Macrowine 2021
IVES 9 IVES Conference Series 9 Contribution of Piperitone to the mint nuances perceived in the aging bouquet of red Bordeaux wines

Contribution of Piperitone to the mint nuances perceived in the aging bouquet of red Bordeaux wines

Abstract

During the tasting of a fine, old wine, the aromas generated in the glass are intertwined in an intimate, complex manner, expressing the fragrance of the aging bouquet. This aging bouquet, which develops during bottle storage through a complex transformation process, may result in a broad palette of nuances. Among these, undergrowth, truffle, toasted, spicy, licorice, fresh red- and black-berry fruit and mint descriptors were recently identified as features of its olfactory representation for red Bordeaux wines. Although a targeted chemical approach focusing on volatile sulfur compounds revealed the role played by dimethyl sulfide, 2-furanmethanethiol, and 3-sulfanylhexanol as molecular markers of the typicality of the wine aging bouquet of red Bordeaux wines, its chemical transcription has only partially been elucidated. As the aromatic signature of wine aging bouquet results in a complex mixture of odorants, reconstitution experiments represent a powerful strategy to provide confirmation of odorant identification and understand how sensory interactions between these aromatic compounds modify the overall perception of wine aroma. In that context, a multiple step approach, combining sensory evaluations of red Bordeaux wines and aromatic reconstitutions of wines extract fractions, was used to identify other molecular markers involved. One wine expressing both a high aging-bouquet score and a high mint nuance received particular attention. Various reconstitution and omission tests highlighted the contribution of two specific fractions to the perceived intensity of mint aroma. Then, gas-chromatography coupled to olfactometry and mass spectrometry was applied to those two targeted fractions to identify chemical compound(s) responsible for the mint nuance. A similar analytical process was applied to homologous fractions of minty essential oils to help in characterization and interpretation of the mass spectrometry data. This approach resulted in the detection of piperitone , a monoterpene ketone with an odor reminiscent of mint. The sensory importance of piperitone was also underlined, as its addition at levels found in wines produced an increase in the perceived intensity of the minty character, both in aromatic reconstitution and in wine. Interestingly, piperitone was found at significantly higher concentrations in wines with an aging bouquet, which highlighted for the first time its contribution to the positive mint aroma of fine aged red Bordeaux wines.

Publication date: May 17, 2024

Issue: Macrowine 2016

Type: Article

Authors

Magali Picard*, Georgia Lytra, Gilles De Revel, Jean-Christophe Barbe, Sophie Tempere, Stéphanie Marchand

*ISVV

Contact the author

Tags

IVES Conference Series | Macrowine | Macrowine 2016

Citation

Related articles…

Sensory impacts of the obturator used for the Chasselas: study over the time

Many parameters affect the organoleptic characteristics of wine: internal parameters like the chemical composition or polyphenol content and external as for example storage conditions or the type of obturator. The aim of this study was to characterize sensorally the impacts of several type of obturator on a white wine: Chasselas. To determine the organoleptic characteristics of this wine, a quantitative descriptive analysis could be used. But rapid sensory methods were preferred in this project. Indeed these methods are an appropriate alternative to conventional descriptive methods for quickly assessing sensory product discrimination.

Use of glutathione under different grape processing and winemaking conditions and its impact on the formation of sulfide off-flavors, colour, and sensory characteristics of Riesling, Sauvignon blanc, and Chardonnay

The use of glutathione (GSH) in winemaking has been legitimated recently, according to OIV resolutions OENO 445-2015 and OENO 446-2015 a maximum dose of 20 mg/L is now allowed to use in must and wine. Several studies have proven the benefits of GSH, predominantly in Sauvignon blanc. Thus, oxidative coloration of must and wine is limited, aroma compounds such as volatile thiols are preserved, and the development of ageing flavors such as sotolon and 2-aminoacetophenone is impeded. The protective effect may be explained by the high affinity of GSH to bind o-quinones which are formed during phenolic oxidation and which are known to initiate browning and other oxidative changes. Some researchers have proposed the hydroxycinnamic acid to GSH ratio (HGR) as an indicator of oxidation susceptibility of must and could show that lower ratios yielded lighter musts.

HEAT BERRY : Sensitivity of berries ripening to higher temperature and impact on phenolic compounds in wine

The grapevine is an important economical crop that is very sensitive to climate changes and microclimate. The observations made during the last decades at a vineyard scale all concur to show the impact of climate change on vine physiology, resulting in accelerated phenology and earlier harvest (Jones and Davis 2000). It is well-known that berry content is affected by the ambient temperature. While the first experiences were primarily conducted on the impact of temperature on anthocyanin accumulation in the grape, few studies have focused on others component of phenolic metabolism, such as tannins.

Merging fast sensory profiling with non-targeted GC-MS analysis for multifactorial experimental wine making

Wine aroma is influenced by several viticultural and oenological factors. In this study we used experimental wine making in a full factorial design to determine the impact of grapevine age, must turbidity, and yeast strain on the aroma of Vitis vinifera L. cv. Riesling wines. A recently developed, non-targeted SPME-GC-MS fingerprinting approach for wine volatiles was used. This approach includes the segmentation and mathematical transformation of chromatograms in combination with Parallel Factor Analysis (PARAFAC) and subsequent deconvolution of important chromatogram segments.

Metabolomics of grape polyphenols as a consequence of post-harvest drying: on-plant dehydration vs warehouse withering

A method of suspect screening analysis to study grape metabolomics, was developed [1]. By performing ultra-high performance liquid chromatography (UHPLC) – high-resolution mass spectrometry (HRMS) analysis of the grape extract, averaging 320-450 putative grape compounds are identified which include mainly polyphenols. Identification of metabolites is performed by a new HRMS-database of putative grape and wine compounds expressly constructed (GrapeMetabolomics) which currently includes around 1,100 entries.