Macrowine 2021
IVES 9 IVES Conference Series 9 Contribution of Piperitone to the mint nuances perceived in the aging bouquet of red Bordeaux wines

Contribution of Piperitone to the mint nuances perceived in the aging bouquet of red Bordeaux wines

Abstract

During the tasting of a fine, old wine, the aromas generated in the glass are intertwined in an intimate, complex manner, expressing the fragrance of the aging bouquet. This aging bouquet, which develops during bottle storage through a complex transformation process, may result in a broad palette of nuances. Among these, undergrowth, truffle, toasted, spicy, licorice, fresh red- and black-berry fruit and mint descriptors were recently identified as features of its olfactory representation for red Bordeaux wines. Although a targeted chemical approach focusing on volatile sulfur compounds revealed the role played by dimethyl sulfide, 2-furanmethanethiol, and 3-sulfanylhexanol as molecular markers of the typicality of the wine aging bouquet of red Bordeaux wines, its chemical transcription has only partially been elucidated. As the aromatic signature of wine aging bouquet results in a complex mixture of odorants, reconstitution experiments represent a powerful strategy to provide confirmation of odorant identification and understand how sensory interactions between these aromatic compounds modify the overall perception of wine aroma. In that context, a multiple step approach, combining sensory evaluations of red Bordeaux wines and aromatic reconstitutions of wines extract fractions, was used to identify other molecular markers involved. One wine expressing both a high aging-bouquet score and a high mint nuance received particular attention. Various reconstitution and omission tests highlighted the contribution of two specific fractions to the perceived intensity of mint aroma. Then, gas-chromatography coupled to olfactometry and mass spectrometry was applied to those two targeted fractions to identify chemical compound(s) responsible for the mint nuance. A similar analytical process was applied to homologous fractions of minty essential oils to help in characterization and interpretation of the mass spectrometry data. This approach resulted in the detection of piperitone , a monoterpene ketone with an odor reminiscent of mint. The sensory importance of piperitone was also underlined, as its addition at levels found in wines produced an increase in the perceived intensity of the minty character, both in aromatic reconstitution and in wine. Interestingly, piperitone was found at significantly higher concentrations in wines with an aging bouquet, which highlighted for the first time its contribution to the positive mint aroma of fine aged red Bordeaux wines.

Publication date: May 17, 2024

Issue: Macrowine 2016

Type: Article

Authors

Magali Picard*, Georgia Lytra, Gilles De Revel, Jean-Christophe Barbe, Sophie Tempere, Stéphanie Marchand

*ISVV

Contact the author

Tags

IVES Conference Series | Macrowine | Macrowine 2016

Citation

Related articles…

Correlations between sensory characteristics and colloidal content in dry white wines

Must clarification is an important step occurring just after grape extraction in the elaboration of white wine, consisting in a solid-liquid separation. Traditionally, low must turbidity, around 50-150 NTU, is generally reached in white winemaking in order to prevent reductive aromas and facilitating alcoholic fermentation. Alternatively, a higher turbidity (300 NTU or above) can be sought for reasons such as a better expression of grapes identity (terroir), or for getting a must matrix that could supposedly lead to wines having greater ageing potential.

Supramolecular approaches to the study of the astringency elicited by wine phenolic compounds

The objective of this study is to review the scientific evidences and to advance into the knowledge of the molecular mechanisms of astringency. Astringency has been described as the drying, roughing and puckering sensation perceived when some food and beverages are tasted (1). The main, but possibly not the only, mechanism for the astringency is the precipitation of salivary proteins (2,3). Between phenolic compounds found in red wines, flavan-3-ols are the group usually related to the development of this sensation. Other compounds, phenolic or not, like anthocyanins, polysaccharides and mannoproteins could act modifying or modulating astringency perception by hindering the interaction between flavanols and salivary proteins either because of their interaction with the flavanols or because of their interaction with the salivary proteins.

The influence of soil management practices on functional traits and biodiversity of weed communities in Swiss vineyards

Green cover in vine rows provides many ecological services, but can also negatively impact the crop, depending on the weed species. The composition of a vineyard weed community is influenced by many parameters. Ensuring an evolution of the vine row flora into a desired direction is therefore very complex. A key step towards this goal is to know which factors influence the establishment of the weed community and which types of communities are best suited for vineyards. In this study, we analysed the weed communities of several vineyards in the Lake Geneva region (379 botanical surveys on 117 plots), with the aim to highlight the links between soil management practices (chemical and mechanical weeding, mowing, mulching roll) and phytosociological profiles, biodiversity and selected functional traits (growth forms, life strategies, root depth). T

Innovations in the use of bentonite in enology: interactions with grape and wine proteins, colloids, polyphenols and aroma compounds.

The use of bentonite in oenology rounds around the limpidity and the stability that determine consumer acceptability. As a matter of fact, the haze formation in wine reduces its commercial value and makes it unacceptable for sale. Stabilization treatments are, therefore, essential to ensure a long-time limpidity and to forecast the formation of deposits in the bottle. Bentonite that is normally used in oenology for clarifying-fining purpose, shows a natural clay-based mineral structure allowing it to swell and to jelly in water and hence in must and wine.

Attractiveness and sweetness of red wines: Synergies between American oak barrels and mannoproteins

In partnership with a Bordeaux property wanting to improve the quality of its second wine, the effects of two factors, American oak barrels and mannoproteins were studied. Their impact on the attractiveness and sweetness of wines were characterized during two successive vintages (2012 and 2013). Vinification took place with a homogeneous batch of Cabernet Sauvignon. The wine was then divided up into various groups of five barrels of French and American oak, new or reused. Analyses of volatile and non-volatile wood compounds were undertaken at four months and eight months of wood ageing, by LC-MS and GC-MS.