Macrowine 2021
IVES 9 IVES Conference Series 9 Innovations in the use of bentonite in enology: interactions with grape and wine proteins, colloids, polyphenols and aroma compounds.

Innovations in the use of bentonite in enology: interactions with grape and wine proteins, colloids, polyphenols and aroma compounds.

Abstract

The use of bentonite in oenology rounds around the limpidity and the stability that determine consumer acceptability. As a matter of fact, the haze formation in wine reduces its commercial value and makes it unacceptable for sale. Stabilization treatments are, therefore, essential to ensure a long-time limpidity and to forecast the formation of deposits in the bottle. Bentonite that is normally used in oenology for clarifying-fining purpose, shows a natural clay-based mineral structure allowing it to swell and to jelly in water and hence in must and wine. The exchangeable cations in its lamellar structures strongly influence some properties, like, for instance, the specific surface, the exchange capacity, as well as the adsorption behaviour. The interactions with haze forming proteins, other colloids, as well as aroma compounds and polyphenols would have been to discover as the modulation of wine colloids by an adjuvant severely affects the wine sensory profile. Body Oenologists do not really know on which parameters they have to focus for the choice of the bentonite targeted at gaining both the desired degree of limpidity and stability coupled with the avoiding of undesirable side effects. In this field, the authors have carried out many scientific and technical activities that led to detect: -The proteins targeted by the bentonite; -The endogenous allergenic wine compounds that are removed by bentonite; -The effect of protein origin, content, and pH toward wine colloidal (heat) stability; -The bentonite optimization for red wine fining; -The bentonite side effects on polyphenols and colour; -The interactions with the free- and glycosylated-varietal aroma in musts and wines; -The removal of fermentative aroma according to the wine aging, colloids and protein content; -The adsorption mechanism and modelling of wine aroma compounds onto bentonite. Conclusion The role of bentonite added to settling juices and/or to fining wine was not fully clear. This work collects several studies from authors focusing on the impact of several commercial bentonite samples, used for both juice clarification and wine fining, on the colloids, proteins, polyphenols and aroma compounds of white and red wines. Some parameters of practical value, such as the heat-stability of colloids, the concentration of total and haze-forming proteins, the content of the most relevant varietal and fermentative aroma were assessed to track bentonite effects and to achieve findings that are immediately applicable in the field of oenology.

Publication date: May 17, 2024

Issue: Macrowine 2016

Type: Poster

Authors

Milena Lambri*, Dante Marco De Faveri, Donato Colangelo, Fabrizio Torchio

*UCSC

Contact the author

Tags

IVES Conference Series | Macrowine | Macrowine 2016

Citation

Related articles…

Impact of industrial-scale serial filtration on macromolecules in red wines

Filtration is a critical step in ensuring the clarity and microbial stability of wine prior to bottling. However the process of filtering potentially reduces red wine quality by removing some of the macromolecules that contribute to the texture of the wine. Commercial red wines, Cabernet Sauvignon (CAS) and Shiraz (SHZ), of two vintages and two grades (premium grade wines from the older vintage: CAS13 and SHZ13; and standard grade wines from a younger vintage: CAS14 and SHZ14) were filtered through industrial-scale commercial filtration units prior to bottling. Samples were taken before and after cross-flow filtration, lenticular filters, 0.65 µm and 0.45 µm pore size nylon membrane filters. The concentration and composition of macromolecules, including tannins and polysaccharides, were measured in all samples as well as particle size distribution and wine colour.

Multivariate strategies for red wines classification using stilbenes and flavonols content

Bioactive polyphenols from grapes and wines, like stilbenes and flavonols (SaF), are often determined to nutritional evaluation, but also for many other purposes. The objective of this study was to quantify SaF in red wines from “Campanha Gaúcha”, a large and young viticultural region from South Brazil. Moreover, through statistical analysis, evaluate the influence of these compounds according to varieties, production process, harvest years and micro-regions of cultivation. A total of 58 samples of red wines were analyzed by high-performance liquid chromatography coupled to diode array detector (HPLC-DAD) for determination of trans-resveratrol (R), quercetin (Q), myricetin (M), kaempferol (K), trans-e-viniferin (V) and their precursor, cinnamic acid (C).

Impact of non-fruity compounds on red wines fruity aromatic expression: the role of higher alcohols

A part, at least, of the fruity aroma of red wines is the consequence of perceptive interactions between various aromatic compounds, particularly ethyl esters and acetates, which may contribute to the perception of fruity aromas, specifically thanks to synergistic effects.1,2 The question of the indirect impact of non-fruity compounds on this particular aromatic expression has not yet been widely investigated. Among these compounds higher alcohols (HA) represent the main group, from a quantitative standpoint, of volatiles in many alcoholic beverages. Moreover, some bibliographic data suggested their contribution to the aromatic complexity by either increasing or masking flavors of wine, depending of their concentrations.

DNA and type of grain: which factor does better explain sensory differences of sessile and pedunculate oaks?

Sessile oak and pedunculate oak have shown several differences of interest for enological purposes. Tannic and aromatic composition among sessile oak or pedonculate oak has been well studied. Sessile oak is generally more aromatic than pedunculated, while the later is more tannic. This scientific point of view is rarely applied to classify oak in cooperages. Most coopers use the type of grain to distinguish wide and thin grain.

Elicitors used as a tool to increase stilbenes in grapes and wines

The economic importance of grapevine as a crop plant makes Vitis vinífera a good model system to study the improvement of the nutraceutical properties of food products (Vezulli et al. 2007). Stilbenes in general, and trans-resveratrol in particular, have been reported to be responsible for various beneficial effects. Resveratrol´s biological properties include antibacteria and antifungal effects, as well as cardioprotective, neuroprotective and anticâncer actions (Guerrero et al. 2010 ). Stilbenes can be induced by biotic and abiotic elicitors since they are phytoalexins (Bavaresco et al. 2001).