VP < SMS. The Kf values of amended soils, especially for SMS-amended soils, were higher than those of unamended soils, due to their higher OC content. The application of organic residues to S1 soil increased its Kf value between 3.7-5.4 times, and that of S2 soil up to 2.7 times. However, the Kf values of S1 soil amended with the different organic residues were higher than those of amended S2 soils, despite their lower OC content. Therefore, physicochemical characteristics of soils different from OC (pH, carbonates, clay content, etc.) may also play an important role on the adsorption of tetraconazole by amended soils as observed for other fungicides.

Acknowledgements: We give thanks to Project TED2021-129962B-C41, funded by MCIN/AEI/10.13039/501100011033/ and the European Union (NextGenerationEU/PRTR).

DOI:

Publication date: October 9, 2023

Issue: ICGWS 2023

Type: Poster

Authors

Asier Barrio1, M. Soledad Andrades2, M. Sonia Rodríguez-Cruz1, Jesús M. Marín-Benito1*

Institute of Natural Resources and Agrobiology of Salamanca (IRNASA, CSIC), Cordel de Merinas 40-52, 37008 Salamanca, Spain.
2 Agriculture and Food Department, University of La Rioja, Madre de Dios 51, 26006 Logroño, Spain.

Contact the author*

Keywords

adsorption, fungicide, vineyard soil, conservation, organic amendment

Tags

2ICGWS | ICGWS | ICGWS 2023 | IVES Conference Series

Citation

Related articles…

Genetic variation among wild grapes native to Japan

Domesticated grapes are assumed to have originated in the Middle East. However, a considerable number of species are native in East Asian countries such as China, Korea and Japan as well. Evidence suggests that a total of seven species and eight varieties have been found to be native to Japan. A wide level variation in morphology, genetic and fruit composition exist in wild grape native to Japan.

Comparison of the effects of hormone- and natural-based elicitors on key metabolic pathways in cv. Tempranillo

One of the most important effects of climate change in wine-growing areas is the advance of phenological stages, especially concerning early berry ripening. In the hottest seasons, this results in a lack of synchrony between sugar and phenolic ripeness. In order to cope with this fact, a general effort is being made by researchers and growers aiming at delaying ripening through different strategies. One of the proposed approaches is the application of elicitors. This study aims to assess the effect at the transcriptomic level of application of three elicitors (Vitalfit, Fruitel, and Protone) in Tempranillo.

Biotype diversity within the autochthonous ‘Bobal’ grapevine variety

Bobal is the second most widely grown Spanish red grape variety (54,165 has), mainly cultivated in the Valencian Community and especially, in Utiel-Requena region (about 67% of 34,000 has). In this study, agronomic and enological parameters were determined in 98 biotypes selected during 2018 and 2019 in more than 50 vineyards over 50 years-old in the Utiel-Requena region. Moreover, a multi-criteria approach considering temperature and rainfall (Fig. 1A), among other parameters, was made to establish three different zones within the region (Fig. 1B), where in the future the selected biotypes will evaluated. In fact, in 2020, 4 replicates and 12 vines per biotype were planted in an experimental vineyard to preserve this important intra-cultivar diversity.

Crown procyanidin quantification in red wines, rosé wines and Port wines

Condensed grape tannins play a major role in the organoleptic properties and quality of red wine. Recently, a new sub-family of macrocyclic condensed tannins has been identified in red wine and named “crown tannins”. Indeed, the first compound of the family identified and characterised by NMR was the crown procyanidin tetramer which is composed of a macrocyclic structure composed of four (-)-epicatechins link together by B-type interflavanoid linkage in the following an alternative sequences of C4-C8 and C4-C6 linkage. The 3D structure of this unusual crown procyanidin family reveals a central cavity in the molecule [1].

Wine racking in the winery and the use of inerting gases

The O2 uptake in the different winemaking processes is generally considered to be negative for the sensory characteristics of white and rosé wines. Wine racking is a critical point of O2 uptake, as the large surface area of the wine exposed during this operation and the inability to maintain an effective inert gas blanket over it.
The objective was to study O2 uptake during the racking of a model wine without using inert gases and to compare it with the purging of the destination tank with different inert gases.