terclim by ICS banner
IVES 9 IVES Conference Series 9 ‘TROPICAL’ POLYFUNCTIONAL THIOLS AND THEIR ROLE IN AUSTRALIAN RED WINES

‘TROPICAL’ POLYFUNCTIONAL THIOLS AND THEIR ROLE IN AUSTRALIAN RED WINES

Abstract

Following anecdotal evidence of unwanted ‘tropical’ character in red wines resulting from vineyard interventions and a subsequent yeast trial observing higher ‘red fruit’ character correlated with higher thiol concentrations, the role of polyfunctional thiols in commercial Australian red wines was investigated.

First, trials into the known tropical thiol modulation technique of foliar applications of sulfur and urea were conducted in parallel on Chardonnay and Shiraz.1 The Chardonnay wines showed expected results with elevated concentrations of 3-sulfanylhexanol (3-SH) and 3-sulfanylhexyl acetate (3-SHA), whereas the Shiraz wines lacked 3-SHA. Furthermore, the Shiraz wines were described as ‘drain’ (known as ‘reductive’ aroma character) during sensory evaluation although they did not contain thiols traditionally associated with ‘reductive’ thiols (H2S, methanethiol etc.).

Secondly, a survey of over 100 commercial Australian red wines across 10 different varieties supported the outcome of the foliar application trial.2 While all red wines contained 3-SH above the sensory detection threshold (60 ng/L, aqueous ethanol), no wines were observed to contain detectable concentrations of 3-SHA. As such, the acetylation of 3-SH to 3-SHA in red wine fermentations appears to be extremely limited.

Lastly, 3-SH and/or 3-SHA were spiked into four different varieties of red wine to understand the impact on sensory attributes.2 Traditionally lighter varieties (Pinot Noir and Grenache) had increased ‘red fruit’ and ‘lolly’ ratings at low concentrations of 3-SH and 3-SHA but changed to ‘tropical’ at higher concentrations. For Cabernet Sauvignon, 3-SH and 3-SHA additions resulted in increases to ‘blackcurrant’ and ‘tropical’ attributes, whereas Shiraz additions of 3-SH resulted in ‘sweaty’ and ‘tropical’ descriptors.

The ‘tropical’ thiol, 3-SH, was ubiquitous in Australian red wines although the acetylation to 3-SHA was not commonly observed. The impact of these thiols in red wines differed by variety, and their presence was increased by vineyard foliar application treatments. As such, vineyard management practises might hold the key to avoiding undesirable expressions of ‘tropical’ characters in red wine.

 

1. Cordente, A. G.; Curtin, C. D.; Solomon, M.; Kulcsar, A. C.; Watson, F.; Pisaniello, L.; Schmidt, S. A.; Espinase Nandorfy, D. Modulation of volatile thiol release during fermentation of red musts by wine yeast. Processes 2022, 10 (3), 502.
2. Hixson, J.; Bilogrevic, E.; Capone, D.; Nandorfy, D. E.; Francis, L.; Petrie, P.; Solomon, M.; Krstic, M. AWRI report: Enhancing tropical fruit flavour in Chardonnay and Shiraz through foliar nutrient sprays. Wine & Vitic. J. 2020, 35 (3), 30-33. 
3. Siebert, T.; Francis, L.; Pisaniello, L.; Melzer, S.; Bey, L.; Watson, F.; Espinase Nandorfy, D.; Cordente, T. Do varietal thiols matter in red wine? AWRI Tech. Rev. 2019, 243, 10-15.

DOI:

Publication date: February 9, 2024

Issue: OENO Macrowine 2023

Type: Article

Authors

Tracey Siebert1, Mark Solomon1, Lisa Pisaniello1, Damian Espinase Nandorfy1,2, Eleanor Bilogrevic1, Flynn Wat-Son1, Toni Cordente1, Leigh Francis1, Josh Hixson1

1. The Australian Wine Research Institute, Waite Precinct, Hartley Grove cnr Paratoo Road, Urrbrae 5064, Australia.
2. CASS Food Research Centre, School of Exercise and Nutrition Sciences, Deakin University, 221 Burwood Highway, Burwood, VIC, 3125, Australia.

Contact the author*

Keywords

red wine, ‘tropical’ aroma, thiols, sensory

Tags

IVES Conference Series | oeno macrowine 2023 | oeno-macrowine

Citation

Related articles…

CONSENSUS AND SENSORY DOMINANCE ARE DEPENDENT ON QUALITY CONCEPT DEFINITIONS

The definition of the term “quality” in sensory evaluation of food products does not seem to be consensual. Descriptive or liking methods are generally used to differentiate between wines (Lawless et al., 1997). Nevertheless, quality evaluation of a product such as wine can also relate to emotional aspects. As exposed by Costell (2002), product quality is defined as an integrated impression, like acceptability, pleasure, or emotional experiences during tasting. According to the ‘modality appropriateness’ hypothesis which predicts that wine tasters weigh the most suitable sensory inputs for a specific assess- ment (Freides, 1974; Welch & Warren, 1980), the nature of the quality definitions may modulate sensory influences.

THE EFFECT OF PRE-FERMENTATIVE GLYPHOSATE ADDITION ON THE METABOLITE PROFILE OF WINE

The synthetic herbicide glyphosate has been used extensively in viticulture over many decades to combat weeds. Despite this, the possible influence of residual glyphosate on both the alcoholic fermentation of grape juice and the subsequent metabolite profile of wines has not been investigated. In this study, Pinot noir juice supplemented with different concentrations of glyphosate (0 µg L-1, 10 µg L-1 and 1000 µg L-1) was fermented with commercial Saccharomyces cerevisiae yeast strains. Using a combination of analytical methods, 80 metabolites were quantified in the resulting wines.

VOLATILE COMPOUNDS AND SENSORY PROFILE OF NEBBIOLO RED WINES TREATED WITH WOOD FORMATS ALTERNATIVE TO BARRELS

In winemaking, the use of wood products alternative to barrels, has become a useful tool for the achievement of numerous oenological objectives, including the fast release of desirable volatile and polyphenolic compounds, colour stabilization, and important economic advantages if compared to the traditional barrel production. Among a huge array of variables, the wood format, the vinification protocol, especially the moment of the infusion of the woods and the exposed surface area of the alternative woods are of relevant significance, since they may influence the speed and intensity of the aroma transfer from the wood to the wine defining different sensory profiles.

IMPACT OF RHIZOPUS AND BOTRYTIS ON WINE FOAMING PROPERTIES

A lot of work has been done on the impact of Botrytis on the foam of sparkling wines. This work often concerns wines produced in cool regions, where Botrytis is the dominant fungal pathogen. However, in southern countries such as Spain, in particularly hot years such as 2022, the majority fungal pathogen is sometimes Rhizopus. Like Botrytis, Rhizopus is a fungus that produces an aspartic protease.

INTENSE PULSED LIGHT FOR VINEYARD WASTEWATER: A PROMISING NEW PROCESS OF DEGRADATION FOR PESTICIDES

The use of pesticides for vine growing is responsible for generating an important volume of wastewater. In 2009, 13 processes were authorized for wastewater treatment but they are expensive and the toxicological impact of the secondary metabolites that are formed is not clearly established. Recently photodecomposition processes have been studied and proved an effectiveness to degrade pesticides and to modify their structures (Maheswari et al., 2010, Lassale et al., 2014). In this field, Pulsed Light (PL) seems to be an interesting and efficient process (Baranda et al., 2017). Therefore, the aim of this work was to investigate the PL technology as a new process for the degradation of pesticides.