terclim by ICS banner
IVES 9 IVES Conference Series 9 NEW TOOL FOR SIMULTANEOUS MEASUREMENT OF OXYGEN CONSUMPTION AND COLOUR MODIFICATIONS IN WINES

NEW TOOL FOR SIMULTANEOUS MEASUREMENT OF OXYGEN CONSUMPTION AND COLOUR MODIFICATIONS IN WINES

Abstract

Measuring the effect of oxygen consumption on the colour of wines as the level of dissolved oxygen decreases over time is very useful to know how much oxygen a wine is able to consume without significantly altering its colour. The changes produced in wine after being exposed to high oxygen concen-trations have been studied by different authors, but in all cases the wine has been analysed once the oxygen consumption process has been completed. This work presents the results obtained with the use of an equipment designed and made to measure simultaneously the level of dissolved oxygen and the spectrum of the wine, during the oxygen consumption process from saturation levels with air to very low levels, which indicate the total consumption of the dosed oxygen.

For this purpose, this equipment has been designed, built and prepared and has been validated with the measurement of red wines made from different grape varieties.

The equipment built has 2 mm quartz cuvettes for the measurement of the spectrum in the visible with a spectrophotometer and a sensor for the simultaneous measurement of dissolved oxygen with a luminescent measurement system, both measurements were carried out every 15 minutes during oxy-gen consumption. The tightness of the cuvettes during the process of measuring the kinetics of oxygen consumption was evaluated, as well as the reproducibility of the measurements of both parameters.

The results of this study show that the equipment designed and built is valid for monitoring the kinetics of oxygen consumption with the simultaneous measurement of the spectrum in the visible and dissolved oxygen. The tightness tests corroborated that all the cells used simultaneously are airtight, keeping their interior totally isolated from the exterior, showing a variability between cells of less than 10%. The results of the repeatability tests showed that the same wine measured simultaneously in the different cuvettes showed the same results both in the measurement of the consumption kinetics and in the measurement of the spectrum in the visible. The application of the system developed for the study of red wines allowed to know the characteristics of the consumption kinetics, obtaining that all red wines were initially able to take up the same amounts of oxygen (Omax), with values of 174 hPa. However, the wines made with Tempranillo grapes showed higher oxygen consumption (∆Omax_min), 115 hPa, and lower residual oxygen values (Omin), 59 hPa compared to than those made with the Garnacha grapes with 84 y 88 hPa of Omin and ∆Omax_min, respectively. One of the main advantages of this equipment is the ability to record the changes produced in the spectrum as the wine consumes oxygen, thus, an increase in red tones (450 and 580 nm) was observed in all the wines studied. It was found that the wines made with the Garnacha grapes underwent increases in absorbance between 400 and 460 nm and between 610 and 670 nm as they consumed oxygen, indicating an increase in the compounds responsible for the purple and yellow hues. On the other hand, wines made with the Tempranillo grapes, as they consumed oxygen, showed a decrease in purple hues.

DOI:

Publication date: February 9, 2024

Issue: OENO Macrowine 2023

Type: Poster

Authors

Marioli Alejandra, Carrasco-Quiroz ¹, Ignacio Nevares ², Ana Martinez-Gil ¹, Rubén Del Barrio-Galan ¹. Maria Asensio-Cuadrado ², Maria Del Alamo-Sanza ¹
1. Dpt. Química Analítica, UVaMOX-Group, Universidad de Valladolid, Avda. Madrid, 50, 34004 Palencia, Spain.
2. Dpt. Ingeniería Agrícola y Forestal, UVaMOX-Group, Universidad de Valladolid, Avda. Madrid, 50, 34004 Palencia, Spain

Contact the author*

Keywords

Oxygen consumption, colour, wine, kinetics

Tags

IVES Conference Series | oeno macrowine 2023 | oeno-macrowine

Citation

Related articles…

PHOTO OXIDATION OF LUGANA WINES: INFLUENCE OF YEASTS AND RESIDUAL NITROGEN ON VSCS PROFILE

Lugana wines are made from Turbiana grapes. In recent times, many white and rosé wines are bottled and stored in flint glass bottles because of commercial appeal. However, this practice could worsen the aroma profile of the wine, especially as regards the development of volatile sulfur compounds (VSCs). This study aims to investigate the consequences of exposure to light in flint bottles on VSCs profile of Lugana wines fermented with two different yeasts and with different post-fermentation residual nitrogen.

CHANGES IN CU FRACTIONS AND RIBOFLAVIN IN WHITE WINES DURING SHORT-TERM LIGHT EXPOSURE: IMPACTS OF OXYGEN AND BOTTLE COLOUR

Copper in white wine can be associated with Cu(II) organic acids (Cu fraction I), Cu(I) thiol species (Cu fraction II), and Cu sulfides (Cu fraction III). The first two fractions are associated with the repression of reductive aromas in white wine, but these fractions gradually decrease in concentration during the normal bottle aging of wine. Although exposure of white wine to fluorescent light is known to induce the accumulation of volatile sulfur compounds, causing light-struck aroma, the influence on the loss of protective Cu fractions is uncertain. Riboflavin is known to be a critical initiator of photochemical reac-tions in wine, but the rate of its decay under short-term light exposure in different coloured bottles and for wine of different oxygen concentrations is not well understood.

TARTARIC STABILIZATION MAY AFFECT THE COLOR AND POLYPHENOLIC COMPOSITION OF TANNAT RED WINES FROM URUGUAY

Tartrate precipitation affects the properties of wines, due to the formation of crystals that cause turbidity, even after being bottled. The forced tartaric stabilization is carried out frequently for young wines, through various physicochemical procedures. The traditional treatment for tartaric stabilization is refrigeration, but it can have a negative effect on wine’s sensory properties, and particularly on the color of red wines. The aim of this study was to evaluate the effect of different tartaric stabilization options on the color and phenolic composition of Tannat red wines from Uruguay.

VOLATILE, PHENOLIC AND COLORIMETRIC CHARACTERIZATION OF THREE DIFFERENT LAMBRUSCO APPELLATIONS

Lambrusco is a commercially successful sparkling red and rosé wine. With 13.06 million litres sold in 2021 was the second best-selling Italian wine after Chianti. According to National Catalogue of Vine Varieties there are thirteen Lambrusco Varieties with which to date are produced seven PDO wines. Among these, “Lambrusco Salamino di Santa Croce”, “Lambrusco Grasparossa di Castelvetro” and “Lambrusco di Sorbara” are the only ones that can be considered mono-varietal appellations, all located in Modena area. The PDOs contemplate the possibility of producing wines by secondary fermentation either in tank (Charmat method), or in bottle (Classico method). Sur lie is a third method commonly employed for Lambrusco, similar to the Classico method, from which differs for the absence of disgorgement.

SENSORY CHARACTERIZATION OF COGNAC EAUX-DE-VIE AGED IN BARRELS REPRESENTING DIFFERENT TOASTING PROCESS

Cognac is an outstanding french wine spirit appreciated around the world and produced exclusively in the Nouvelle-Aquitaine region, and more precisely in the Cognac area. According to AOC regulations (Appellation D’origine Controlée), the spirit required at least 2 years of continuous ageing in oak barrels to be granted the title of Cognac. The oak wood will import color, structure and organoleptic complexity. The different steps during barrel-making process, such as seasoning and toasting, influence the above quality attributes in both wines and spirits.