Macrowine 2021
IVES 9 IVES Conference Series 9 Impact of smoke exposure on the chemical composition of grapes

Impact of smoke exposure on the chemical composition of grapes

Abstract

Vineyard exposure to smoke can lead to grapes and wine which exhibit objectionable smoky and ashy aromas and flavours, more commonly known as ‘smoke taint’ [1, 2]. In the last decade, significant bushfires have occurred around the world, including near wine regions in Australia, Canada, South Africa and the USA, as a consequence of the warmer, drier conditions associated with climate change. Considerable research has subsequently been undertaken to determine the chemical, sensory and physiological consequences of grapevine exposure to smoke. The sensory attributes associated with smoke-tainted wine have been linked to the presence of several smoke-derived volatile phenols, such as guaiacols, syringols and cresols [2]. These volatile phenols have been shown to accumulate in grapes in glycoconjugate forms, following grapevine exposure to smoke [3, 4]. However, their mode of entry, and therefore the factors influencing their uptake from smoke by grapevine leaves and fruit, have not as yet, been adequately investigated. This study aimed to investigate the extent to which berry physiology, in particular, the development of the berry cuticle and epicuticular wax, influences the uptake of volatile compounds from smoke. Potted Chardonnay and Shiraz grapevines were exposed to smoke for 60 minutes, at approximately one week prior to maturity. Fruit samples were collected immediately after smoke treatment, and again at maturity (i.e. one week later), for imaging (using an environmental scanning electron microscope) to identify any differences in the physiology of control and smoke-affected berries. Fruit sampled at maturity was also analysed by gas chromatography-mass spectrometry and ultrahigh performance liquid chromatography-tandem mass spectrometry to determine concentrations of volatile phenols and their glycoconjugates, respectively. The potential for a commercial particle film, i.e. kaolin, to act as a protective barrier against smoke, was also investigated, by comparing the volatile phenol and glycoconjugate concentrations of fruit harvested from grapevines treated with kaolin and/or smoke.

Literature: 1. Kennison, K.R., et al., Smoke-derived taint in wine: The release of smoke-derived volatile phenols during fermentation of Merlot juice following grapevine exposure to smoke. Journal of Agricultural and Food Chemistry, 2008, 56(16): 7379-7383. 2. Parker, M., et al., Contribution of several volatile phenols and their glycoconjugates to smoke-related sensory properties of red wine. Journal of Agricultural and Food Chemistry, 2012, 60(10): 2629-2637. 3. Hayasaka, Y., et al., Identification of a beta-D-glucopyranoside precursor to guaiacol in grape juice following grapevine exposure to smoke. Analytica Chimica Acta, 2010, 660(1-2): 143-148. 4. Ristic, R., et al., The effect of winemaking techniques on the intensity of smoke taint in wine. Australian Journal of Grape and Wine Research, 2011, 17(2): S29-S40.

Publication date: May 17, 2024

Issue: Macrowine 2016

Type: Article

Authors

Lieke Van der Hulst*, Christopher Ford, Kerry Wilkinson, Natoiya Lloyd, Rachel Burton

*University of Adelaide

Contact the author

Tags

IVES Conference Series | Macrowine | Macrowine 2016

Citation

Related articles…

Study of the content of amino acids and biogenic amines in sparkling red wines

The production of red sparkling wines is lower in Spain in comparison with the winemaking of white or rosé sparkling wines. In red sparkling wine processing it is essential to obtain suitable base wines that should have moderate alcohol content, high acidity, good color values, an adequate mouth-feel and a sweet tannin. Grapes for sparkling wine production have to be harvested at low maturity stages, with lower alcohol contents and higher acidities, which will that the phenolic maturity of the grapes is also low, showing green tannins. This paper analyses different treatments in order to minimize these inconveniences: cold maceration-prefermentation and delestage to elaborate the grapes with lower maturity, must nanofiltration, and the partial osmosis of the wines made from grapes with an adequate maturity degree.

Comparative proteomic analysis of wines made from Botrytis cinerea infected and healthy grapes reveal interesting parallels to the gushing phenomenon in sparkling wine

In addition to aroma compounds also protein composition strongly influences the quality of wines. Proteins of wine derive mainly from the plant Vitis vinifera and may be influenced by abiotic stress as well as fermentation conditions or fining. Additionally, fungal infections can affect the protein content as well by introducing fungal proteins or affecting grape protein composition. An infection of the vine with the plant pathogenic fungus Botrytis (B.) cinerea was shown to cause a degradation of proteins in the resulting wine. Moreover, it influences the foaming properties in sparkling wine.

The effect of Nitrogen and Sulphur foliar applications in hot climates

ine nitrogen deficiency can negatively influence the aroma profile and ageing potential of white wines. Canopy management can alter vine microclimate, affect the nitrogen availability and influence the response of leaf senescence. Increasing the nitrogen availability to vines can increase the Yeast Assimilable Nitrogen (YAN) levels in harvested fruit and wine. Studies show that foliar nitrogen and sulphur applications at véraison, on low YAN Sauvignon blanc grapes have an effect on the level of amino acids (Jreij et al. 2009) and on S-containing compounds such as glutathione and thiols (Lacroux et al. 2008), which in turn can influence the formation of major volatiles and the aroma profile of the wine.

Petrolomics-derived data interpretation to study acetaldehyde-epicatechin condensation reactions

During red wine ageing or conservation, color and taste change and astringency tends to reduce. These changes result from reactions of flavan-3-ols and/or anthocyanins among which condensation reactions with acetaldehyde are particularly important. The full characterization of these reactions has not been fully achieved because of difficulties in extracting and separating the newly formed compounds directly from wine. Model solutions mimicking food products constitute a simplified medium for their exploration, allowing the detection of the newly formed compounds, their isolation, and their structure elucidation.

Influence of methyl jasmonate foliar application to vineyard on grape volatile composition over three consecutive vintages

An alternative to improve grape quality is the application to the vineyard of elicitors. Although these compounds were first used to increase resistance of plants against pathogens, it has been found that they are also able to induce mechanisms involved in the synthesis of phenolic compounds and some amino acids. However, researches about the influence of elicitors on grape volatile composition are scarcely. Therefore, the aim of this work was to study the influence of methyl jasmonate (MeJ) foliar application on grape aroma composition over three consecutive vintages. MeJ was applied to Tempranillo grapevines at a concentration of 10 mM in 2013, 2014, and 2015 years. Control plants were sprayed with water.