terclim by ICS banner
IVES 9 IVES Conference Series 9 THE ODORIFEROUS VOLATILE CHEMICALS BEHIND THE OXIDATIVE AROMA DEGRADATION OF SPANISH RED WINES

THE ODORIFEROUS VOLATILE CHEMICALS BEHIND THE OXIDATIVE AROMA DEGRADATION OF SPANISH RED WINES

Abstract

It is a well-established fact that premature oxidation is noxious for wine aromatic quality and longevity. Although some oxidation-related aroma molecules have been previously identified, there are not works carrying out systematic research about the changes in the profiles of odour-active volatiles during wine oxidation.

Different types of wines in terms of region, grape variety, oak aging and price were subjected to an oxidative aging procedure, sensory analysis, gas-chromatography olfactometry (GC-O) and quantitative analysis. Sensory notes such as dried fruit, cooked vegetables or liquorice-alcohol were oxidation-related. The GCO analysis of the samples with highest oxidation notes, revealed highest levels of four odour zones, which were identified in a dual system GC-O/FID-GC-O/MS as 1,1-diethoxyethane (liquor, strawberry, sweet), 2,4,5-trimethyl-1,3-dioxolane (fruity, solvent), 3-methylbutanal (solvent, yeasty) and methional (boiled potato, cooked vegetables).

The two aldehydes were quantified by gas chromatography-mass spectrometry (GC-MS). together with isobutanal, 2-methylbutanal and phenylacetaldehyde. All them were already present in significant amounts before oxidation. However, as they were forming odourless reversible adducts with SO₂ (α-hydroxyalkylsulphonates)1 they were initially non-odour active. However, as free SO₂ disappeared during oxidation² they become odour-active in oxidized samples. Additional quantities were formed during oxidation, most likely by the reaction of wine dicarbonyls with the amino acid precursors. This additional formation was particularly relevant for 2-methylbutanal, followed by methional and isobutanal, while for phenylacetaldehyde and 3-methylbutanal, quantities formed were smaller than those originally present. These results confirm that both, pre-existent levels of Strecker aldehydes and the ability to form them during oxidation, are relevant in wine stability.

Acetals were determined by L-L microextraction followed by GC-MS. Results revealed that during oxidation there is a clear increment on the levels of acetals formed from the condensation of acetaldehyde with ethanol, 2,3-butanediol and glycerol; leading to 1,1-diethoxyethane, 2,4,5-trimethyl-1,3-dioxolane and several heterocyclic acetals, respectively. Levels formed were high enough to be odour-active. This suggests that the formation of acetals is an essential part of the sensory changes noted during wine oxidation.

 

1. L.C. de Azevedo et al., Journal of Agricultural and Food Chemistry 2007, 55 (21)
2. M. Bueno, V. Carrascón & V.Ferreira. Journal of Agricultural and Food Chemistry 2016, 64 (3)

DOI:

Publication date: February 9, 2024

Issue: OENO Macrowine 2023

Type: Poster

Authors

A. M. Aragón-Capone¹, A. de-la-Fuente-Blanco¹, M.P. Saenz-Navajas², V.Ferreira¹, M.Bueno¹
1. Laboratorio de Análisis del Aroma y Enología (LAAE), Departamento de Química Analítica, Universidad de Zaragoza, Institu-to Agroalimentario de Aragón (IA2) (UNIZAR-CITA).Associated to Instituto de Ciencias de la Vid y del Vino (ICVV)(UR-CSIC-GR), c/Pedro Cerbuna 12, 50009 Zaragoza, Spain.
2. Instituto de Ciencias de la Vid y el Vino (ICVV) (UR-CSIC-GR), Departamento de Enología, Logroño, La Rioja, Spain.

Contact the author*

Keywords

Chemosensory analysis, Gas chromatography-olfactometry (GC-O), Oxidative aging, Wine’s longevity

Tags

IVES Conference Series | oeno macrowine 2023 | oeno-macrowine

Citation

Related articles…

FREE TERPENE RESPONSE OF ‘MOSCATO BIANCO’ VARIETY TO GRAPE COLD STORAGE

Temperature control is crucial in wine production, starting from grape harvest to the bottled wine storage. Climate change and global warming affect the timing of grape ripening, and harvesting is often done during hot summer days, influencing berry integrity, secondary metabolites potential, enzyme and oxidation phenomena, and even fermentation kinetics. To curb this phenomenon, pre-fermentative cold storage can help preserve the grapes and possibly increase the concentration of key secondary metabolites. In this study, the effect of grape pre-fermentative cold storage was assessed on the ‘Moscato bianco’ white grape cultivar, known for its varietal terpenes (65% of free terpenes represented by linalool and its derivatives) and widely used in Piedmont (Italy) to produce Asti DOCG wines.

WINE AS AN EMOTIONAL AND AESTHETIC OBJECT: IMPACT OF EXPERTISE

Wine tasting has been shown to provide emotions to tasters (Coste et al. 2018). How will expertise impact this emotional response? Burnham and Skilleås (2012) reported that the cultural, experiential, and aesthetic competencies characterize an expert in wine compared to a novice. Although there is no consensual definition of an aesthetic experience, Burnham and Skilleås (2012) reported that aesthetic appreciation is “disinterested, normative for others and communicable” in comparison to sensory pleasure.

DEVELOPMENT OF DISTILLATION SENSORS FOR SPIRIT BEVERAGES PRODUCTION MONITORING BASED ON IMPEDANCE SPECTROSCOPY MEASUREMENT AND PARTIAL LEAST SQUARES REGRESSION (PLS-R)

During spirit beverages production, the distillate is divided in three parts: the head, the heart, and the tail. Acetaldehyde and ethanol are two key markers which allow the correct separation of distillate. Being toxic, the elimination of the head part, which contains high concentration of acetaldehyde, is crucial to guarantee the consumer’s health and security. Plus, the tail should be separated from the heart based on ethanol concentration.

UNTARGETED METABOLOMICS ANALYSES TO IDENTIFY A NEW SWEET COMPOUND RELEASED DURING POST-FERMENTATION MACERATION OF WINE

The gustatory balance of dry wines is centered on three flavors, sourness, bitterness and sweetness. Even if certain compounds were already identified as contributing to sweetness, some taste modifications remain largely unexplained1,2. Some empirical observations combined with sensory analyzes have shown that an increase of wine sweetness occurs during post-fermentation maceration³. This step is a key stage of red winemaking during which the juice is left in contact with the marc, that contains the solid parts of the grape (seeds, skins and sometimes stems). This work aimed to identify a new taste-active compound that contributes to this gain of sweetness.

VOLATILE, PHENOLIC AND COLORIMETRIC CHARACTERIZATION OF THREE DIFFERENT LAMBRUSCO APPELLATIONS

Lambrusco is a commercially successful sparkling red and rosé wine. With 13.06 million litres sold in 2021 was the second best-selling Italian wine after Chianti. According to National Catalogue of Vine Varieties there are thirteen Lambrusco Varieties with which to date are produced seven PDO wines. Among these, “Lambrusco Salamino di Santa Croce”, “Lambrusco Grasparossa di Castelvetro” and “Lambrusco di Sorbara” are the only ones that can be considered mono-varietal appellations, all located in Modena area. The PDOs contemplate the possibility of producing wines by secondary fermentation either in tank (Charmat method), or in bottle (Classico method). Sur lie is a third method commonly employed for Lambrusco, similar to the Classico method, from which differs for the absence of disgorgement.