Macrowine 2021
IVES 9 IVES Conference Series 9 Contribution of Piperitone to the mint nuances perceived in the aging bouquet of red Bordeaux wines

Contribution of Piperitone to the mint nuances perceived in the aging bouquet of red Bordeaux wines

Abstract

During the tasting of a fine, old wine, the aromas generated in the glass are intertwined in an intimate, complex manner, expressing the fragrance of the aging bouquet. This aging bouquet, which develops during bottle storage through a complex transformation process, may result in a broad palette of nuances. Among these, undergrowth, truffle, toasted, spicy, licorice, fresh red- and black-berry fruit and mint descriptors were recently identified as features of its olfactory representation for red Bordeaux wines. Although a targeted chemical approach focusing on volatile sulfur compounds revealed the role played by dimethyl sulfide, 2-furanmethanethiol, and 3-sulfanylhexanol as molecular markers of the typicality of the wine aging bouquet of red Bordeaux wines, its chemical transcription has only partially been elucidated. As the aromatic signature of wine aging bouquet results in a complex mixture of odorants, reconstitution experiments represent a powerful strategy to provide confirmation of odorant identification and understand how sensory interactions between these aromatic compounds modify the overall perception of wine aroma. In that context, a multiple step approach, combining sensory evaluations of red Bordeaux wines and aromatic reconstitutions of wines extract fractions, was used to identify other molecular markers involved. One wine expressing both a high aging-bouquet score and a high mint nuance received particular attention. Various reconstitution and omission tests highlighted the contribution of two specific fractions to the perceived intensity of mint aroma. Then, gas-chromatography coupled to olfactometry and mass spectrometry was applied to those two targeted fractions to identify chemical compound(s) responsible for the mint nuance. A similar analytical process was applied to homologous fractions of minty essential oils to help in characterization and interpretation of the mass spectrometry data. This approach resulted in the detection of piperitone , a monoterpene ketone with an odor reminiscent of mint. The sensory importance of piperitone was also underlined, as its addition at levels found in wines produced an increase in the perceived intensity of the minty character, both in aromatic reconstitution and in wine. Interestingly, piperitone was found at significantly higher concentrations in wines with an aging bouquet, which highlighted for the first time its contribution to the positive mint aroma of fine aged red Bordeaux wines.

Publication date: May 17, 2024

Issue: Macrowine 2016

Type: Article

Authors

Magali Picard*, Georgia Lytra, Gilles De Revel, Jean-Christophe Barbe, Sophie Tempere, Stéphanie Marchand

*ISVV

Contact the author

Tags

IVES Conference Series | Macrowine | Macrowine 2016

Citation

Related articles…

Proteomic and activity characterization of exocellular laccases from three Botrytis cinerea strains

Botrytis cinerea is a fungus that causes common infection in grapes and other fruits. In winemaking, its presence can be both considered desirable in the case of noble rot infection or undesirable when grey rot is developed. This fungus produces an extracellular enzyme known as laccase which is able to cause oxidation of phenolic compounds present in must and wine, causing most of the times a decrease in its quality and problems during the winemaking process [1]. Material and methods: Three B. cinerea strains (B0510, VA612 and RM344) were selected and grown in a liquid medium adapted from one previously described [2]. The enzyme was isolated by tangential ultrafiltration of the culture medium using a QuixStand system equipped with a 30 KDa filtration membrane.

Petrolomics-derived data interpretation to study acetaldehyde-epicatechin condensation reactions

During red wine ageing or conservation, color and taste change and astringency tends to reduce. These changes result from reactions of flavan-3-ols and/or anthocyanins among which condensation reactions with acetaldehyde are particularly important. The full characterization of these reactions has not been fully achieved because of difficulties in extracting and separating the newly formed compounds directly from wine. Model solutions mimicking food products constitute a simplified medium for their exploration, allowing the detection of the newly formed compounds, their isolation, and their structure elucidation.

Effects of a new vacuum evaporation method on chemical and sensory properties of must and wine

A new process for vacuum evaporation was developed where evaporation takes place near the inner surface of a vortex produced by a rotor submerged in the liquid. Contrary to the state of the art the Vortex rotor process does not need a vacuum vessel but the rotating liquid creates a geometrically stable low pressure void surrounded by a vortex stabilized by the equilibrium between centrifugal forces and the pressure difference. First tests with water and sugar solutions at concentrations similar to grape must were conducted to verify the theoretical predictions, test the performance under different conditions and study the effect of various process parameters (Rösti et al 2015).

Sensory impacts of the obturator used for the Chasselas: study over the time

Many parameters affect the organoleptic characteristics of wine: internal parameters like the chemical composition or polyphenol content and external as for example storage conditions or the type of obturator. The aim of this study was to characterize sensorally the impacts of several type of obturator on a white wine: Chasselas. To determine the organoleptic characteristics of this wine, a quantitative descriptive analysis could be used. But rapid sensory methods were preferred in this project. Indeed these methods are an appropriate alternative to conventional descriptive methods for quickly assessing sensory product discrimination.

Simultaneous monitoring of dissolved CO2 and collar from Rosé sparkling wine glasses: the impact of yeast macromolecules

Champagne or sparkling wines elaborated through the same traditional method, which consists in two major yeast-fermented steps, typically hold about 10 to 12 g/L of dissolved CO2 after the second fermentation in a closed bottle. Hundreds of molecules and macromolecules originating from grape and yeast cohabit with dissolved CO2; they are essential compounds contributing to many organoleptic characteristics (effervescence, foam, aroma, taste, colour…). Indeed, the second alcoholic fermentation and the maturation on lees (which may last from 12 months up to several years) both induce various quantitative and qualitative changes in the wine through the action of yeast, as listed hereafter: development of aromas during aging on lees, release of nitrogen compounds during autolysis and release of macromolecules (polysaccharides, lipids, nucleic acids) in wine.