terclim by ICS banner
IVES 9 IVES Conference Series 9 ‘TROPICAL’ POLYFUNCTIONAL THIOLS AND THEIR ROLE IN AUSTRALIAN RED WINES

‘TROPICAL’ POLYFUNCTIONAL THIOLS AND THEIR ROLE IN AUSTRALIAN RED WINES

Abstract

Following anecdotal evidence of unwanted ‘tropical’ character in red wines resulting from vineyard interventions and a subsequent yeast trial observing higher ‘red fruit’ character correlated with higher thiol concentrations, the role of polyfunctional thiols in commercial Australian red wines was investigated.

First, trials into the known tropical thiol modulation technique of foliar applications of sulfur and urea were conducted in parallel on Chardonnay and Shiraz.1 The Chardonnay wines showed expected results with elevated concentrations of 3-sulfanylhexanol (3-SH) and 3-sulfanylhexyl acetate (3-SHA), whereas the Shiraz wines lacked 3-SHA. Furthermore, the Shiraz wines were described as ‘drain’ (known as ‘reductive’ aroma character) during sensory evaluation although they did not contain thiols traditionally associated with ‘reductive’ thiols (H2S, methanethiol etc.).

Secondly, a survey of over 100 commercial Australian red wines across 10 different varieties supported the outcome of the foliar application trial.2 While all red wines contained 3-SH above the sensory detection threshold (60 ng/L, aqueous ethanol), no wines were observed to contain detectable concentrations of 3-SHA. As such, the acetylation of 3-SH to 3-SHA in red wine fermentations appears to be extremely limited.

Lastly, 3-SH and/or 3-SHA were spiked into four different varieties of red wine to understand the impact on sensory attributes.2 Traditionally lighter varieties (Pinot Noir and Grenache) had increased ‘red fruit’ and ‘lolly’ ratings at low concentrations of 3-SH and 3-SHA but changed to ‘tropical’ at higher concentrations. For Cabernet Sauvignon, 3-SH and 3-SHA additions resulted in increases to ‘blackcurrant’ and ‘tropical’ attributes, whereas Shiraz additions of 3-SH resulted in ‘sweaty’ and ‘tropical’ descriptors.

The ‘tropical’ thiol, 3-SH, was ubiquitous in Australian red wines although the acetylation to 3-SHA was not commonly observed. The impact of these thiols in red wines differed by variety, and their presence was increased by vineyard foliar application treatments. As such, vineyard management practises might hold the key to avoiding undesirable expressions of ‘tropical’ characters in red wine.

 

1. Cordente, A. G.; Curtin, C. D.; Solomon, M.; Kulcsar, A. C.; Watson, F.; Pisaniello, L.; Schmidt, S. A.; Espinase Nandorfy, D. Modulation of volatile thiol release during fermentation of red musts by wine yeast. Processes 2022, 10 (3), 502.
2. Hixson, J.; Bilogrevic, E.; Capone, D.; Nandorfy, D. E.; Francis, L.; Petrie, P.; Solomon, M.; Krstic, M. AWRI report: Enhancing tropical fruit flavour in Chardonnay and Shiraz through foliar nutrient sprays. Wine & Vitic. J. 2020, 35 (3), 30-33. 
3. Siebert, T.; Francis, L.; Pisaniello, L.; Melzer, S.; Bey, L.; Watson, F.; Espinase Nandorfy, D.; Cordente, T. Do varietal thiols matter in red wine? AWRI Tech. Rev. 2019, 243, 10-15.

DOI:

Publication date: February 9, 2024

Issue: OENO Macrowine 2023

Type: Article

Authors

Tracey Siebert1, Mark Solomon1, Lisa Pisaniello1, Damian Espinase Nandorfy1,2, Eleanor Bilogrevic1, Flynn Wat-Son1, Toni Cordente1, Leigh Francis1, Josh Hixson1

1. The Australian Wine Research Institute, Waite Precinct, Hartley Grove cnr Paratoo Road, Urrbrae 5064, Australia.
2. CASS Food Research Centre, School of Exercise and Nutrition Sciences, Deakin University, 221 Burwood Highway, Burwood, VIC, 3125, Australia.

Contact the author*

Keywords

red wine, ‘tropical’ aroma, thiols, sensory

Tags

IVES Conference Series | oeno macrowine 2023 | oeno-macrowine

Citation

Related articles…

IMPACT OF THE WINES’ QUALITY ON THE WINE DISTILLATES’ ORGANOLEPTIC PROFILE

Brandy de Jerez (BJ) is a spirit drink made exclusively from spirits and wine distillates and is characterized by the use of casks for aging that previously contained Sherries. The quality and sensory complexity of BJ depend on the raw materials and some factors: grape variety, conditions during processing the wine and its distillation, as well as the aging in the cask. Therefore, the original compounds of the grapes from which it comes are of great interest (1 y 2) being in most cases the Airén variety. Their relationship with the quality of the musts and the wines obtained from them has been studied (3) and varies each year of harvest depending on the weather conditions (4).

DETERMINATION OF MINERAL COMPOSITION IN CV. TERAN (VITIS VINIFERA L.) RED WINE AFFECTED BY PRE-FERMENTATIVE MASH COOLING, HEATING, SAIGNÉE TECHNIQUE AND PROLONGED POST-FERMENTATIVE MACERATIONS

This study aimed to determine mineral composition in red wine obtained from cv. Teran (Vitis vinifera L.), autochtonous Croatian grape variety. Six different vinification treatments, including the control treatment (7-day standard maceration), were performed to study the effects of: 48-hour pre-fermentative mash cooling (8 °C) followed by prolonged post-fermentative maceration of 13 days (C15), 28 days (C30), and saignée technique (juice runoff) proceeded with prolonged post-fermentative maceration of 13 days (CS15); and effect of 48-hour heating (50 °C) followed by prolonged post-fermentative maceration of 13 days (H15) and 28 days (H30) on macro- and microelements in wine.

IDENTIFICATION AND LEVELS OF PHENOLIC COMPOUNDS (TANINS, ANTHO-CYANS) IN RED VARIETAL WINES (PROKUPAC AND BLACK TAMJANIKA) FROM SERBIA

The phenolic compounds of red wines represent a source of numerous benefits for human health, which is why they are a constant subject of scientific research. Winemaking in Serbia has a growing economic significance, with particularly autochthonous varieties included [1]. This research identifies and quantifies phenolic compounds of Serbian red varietal wines of Prokupac and Black Tamjanika varieties. Quantification of the level of phenolics has been conducted, including molecular tannins [(+)-catechin, (-)-epicatechin, procyanidin dimers B1, B2, B3, B4], molecular anthocyanins, and the mean degree of polymerization of tannins by HPLC by UV detection, total antioxidant capacity via spectrophotometric methods and chromatic characteristics via CIELAB.

INTENSE PULSED LIGHT FOR VINEYARD WASTEWATER: A PROMISING NEW PROCESS OF DEGRADATION FOR PESTICIDES

The use of pesticides for vine growing is responsible for generating an important volume of wastewater. In 2009, 13 processes were authorized for wastewater treatment but they are expensive and the toxicological impact of the secondary metabolites that are formed is not clearly established. Recently photodecomposition processes have been studied and proved an effectiveness to degrade pesticides and to modify their structures (Maheswari et al., 2010, Lassale et al., 2014). In this field, Pulsed Light (PL) seems to be an interesting and efficient process (Baranda et al., 2017). Therefore, the aim of this work was to investigate the PL technology as a new process for the degradation of pesticides.

Searching for the sweet spot: a focus on wine dealcoholization

It is well known that the vinification of grapes at full maturation can produce rich, full-bodied wines,
with intense and complex flavour profiles. However, the juice obtained from such grapes may have very
high sugar concentration, resulting in wines with an excessive concentration of ethanol. In addition, the decoupling between technological maturity and phenolic/aromatic one due to global warming, exacerbates this problem in some wine-growing regions. In parallel with the increase of the mean alcohol content of wines on the market, also the demand for reduced alcohol beverages has increased in recent years, mainly as a result of health and social concerns about the risks related to the consumption of alcohol.