terclim by ICS banner
IVES 9 IVES Conference Series 9 NEW TOOL FOR SIMULTANEOUS MEASUREMENT OF OXYGEN CONSUMPTION AND COLOUR MODIFICATIONS IN WINES

NEW TOOL FOR SIMULTANEOUS MEASUREMENT OF OXYGEN CONSUMPTION AND COLOUR MODIFICATIONS IN WINES

Abstract

Measuring the effect of oxygen consumption on the colour of wines as the level of dissolved oxygen decreases over time is very useful to know how much oxygen a wine is able to consume without significantly altering its colour. The changes produced in wine after being exposed to high oxygen concen-trations have been studied by different authors, but in all cases the wine has been analysed once the oxygen consumption process has been completed. This work presents the results obtained with the use of an equipment designed and made to measure simultaneously the level of dissolved oxygen and the spectrum of the wine, during the oxygen consumption process from saturation levels with air to very low levels, which indicate the total consumption of the dosed oxygen.

For this purpose, this equipment has been designed, built and prepared and has been validated with the measurement of red wines made from different grape varieties.

The equipment built has 2 mm quartz cuvettes for the measurement of the spectrum in the visible with a spectrophotometer and a sensor for the simultaneous measurement of dissolved oxygen with a luminescent measurement system, both measurements were carried out every 15 minutes during oxy-gen consumption. The tightness of the cuvettes during the process of measuring the kinetics of oxygen consumption was evaluated, as well as the reproducibility of the measurements of both parameters.

The results of this study show that the equipment designed and built is valid for monitoring the kinetics of oxygen consumption with the simultaneous measurement of the spectrum in the visible and dissolved oxygen. The tightness tests corroborated that all the cells used simultaneously are airtight, keeping their interior totally isolated from the exterior, showing a variability between cells of less than 10%. The results of the repeatability tests showed that the same wine measured simultaneously in the different cuvettes showed the same results both in the measurement of the consumption kinetics and in the measurement of the spectrum in the visible. The application of the system developed for the study of red wines allowed to know the characteristics of the consumption kinetics, obtaining that all red wines were initially able to take up the same amounts of oxygen (Omax), with values of 174 hPa. However, the wines made with Tempranillo grapes showed higher oxygen consumption (∆Omax_min), 115 hPa, and lower residual oxygen values (Omin), 59 hPa compared to than those made with the Garnacha grapes with 84 y 88 hPa of Omin and ∆Omax_min, respectively. One of the main advantages of this equipment is the ability to record the changes produced in the spectrum as the wine consumes oxygen, thus, an increase in red tones (450 and 580 nm) was observed in all the wines studied. It was found that the wines made with the Garnacha grapes underwent increases in absorbance between 400 and 460 nm and between 610 and 670 nm as they consumed oxygen, indicating an increase in the compounds responsible for the purple and yellow hues. On the other hand, wines made with the Tempranillo grapes, as they consumed oxygen, showed a decrease in purple hues.

DOI:

Publication date: February 9, 2024

Issue: OENO Macrowine 2023

Type: Poster

Authors

Marioli Alejandra, Carrasco-Quiroz ¹, Ignacio Nevares ², Ana Martinez-Gil ¹, Rubén Del Barrio-Galan ¹. Maria Asensio-Cuadrado ², Maria Del Alamo-Sanza ¹
1. Dpt. Química Analítica, UVaMOX-Group, Universidad de Valladolid, Avda. Madrid, 50, 34004 Palencia, Spain.
2. Dpt. Ingeniería Agrícola y Forestal, UVaMOX-Group, Universidad de Valladolid, Avda. Madrid, 50, 34004 Palencia, Spain

Contact the author*

Keywords

Oxygen consumption, colour, wine, kinetics

Tags

IVES Conference Series | oeno macrowine 2023 | oeno-macrowine

Citation

Related articles…

INVESTIGATING TERROIR TYPICITY: A COMPREHENSIVE STUDY BASED ON THE AROMATIC AND SENSORIAL PROFILES OF RED WINES FROM CORBIÈRES APPELLATION

Volatile compounds play a significant role on the organoleptic properties defining wines quality. This particular role was exploited in several studies with the aim to differentiate wines from a more or less extensive production area, according to their sensory profile [1], as well as their chemical composition [2,3] (Di Paola-Naranjo et al., 2011; Kustos et al., 2020). Indeed, since aroma compounds development in grapes depends primarily on the environmental conditions of the vines and grapes (soil and climate), it is conceivable that these parameters craft the aromatic signature of the wine produced, in relation to its origin (Van Leeuwen et al., 2020). In this work, a general study on the aromatic and sensorial profile of wines produced in five sub-regions of the Corbières denomination, a renowned red grape varieties viticultural region in South France, was reported.

FOURIER TRANSFORM INFRARED SPECTROSCOPY IN MONITORING THE WINE PRODUCTION

The complexity of the wine matrix makes the monitoring of the winemaking process crucial. Fourier Transform Infrared Spectroscopy (FTIR) along with chemometrics is considered an effective analytical tool combining good accuracy, robustness, high sample throughput, and “green character”. Portable and non-portable FTIR devices are already used by the wine industry for routine analysis. However, the analytical calibrations need to be enriched, and some others are still waiting to be thoroughly developed.

PERCEPTUAL INTERACTIONS PHENOMENA INVOLVING VARIOUS VOLATILE COMPOUND FAMILIES LINKED TO SOME FRUITY NOTES IN BORDEAUX RED WINES

Fruity notes play a key role in the consumer’s appreciation of Bordeaux red wines. If literature provides a lot of knowledge about the nature of volatile compounds involved in this fruity expression, the sensory phenomena involving these compounds in mixture still need to be explored. Considering previous sensory works about the impact of esters and some overripening compounds, the goal of this work was to study the implication of perceptual interactions involving red wine odorant compounds of diverse origins and described as potentially affecting fruity aromatic expression.

SENSORY DEFINITION OF A TECHNICAL UNAVOIDABLE TRANSFER OF AROMA COMPOUNDS VIA SEALING IN A BOTTLING LINE IN ORDER TO PREVENT PROSECUTION DUE TO FRAUDULENT AROMATIZATION OF A SUBSEQUENTLY FILLED WINE

In 2020, 12% of all bottled German wines were aromatized, which may increase further due to rising popularity of dealcoholized wines. As sealing polymers of a bottling line absorb aroma compounds and may release them into regular wines in the next filling¹, this unintentional carry-over bears the risk to violate the legal ban of any aromatization of regular wine. However, following EU legislation, German food control authorities accept a technical unavoidable transfer of aroma compounds, if this is of no sensory significance.

HYBRID GRAPEVINE CV BACO BLANC, BETWEEN TRADITION AND MODERNISM: FOCUS ON ENDOGENOUS EUGENOL AS RESISTANCE FACTOR TO BOTRYTIS CINEREA

The well-known antifungal and antibiotic molecule, eugenol, is widely spread in various plants including clove, basil and bay. It is also abundant in the hybrid grapevine cultivar (cv) Baco blanc (Vitis vi-nifera x Vitis riparia x Vitis labrusca), created by François Baco (19th century) in the Armagnac region. This study confirmed this cv as highly resistant to Botrytis cinerea by comparing fruit rot incidence and severity with two Vitis vinifera cultivars: Folle Blanche and Ugni Blanc. We have demonstrated the efficiency of eugenol in vitro, by further investigating the effect of small concentrations of eugenol, 3 to 4 ppm (corresponding to IC10), on B. cinerea. By comparing the two major modes of action (direct or volatile antibiosis), the vapour inhibiting effect of eugenol was more powerful. In the skin of Baco blanc berry, the total eugenol concentration reached a maximum at veraison, i.e. 1118 to 1478 μg/kg.