terclim by ICS banner
IVES 9 IVES Conference Series 9 THE ODORIFEROUS VOLATILE CHEMICALS BEHIND THE OXIDATIVE AROMA DEGRADATION OF SPANISH RED WINES

THE ODORIFEROUS VOLATILE CHEMICALS BEHIND THE OXIDATIVE AROMA DEGRADATION OF SPANISH RED WINES

Abstract

It is a well-established fact that premature oxidation is noxious for wine aromatic quality and longevity. Although some oxidation-related aroma molecules have been previously identified, there are not works carrying out systematic research about the changes in the profiles of odour-active volatiles during wine oxidation.

Different types of wines in terms of region, grape variety, oak aging and price were subjected to an oxidative aging procedure, sensory analysis, gas-chromatography olfactometry (GC-O) and quantitative analysis. Sensory notes such as dried fruit, cooked vegetables or liquorice-alcohol were oxidation-related. The GCO analysis of the samples with highest oxidation notes, revealed highest levels of four odour zones, which were identified in a dual system GC-O/FID-GC-O/MS as 1,1-diethoxyethane (liquor, strawberry, sweet), 2,4,5-trimethyl-1,3-dioxolane (fruity, solvent), 3-methylbutanal (solvent, yeasty) and methional (boiled potato, cooked vegetables).

The two aldehydes were quantified by gas chromatography-mass spectrometry (GC-MS). together with isobutanal, 2-methylbutanal and phenylacetaldehyde. All them were already present in significant amounts before oxidation. However, as they were forming odourless reversible adducts with SO₂ (α-hydroxyalkylsulphonates)1 they were initially non-odour active. However, as free SO₂ disappeared during oxidation² they become odour-active in oxidized samples. Additional quantities were formed during oxidation, most likely by the reaction of wine dicarbonyls with the amino acid precursors. This additional formation was particularly relevant for 2-methylbutanal, followed by methional and isobutanal, while for phenylacetaldehyde and 3-methylbutanal, quantities formed were smaller than those originally present. These results confirm that both, pre-existent levels of Strecker aldehydes and the ability to form them during oxidation, are relevant in wine stability.

Acetals were determined by L-L microextraction followed by GC-MS. Results revealed that during oxidation there is a clear increment on the levels of acetals formed from the condensation of acetaldehyde with ethanol, 2,3-butanediol and glycerol; leading to 1,1-diethoxyethane, 2,4,5-trimethyl-1,3-dioxolane and several heterocyclic acetals, respectively. Levels formed were high enough to be odour-active. This suggests that the formation of acetals is an essential part of the sensory changes noted during wine oxidation.

 

1. L.C. de Azevedo et al., Journal of Agricultural and Food Chemistry 2007, 55 (21)
2. M. Bueno, V. Carrascón & V.Ferreira. Journal of Agricultural and Food Chemistry 2016, 64 (3)

DOI:

Publication date: February 9, 2024

Issue: OENO Macrowine 2023

Type: Poster

Authors

A. M. Aragón-Capone¹, A. de-la-Fuente-Blanco¹, M.P. Saenz-Navajas², V.Ferreira¹, M.Bueno¹
1. Laboratorio de Análisis del Aroma y Enología (LAAE), Departamento de Química Analítica, Universidad de Zaragoza, Institu-to Agroalimentario de Aragón (IA2) (UNIZAR-CITA).Associated to Instituto de Ciencias de la Vid y del Vino (ICVV)(UR-CSIC-GR), c/Pedro Cerbuna 12, 50009 Zaragoza, Spain.
2. Instituto de Ciencias de la Vid y el Vino (ICVV) (UR-CSIC-GR), Departamento de Enología, Logroño, La Rioja, Spain.

Contact the author*

Keywords

Chemosensory analysis, Gas chromatography-olfactometry (GC-O), Oxidative aging, Wine’s longevity

Tags

IVES Conference Series | oeno macrowine 2023 | oeno-macrowine

Citation

Related articles…

POTENTIAL DEACIDIFYING ROLE OF A COMMERCIAL CHITOSAN: IMPACT ON PH, TITRATABLE ACIDITY, AND ORGANIC ACIDS IN MODEL SOLUTIONS AND WHITE WINE

Chitin is the main structural component of a large number of organisms (i.e., mollusks, insects, crustaceans, fungi, algae), and marine invertebrates including crabs and shrimps. The main derivative of chitin is chitosan (CH), produced by N-deacetylation of chitin in alkaline solutions. Over the past decade, the OIV/OENO 338A/ 2009 resolution approved the addition of allergen-free fungoid CH to must and wine as an adjuvant for microbiological control, prevention of haziness, metals chelation and ochratoxins removal (European Commission. 2011). Despite several studies on application of CH in winemaking, there are still very limited and controversial data on its interaction with acidic components in wine (Colan-gelo et al., 2018; Castro Marin et al., 2021).

REGULATION OF CENTRAL METABOLISM IN THE LEAVES OF A GRAPE VINES VA- RIETAL COLLECTION ON A TEMPERATURE CLINE

Grape (Vitis vinifera) is one of the world’s oldest agricultural fruit crops, grown for wine, table grape, raisin, and other products. One of the factors that can cause a reduction in the grape growing area is temperature rise due to climate change. Elevated temperature causes changes in grapevine phenology and fruit chemical composition. Previous studies showed that grape varieties respond differently to a temperature shift of 1.5°C; few varieties had difficulties in the fruit development or could not reach the desired Brix level.

Rootstock mediated responses of grapevine (Vitis vinifera L.) metabolism and physiology to combined water deficit and salinity stress in Syrah grafts

Water deficit and salinity are increasingly affecting the viticulture and wine industry. These two stresses are intimately related; understanding the physiological and metabolic responses of grapevines to water deficit, salinity and combined stress is critical for developing strategies to mitigate the nega- tive impacts of these stresses on wine grape production. These strategies can include selecting more tolerant grapevine cultivars and graft combinations, improving irrigation management, and using soil amendments to reduce the effects of salinity. For this purpose, understanding the response of grape- vine metabolism to altered water balance and salinity is of pivotal importance.

CHARACTERIZATION AND ANTIBACTERIAL ACTIVITY OF A POLYPHENOLIC EXTRACT OBTAINED BY GREEN SUPERCRITICAL CO₂ EXTRACTION FROM RED GRAPE POMACE

Upgrading wine industry solid wastes is considered as one of the main strategies to support the circular economy. Red grape pomaces constitute a rich source of polyphenols, which have been shown to possess antioxidant properties and to provide benefits for human and animal health. The objective of this work was to obtain and characterise polyphenolic extracts from red grape pomaces via green supercritical CO₂ extraction using ethanol as a co-solvent, and to evaluate their antibacterial activity against susceptible and multidrug-resistant Escherichia coli strains of animal intestinal origin.

BIOSORPTION OF UNDESIRABLE COMPONENTS FROM WINE BY YEAST-DERIVED PRODUCTS

4-Ethylphenol (EP) in wine is associated with organoleptic defects such as barn and horse sweat odors. The origin of EP is the bioconversion reaction of p-coumaric acid (CA), naturally present in grapes and grape musts by contaminating yeasts of the genus Brettanomyces bruxellensis.
Yeast cell walls (YCW) have shown adsorption capacities for different compounds. They could be applied to wines in order to adsorb either CA and/or EP and thus reduce the organoleptic defects caused by the contaminating yeasts.