terclim by ICS banner
IVES 9 IVES Conference Series 9 International Congress on Grapevine and Wine Sciences 9 2ICGWS-2023 9 Adsorption of tetraconazole by organic residues and vineyard organically-amended soils 

Adsorption of tetraconazole by organic residues and vineyard organically-amended soils 

Abstract

Spain is the country with the largest wine-producing area in the EU and its productivity is largely controlled applying fungicides. However, residues of these compounds can move and contaminate surface and groundwater. The objective of this work was to evaluate the capacity of bioadsorbents from different origin to adsorb and immobilize tetraconazole by themselves or when applied as organic soil amendment, and to prevent soil and water contamination by this fungicide. The adsorption of tetraconazole by 3 organic residues: spent mushroom substrate (SMS), green compost (GC) and vine pruning sawdust (VP), as well as by vineyard soils unamended and amended individually with these residues at 1.5% (w/w) was evaluated using the batch equilibrium technique. Two vineyard soils from La Rioja were selected (S1-sandy loam, 0.26% OC; and S2-clay loam, 0.69% OC). Freundlich Kf adsorption constants of tetraconazole (3.6-19.2) by unamended and amended soils increased in the order: S1 < S2 < S2+GC < S2+VP < S1+VP ≈ S1+GC < S2+SMS < S1+SMS; and for the residues in the order: GC < VP < SMS. The Kf values of amended soils, especially for SMS-amended soils, were higher than those of unamended soils, due to their higher OC content. The application of organic residues to S1 soil increased its Kf value between 3.7-5.4 times, and that of S2 soil up to 2.7 times. However, the Kf values of S1 soil amended with the different organic residues were higher than those of amended S2 soils, despite their lower OC content. Therefore, physicochemical characteristics of soils different from OC (pH, carbonates, clay content, etc.) may also play an important role on the adsorption of tetraconazole by amended soils as observed for other fungicides.

Acknowledgements: We give thanks to Project TED2021-129962B-C41, funded by MCIN/AEI/10.13039/501100011033/ and the European Union (NextGenerationEU/PRTR).

DOI:

Publication date: October 9, 2023

Issue: ICGWS 2023

Type: Poster

Authors

Asier Barrio1, M. Soledad Andrades2, M. Sonia Rodríguez-Cruz1, Jesús M. Marín-Benito1*

Institute of Natural Resources and Agrobiology of Salamanca (IRNASA, CSIC), Cordel de Merinas 40-52, 37008 Salamanca, Spain.
2 Agriculture and Food Department, University of La Rioja, Madre de Dios 51, 26006 Logroño, Spain.

Contact the author*

Keywords

adsorption, fungicide, vineyard soil, conservation, organic amendment

Tags

2ICGWS | ICGWS | ICGWS 2023 | IVES Conference Series

Citation

Related articles…

Physicochemical behaviour of wine spirit and wine distillate aged in Sherry Casks® and Brandy casks

Brandy is a spirit drink made from “wine spirit” (<86% Alcohol by Volume – ABV; high levels of congeners and they are mainly less volatile than ethanol), it may be blended with a “wine distillate” (<94.8%ABV; low levels of congeners and these are mainly more volatile than ethanol), as long as that distillate does not exceed a maximum of 50% of the alcoholic content of the finished product[1]. Brandy must be aged for at least 6 months in oak casks with <1000L of capacity. During ageing, changes occur in colour, flavour, and aroma that improve the quality of the original distillate.

Typicality of Rioja wines: identification of sensory profiles for the three subregions of DOCa Rioja

Within the DOCa Rioja three main production areas are differentiated: Rioja Alta (RA), Rioja Alavesa (RAv) and Rioja Oriental (RO). They are three diverse territories with particular characteristics that are claimed to give rise to differentiated profiles. The present work aims at evaluating the sensory diversity of young commercial red wines in these three subregions. Therefore 30 young red wines (mainly Tempranillo and vintage 2021), ten from each subregion, were sensory described following a non-verbal free sorting task and a verbal free comment task by 32 well-established Rioja winemakers.

Dynamics of Saccharomyces cerevisiae population in spontaneous fermentations from Granxa D’Outeiro terroir (DOP Ribeiro, NW Spain)

Granxa D’Outeiro is a recovered ancient vineyard located in the heart of DOP Ribeiro, where traditional white grapevine varieties are growing under sustainable management. Spontaneous fermentations using grape must from Treixadura, Albariño, Lado, Godello, and Loureira varieties were carried out at experimental winery of Evega. Yeasts were isolated from must and at different stages of fermentation. Those colonies belonging to Saccharomyces cerevisiae were characterized at strain level by mDNA-RFLPs.

Atypical aging and hydric stress: insights on an exceptionally dry year

Atypical aging (ATA) is a white wine fault characterized by the appearance of notes of wet rag, acacia blossoms and naphthalene, along with the vanishing of varietal aromas. 2-aminoacetophenone (AAP) – a degradation compound of indole-3-acetic acid (IAA) – is regarded as the main sensorial and chemical marker responsible for this defect. About the origin of ATA, a stress reaction occurring in the vineyard has been looked as the leading cause of this defect. Agronomic, climatic and pedological factors are the main triggers and among them, drought stress seems to play a crucial role.[1]

Role of anthocyanins and copigmentation in flavonol solubility in red wines 

Over the last years, due to climate change, several red wines, such as the Sangiovese wines, have been often subjected to loss of clarity due to the formation of deposits of fine needle-shaped crystals. This phenomenon turned out to be due to an excess of quercetin (Q) and its glycosides (Q-Gs) in wines. These compounds are synthesized to a large extent when grapes are excessively exposed to UVB radiations in vineyards[1]. Unfortunately, it is not easy to predict the degree of Q precipitation because its solubility strongly depends on the wine and matrix composition[2].