Macrowine 2021
IVES 9 IVES Conference Series 9 Impact of smoke exposure on the chemical composition of grapes

Impact of smoke exposure on the chemical composition of grapes

Abstract

Vineyard exposure to smoke can lead to grapes and wine which exhibit objectionable smoky and ashy aromas and flavours, more commonly known as ‘smoke taint’ [1, 2]. In the last decade, significant bushfires have occurred around the world, including near wine regions in Australia, Canada, South Africa and the USA, as a consequence of the warmer, drier conditions associated with climate change. Considerable research has subsequently been undertaken to determine the chemical, sensory and physiological consequences of grapevine exposure to smoke. The sensory attributes associated with smoke-tainted wine have been linked to the presence of several smoke-derived volatile phenols, such as guaiacols, syringols and cresols [2]. These volatile phenols have been shown to accumulate in grapes in glycoconjugate forms, following grapevine exposure to smoke [3, 4]. However, their mode of entry, and therefore the factors influencing their uptake from smoke by grapevine leaves and fruit, have not as yet, been adequately investigated. This study aimed to investigate the extent to which berry physiology, in particular, the development of the berry cuticle and epicuticular wax, influences the uptake of volatile compounds from smoke. Potted Chardonnay and Shiraz grapevines were exposed to smoke for 60 minutes, at approximately one week prior to maturity. Fruit samples were collected immediately after smoke treatment, and again at maturity (i.e. one week later), for imaging (using an environmental scanning electron microscope) to identify any differences in the physiology of control and smoke-affected berries. Fruit sampled at maturity was also analysed by gas chromatography-mass spectrometry and ultrahigh performance liquid chromatography-tandem mass spectrometry to determine concentrations of volatile phenols and their glycoconjugates, respectively. The potential for a commercial particle film, i.e. kaolin, to act as a protective barrier against smoke, was also investigated, by comparing the volatile phenol and glycoconjugate concentrations of fruit harvested from grapevines treated with kaolin and/or smoke.

Literature: 1. Kennison, K.R., et al., Smoke-derived taint in wine: The release of smoke-derived volatile phenols during fermentation of Merlot juice following grapevine exposure to smoke. Journal of Agricultural and Food Chemistry, 2008, 56(16): 7379-7383. 2. Parker, M., et al., Contribution of several volatile phenols and their glycoconjugates to smoke-related sensory properties of red wine. Journal of Agricultural and Food Chemistry, 2012, 60(10): 2629-2637. 3. Hayasaka, Y., et al., Identification of a beta-D-glucopyranoside precursor to guaiacol in grape juice following grapevine exposure to smoke. Analytica Chimica Acta, 2010, 660(1-2): 143-148. 4. Ristic, R., et al., The effect of winemaking techniques on the intensity of smoke taint in wine. Australian Journal of Grape and Wine Research, 2011, 17(2): S29-S40.

Publication date: May 17, 2024

Issue: Macrowine 2016

Type: Article

Authors

Lieke Van der Hulst*, Christopher Ford, Kerry Wilkinson, Natoiya Lloyd, Rachel Burton

*University of Adelaide

Contact the author

Tags

IVES Conference Series | Macrowine | Macrowine 2016

Citation

Related articles…

South Africa’s top 10 Sauvignon blanc wines. How do the chemical and sensory profiles compare?

FNB Top 10 Sauvignon Blanc competition, presented by the Sauvignon Blanc Interest Group of South Africa and sponsored by First National Bank, is the country’s foremost platform for producers of this cultivar to showcase and benchmark their wines. Wines entered in the competition originated from all over the winegrowing regions of the country and the winning wines showed good representation of quality South African Sauvignon blanc wines. The ten selected wines were subjected to various chemical analyses including volatile thiol and methoxypyrazine determination, while the sensory profile of each wine was determined using projective mapping.

Microbial life in the grapevine: what can we expect from the leaf microbiome?

The above-ground parts of plants, which constitute the phyllosphere, have long been considered devoid of bacteria and fungi, at least in their internal tissues and microbial presence there was long considered a sign of disease. However, recent studies have shown that plants harbour complex bacterial communities, the so-called “microbiome”[1]. We are only beginning to unravel the origin of these bacterial plant inhabitants, their community structure and their roles, which in analogy to the gut microbiome, are likely to be of essential nature. Among their multifaceted metabolic possibilities, bacteria have been recently demonstrated to emit a wide range of volatile organic compounds (VOCs), which can greatly impact the growth and development of both the plant and its disease-causing agents.

Monitoring of Pesticide Residues from Vine to Wine

Those previous years, pesticides are often brought to the forefront by media. Questions arose about their toxicity for growers and consumers. Even if a downward trend is underway, the use of pesticides is required to ensure steady quality and quantity of harvests. A large number of active ingredients are authorized but regarding viticulture, mainly insecticides and fungicides are applied, to control pests and diseases and to increase crop yield. Some phytosanitary products, principally fungicides, applied close to the harvest date may frequently be detected in wines.

Fingerprinting the origin of rosé wines with a new high throughput polyphenomics method

Wine is a widely consumed alcoholic beverage with a high commercial value. More specifically, the worldwide consumption of rosé wine has increased by 20% since 2002[1]. But because of its high commercial value, it can become a subject of fraud, and authenticity control is necessarily required. More than one hundred polyphenols have been recently quantified in various rosé wines [2]. They are key components defining color, taste and quality of wines. Their amount and composition depend on many different factors such as grape variety, winemaking and age of the wine. In this study, the influence of geographic origin of some rosé French wines was investigated. An original and very fast UPLC-QTOF-MS method was developed and used to predict the geographic origin authenticity of rosé wines.

WineMetrics: A new approach to unveil the “wine-like aroma” chemical feature

“The Human being has an excellent ability to detect and discriminate odors but typically has great difficulty in identifying specific odorants”(1). Furthermore, “from a cognitive point of view the mechanism used to judge wines is closer to pattern recognition than descriptive analysis.” Therefore, when one wants to reveal the volatile “wine-like feature” pattern recognition techniques are required. Sensomics is one of the most recent “omics”, i.e. a holistic perspective of a complex system, which deals with the description of substances originated from microorganism metabolism that are “active” to human senses (2). Depicting the relevant volatile fraction in wines has been an ongoing task in recent decades to which several research groups have allocated important resources. The most common strategy has been the “target approach” in order to identify the “key odorants” for a given wine varietal.