Macrowine 2021
IVES 9 IVES Conference Series 9 Impact of elemental sulfur (S0) residues in Sauvignon blanc juice on the formation of the varietal thiols 3-mercapto hexanol and 3-mercaptohexyl acetate

Impact of elemental sulfur (S0) residues in Sauvignon blanc juice on the formation of the varietal thiols 3-mercapto hexanol and 3-mercaptohexyl acetate

Abstract

Elemental sulfur is a fungicide used by grape growers to control the development of powdery mildew, caused by the fungus Erysiphe necator. This compound is effective, cheap and has a low toxicity with no withholding period recommended. However, high levels of S0 residues in the harvested grapes can lead to the formation of reductive sulfur compounds that can impart taints and faults to the wine. Hydrogen sulphide (H2S) is a very volatile and unpleasant sulfur compound which formation is connected to high residues of S0 in juice (10 – 100 mg/L). These residues can be minimized with pressing and clarification of the juice prior to fermentation, but may increase during prolonged maceration. At the same time, H2S can play a role on the formation of the important varietal thiols 3-mercapto hexanol (3MH) and 4-mercapto-4-methylpentan-2-one (4MMP) as the direct sulfur donor to E-2-hexenal or mesityl oxide, respectively. Sauvignon blanc juices from three different locations was obtained at a commercial winery in Marlborough, New Zealand. One sample (A) was collected from the receival bin and pressed to obtain 25 L of juice. Two other samples (B and C) were collected from the commercial pressing operation. The samples were cold settled, racked to glass bottles (700 mL of juice), and then 0, 2, 10 or 50 mg/L of a wettable elemental sulfur compound was added. The fermentation was carried out using Saccharomyces cerevisiae (EC1118) at 15°C. The juices showed quite different potential to produce 3MH and 3MHA, and without any added sulfur, juice A produced a high amount of 3MH (6,000 ng/L), while juices B and C showed signs of oxidation and little 3MH was formed (< 600 ng/L). The addition of 50 mg/L of elemental sulfur caused a 1.7-fold increment in 3MH for juice A. For juice B detectable levels of 3MH and 3MHA were only observed for the extreme addition of 50 mg/L S0, which led to a 20-fold increase in 3MH production for juice C. Even though the results showed a clear relation between S0 in juice and varietal thiols in wine, the deliberate increase in the fungicide use close to harvest needs to be carefully managed, as levels of unwanted reductive sulfur compounds including H2S, methanethiol and carbon disulfide in the final wine were found to increase with the higher elemental sulfur additions.

Publication date: May 17, 2024

Issue: Macrowine 2016

Type: Poster

Authors

Leandro Dias Araujo*, Bruno Fedrizzi, Paul Kilmartin, Suzanne Callerot, Wessel du Toit

*University of Auckland

Contact the author

Tags

IVES Conference Series | Macrowine | Macrowine 2016

Citation

Related articles…

Update knowledge about the presence of condensed tannins in grapes and their contributions to astringency perception

Condensed tannin is a principle group of polyphenol compounds derived from grape, greatly contributing to the bioactivity and the sensory perception of wine. Condensed tannins present as a heterogeneous mixture in nature involving various degrees of both polymerization and galloylation. Even though multiple attempts focusing on fractionation of grape condensed tannins by solid-phase have been conducted over the past decades, few individual tannins have been purified and identified. Hence, our knowledge on grape and wine condensed tannin moleculars has to be limited at the several known monomeric, dimeric and trimeric proanthocyanidins

Effects of a new vacuum evaporation method on chemical and sensory properties of must and wine

A new process for vacuum evaporation was developed where evaporation takes place near the inner surface of a vortex produced by a rotor submerged in the liquid. Contrary to the state of the art the Vortex rotor process does not need a vacuum vessel but the rotating liquid creates a geometrically stable low pressure void surrounded by a vortex stabilized by the equilibrium between centrifugal forces and the pressure difference. First tests with water and sugar solutions at concentrations similar to grape must were conducted to verify the theoretical predictions, test the performance under different conditions and study the effect of various process parameters (Rösti et al 2015).

Mean polymerization degree of proanthocyanidins of grape seeds, skins and wines from Agiorgitiko (cv. Vitis vinifera): Differences among vintages

Grape phenolic compounds are very important constituents of red wine because, in addition to their antioxidant properties, they contribute to color, astringency and bitterness, oxidation reactions, interactions with proteins and ageing behavior of wines. The aim of our study was to assess the structural characteristics of grape and wine proanthocyanidins of Agiorgitiko variety and to evaluate the influence of the vintage year. Twelve vineyard locations were designated in the Nemea wine region. For three consecutive years (2012-2014), the grapes were harvested at technological maturity and the method of phloroglucinolysis was employed to determine the mean degree of polymerization (mDP) and subunit composition of the samples.

Use of computational modelling for selecting adsorbents for improved fining of wine

The occurrence of faults and taints in wine, such as those caused by microbial spoilage or various taints, have resulted in significant financial losses to wine producers. The wine industry commits significant financial resources towards fining and taint removal processes each year. Fining involves the addition of one or more adsorptive substrates to juice or wine to bind certain components, thus reducing their concentration [1]. However, these processes are often not selective and can also remove desirable flavour and aroma compounds.

Characterization of commercial enological tannins and its effect on human saliva diffusion

Commercial oenological tannins (TECs) are widely used in the wine industry. TECs are rich in condensed tannins, hydrolyzable tannins or a mixture of both. Wine grapes are a important source of proanthocyanidins or condensed tannins while oak wood possess a high concentration of hydrolyzable tannins (Obreque-Slier et al., 2009). TECs contribute with the antioxidant capacity of wine, catalyze oxide-reduction reactions and participate in the removal of sulfur compounds and metals.