Macrowine 2021
IVES 9 IVES Conference Series 9 Contribution of Piperitone to the mint nuances perceived in the aging bouquet of red Bordeaux wines

Contribution of Piperitone to the mint nuances perceived in the aging bouquet of red Bordeaux wines

Abstract

During the tasting of a fine, old wine, the aromas generated in the glass are intertwined in an intimate, complex manner, expressing the fragrance of the aging bouquet. This aging bouquet, which develops during bottle storage through a complex transformation process, may result in a broad palette of nuances. Among these, undergrowth, truffle, toasted, spicy, licorice, fresh red- and black-berry fruit and mint descriptors were recently identified as features of its olfactory representation for red Bordeaux wines. Although a targeted chemical approach focusing on volatile sulfur compounds revealed the role played by dimethyl sulfide, 2-furanmethanethiol, and 3-sulfanylhexanol as molecular markers of the typicality of the wine aging bouquet of red Bordeaux wines, its chemical transcription has only partially been elucidated. As the aromatic signature of wine aging bouquet results in a complex mixture of odorants, reconstitution experiments represent a powerful strategy to provide confirmation of odorant identification and understand how sensory interactions between these aromatic compounds modify the overall perception of wine aroma. In that context, a multiple step approach, combining sensory evaluations of red Bordeaux wines and aromatic reconstitutions of wines extract fractions, was used to identify other molecular markers involved. One wine expressing both a high aging-bouquet score and a high mint nuance received particular attention. Various reconstitution and omission tests highlighted the contribution of two specific fractions to the perceived intensity of mint aroma. Then, gas-chromatography coupled to olfactometry and mass spectrometry was applied to those two targeted fractions to identify chemical compound(s) responsible for the mint nuance. A similar analytical process was applied to homologous fractions of minty essential oils to help in characterization and interpretation of the mass spectrometry data. This approach resulted in the detection of piperitone , a monoterpene ketone with an odor reminiscent of mint. The sensory importance of piperitone was also underlined, as its addition at levels found in wines produced an increase in the perceived intensity of the minty character, both in aromatic reconstitution and in wine. Interestingly, piperitone was found at significantly higher concentrations in wines with an aging bouquet, which highlighted for the first time its contribution to the positive mint aroma of fine aged red Bordeaux wines.

Publication date: May 17, 2024

Issue: Macrowine 2016

Type: Article

Authors

Magali Picard*, Georgia Lytra, Gilles De Revel, Jean-Christophe Barbe, Sophie Tempere, Stéphanie Marchand

*ISVV

Contact the author

Tags

IVES Conference Series | Macrowine | Macrowine 2016

Citation

Related articles…

DNA and type of grain: which factor does better explain sensory differences of sessile and pedunculate oaks?

Sessile oak and pedunculate oak have shown several differences of interest for enological purposes. Tannic and aromatic composition among sessile oak or pedonculate oak has been well studied. Sessile oak is generally more aromatic than pedunculated, while the later is more tannic. This scientific point of view is rarely applied to classify oak in cooperages. Most coopers use the type of grain to distinguish wide and thin grain.

Identification of green, aggressive and hard character of wines by a chemo-sensory directed methodology

With climate change, it is progressively more often to obtain grapes with an acceptable content in sugars or acids but with immature tannins described as green, aggressive or hard (noted as GAH onwards). During winemaking, the oenologist has to make decisions related to the elaboration of such grapes based mainly on empirical experience, given the lack of objective criteria to this concern. An increase in the chemical and sensory knowledge of immature tannins would allow managing this GAH character of grapes with the maximum possible efficiency during winemaking processes. The present work aims at isolating and identifying the group of compounds responsible for the GAH character present in wines.

The challenge of quality in sulphur dioxide free wines: natural polyphenol alternatives

Sulphur dioxide (SO2) seems indispensable in winemaking because of its properties. However, a current increasing concern about its allergies effects in food product has addressed the international research efforts on its replacement. This supposes a sufficient knowledge of its properties and conditions of use. Several studies compared SO2 properties against new alternatives that are supposed to overcome SO2 disadvantages. Firstly, the state of art on SO2 wine replacements is revised, and secondly, the last promising results using natural enriched polyphenol extracts are shown.

Extraction of pathogenesis-related proteins and phenolics in Sauvignon Blanc as affected by different

The composition of wine is largely determined by the composition of pre-fermentation juice, which is influenced by extraction of grape components. Different grape harvesting and processing conditions could affect the extraction of grape components into juice. Among these grape components, pathogenesis-related (PR) proteins are of great concern for white wine maker as they are the main cause of haze formation in finished white wine. If not removed before bottling, these PR proteins may progress into haze through the formation of complex with phenolics under certain conditions. Thaumatin-like proteins (TLPs) and chitinases are the main constituents of PR proteins found in protein haze.

Impact of heating must before fermentation on Chardonnay wines

Prefermentation steps of white winemaking are very important for controlling the stability and the sensory attributes of wines. Usually musts are clarified by cold settling to prevent the start of the fermentation, before racking big lees and thus limiting the appearance of vegetable or reduction off flavour while favouring an aromatic expression with low turbidity. Besides, to reach the protein stability, some white wines further require a bentonite fining, sometimes associated with negative effects on the sensory quality. This study aims to know the impact of musts heating after pressing on a Chardonnay wine in northern conditions by comparison with a classic cold racking of the must.