terclim by ICS banner
IVES 9 IVES Conference Series 9 VOLATILE AND GLYCOSYLATED MARKERS OF SMOKE IMPACT: EVOLUTION IN BOTTLED WINE

VOLATILE AND GLYCOSYLATED MARKERS OF SMOKE IMPACT: EVOLUTION IN BOTTLED WINE

Abstract

Smoke impact in wines is caused by a wide range of volatile phenols found in wildfire smoke. These compounds are absorbed and accumulate in berries, where they may also become glycosylated. Both volatile and glycosylated forms eventually end up in wine where they can cause off-flavors. The impact on wine aroma is mainly attributed to volatile phenols, while in-mouth hydrolysis of glycosylated forms may be responsible for long-lasting “ashy” aftertastes (1).

In order to assess smoke impact, a selection of volatile and glycosylated phenols is proposed, mainly based on research from Australia (2, 3). It includes the volatile phenols guaiacol, 4-methylguaiacol, ortho-, meta- and para- cresol, phenol, syringol, and 4-methylsyringol, as well as their glycosylated forms guaiacol rutinoside, 4-methylguaiacol rutinoside, cresol rutinoside, phenol rutinoside, syringol gen-tiobioside, and 4-methylsyringol gentiobioside. The accurate and reproducible measurement of these compounds is now possible, due to the commercial availability of standards and isotopic analogues.

In this study, we investigated the stability of these markers in bottled wines from smoke-exposed grapes, during a two-year timeframe. Wines monitored were a Chenin Blanc and a Chardonnay (whites), a Grenache (rosé), two Cabernet Sauvignons, a Zinfandel and a Grenache (reds).

No significant increases in guaiacol were observed in the white and rosé wines. Slight increases (2-3 μg/L) were observed in red wines, with the exception of the Pinot Noir (9 μg/L). Non-significant to slight increases were observed for phenol, except in the Zinfandel (10 μg/L). Large increases were observed for syringol in red wines only, especially in Cabernet Sauvignons (up to 60 μg/L). No significant increases were observed for the other volatile phenols measured.

All measured glycosylated markers were stable, in all wines. Therefore, increases in volatile phenols, when they happened, were not explained by the hydrolysis of corresponding glycosylated forms measured.

The observed increases in guaiacol and syringol, as well as the stability of the glycosylated forms measured, are consistent with results from a previous study (4). The stability of glycosylated markers makes them relevant in identifying wines from smoke exposed grapes, possibly for many years after bottling. A limitation is that some smoke impacted wines might show normal or even non-detectable levels of these glycosylated markers.

 

1. Christine M. Mayr, Mango Parker, Gayle A. Baldock, Cory A. Black, Kevin H. Pardon, Patricia O. Williamson, Markus J. Herderich, and I. Leigh Francis.  2014. Determination of the Importance of In-Mouth Release of Volatile Phenol Glycoconjugates to the Flavor of Smoke-Tainted Wines. Journal of Agricultural and Food Chemistry  62 (11), 2327-2336
2. Hayasaka, Y., Parker, M., Baldock, G.A., Pardon, K.H., Black, C.A., Jeffery, D.W. and Herderich, M.J. (2013) Assessing the impact of smoke exposure in grapes: development and validation of a HPLC-MS/MS method for the quantitative analysis of smoke derived phenolic glycosides in grapes and wine. Journal of Agricultural and Food Chemistry 61, 25–33.
3. Krstic, M.P., Johnson, D.L. and Herderich, M.J. (2015) Review of smoke taint in wine: smoke-derived volatile phenols and their glycosidic metabolites in grapes and vines as biomarkers for smoke exposure and their role in the sensory perception of smoke taint. Australian Journal of Grape and Wine Research 21, 537–553.
4. Renata Ristic R., Lieke van der Hulst L., Dimitra L. Capone, and Kerry L. Wilkinson. Impact of Bottle Aging on Smoke-Tainted Wines from Different Grape Cultivars. 2017.
5. Journal of Agricultural and Food Chemistry 65 (20), 4146-4152

DOI:

Publication date: February 9, 2024

Issue: OENO Macrowine 2023

Type: Poster

Authors

Eric Hervé¹, Darren Gullick¹ , Azeem Hasan¹, Anindya Pradhan¹, Gordon Burns¹

1. ETS Laboratories, 899 Adams St. Suite A, St. Helena, CA 94574, USA

Contact the author*

Keywords

smoke impact, volatile phenols, glycosylated phenols

Tags

IVES Conference Series | oeno macrowine 2023 | oeno-macrowine

Citation

Related articles…

DO MICROPLASTICS IN VINEYARD SOIL AFFECT THE BIOAVAILABILITY OF VINE NUTRITION?

Microplastics can alter physicochemical and biogeochemical processes in the soil, but whether these changes have further effects on soil fertility, and if so, whether these effects vary depending on the type of soil in the vineyard and the type of plastic used in the vineyard. Knowing what types of plastics are currently used in vineyards in Slovenian viticultural regions as strings to tie vines to the stake, the aim of our study was to assess the effects of microplastic particles from polypropylene (PP) and polyvinyl chloride (PVC) on the availability of macro (potassium (K), Potassium (K), calcium (Ca), magnesium (Mg) and phosphate (P)) and micronutrients (iron (Fe), copper (Cu), manganese (Mn) and zinc (Zn)) in two vineyard soils contrasting in pH and mineralogy. For this purpose, a short-term soil incubation experiment (120 days) was carried out in which the soil samples were enriched with micro-PP and micro-PVC particles. After the incubation period, macro- and micronutrient availability were measured.

EXPLORING THE METABOLIC AND PHENOTYPIC DIVERSITY OF INDIGENOUS YEASTS ISOLATED FROM GREEK WINE

Climate change leads to even more hostile and stressful for the wine microorganism conditions and consequently issues with fermentation rate progression and off-character formation are frequently observed. The objective of the current research was to classify a great collection of yeast isolates from Greek wines based on their technological properties with oenological interest. Towards this direction, fourteen spontaneously fermented wines from different regions of Greece were collected for further yeast typing. The yeast isolates were subjected in molecular analyses and identification at species level.

PREVALENCE OF OAK-RELATED AROMA COMPOUNDS IN PREMIUM WINES

Barrel fermentation and barrel-ageing of wine are commonly utilised practices in premium wine production. The wine aroma compounds related to barrel contact are varied and can enhance a range of wine aromas and flavours, such as ‘struck flint’, ‘caramel’, ‘red berry’, ‘toasty’ and ‘nutty’, as well as conventional oaky characters such as ‘vanilla’, ‘spice’, ‘smoky’ and ‘coconut’. A survey of commercially produced premium Shiraz, Cabernet Sauvignon, Pinot Noir and Chardonnay wines was conducted, assessing the prevalence of compounds that have been proposed as barrel-ageing markers¹ including oak lactones, volatile phenols, furanones, aldehydes, thiazoles2,3, phenylmethanethiol⁴ and 2-furylmethanethiol.⁵

EXPLORING THE ROLE OF TRANSITION METAL IONS IN THE EVOLUTION OF ESTERS COMPOSITION OF YOUNG WHITE WINE DURING AGEING

Young white wines are typically released to the market a few months after harvest, to be consumed within a year, when their fresh fruity aromas are still dominant and appealing to modern consumers. Esters, particularly higher alcohol acetates (HAAs) and ethyl esters of fatty acids (EEFAs), play a central role in the fruity expression of young white wines [1]. However, these esters are known to undergo significant hydrolysis during the first months of aging [1, 2].

SENSORY EVALUATION OF WINE AROMA: SHOULD COLOR-DRIVEN DESCRIPTORS BE USED?

The vocabulary used to describe wine aroma is commonly organized according to color, raising the question of whether they reflect the reality of olfactory perception. Previous studies have assumed this convention of color-aroma matching, and have investigated color’s influence on the perception of aroma only in dyed white wine or in red wine from particular places of origin. Here 48 white and red varietal wines from around the world were evaluated in black glasses then in clear glasses by a panel of wine experts, who gave intensity ratings for aroma attributes commonly used by wine professionals. In black glasses, aromas conventionally associated with white wine were perceived in the red wines, and vice versa.