Macrowine 2021
IVES 9 IVES Conference Series 9 Innovations in the use of bentonite in enology: interactions with grape and wine proteins, colloids, polyphenols and aroma compounds.

Innovations in the use of bentonite in enology: interactions with grape and wine proteins, colloids, polyphenols and aroma compounds.

Abstract

The use of bentonite in oenology rounds around the limpidity and the stability that determine consumer acceptability. As a matter of fact, the haze formation in wine reduces its commercial value and makes it unacceptable for sale. Stabilization treatments are, therefore, essential to ensure a long-time limpidity and to forecast the formation of deposits in the bottle. Bentonite that is normally used in oenology for clarifying-fining purpose, shows a natural clay-based mineral structure allowing it to swell and to jelly in water and hence in must and wine. The exchangeable cations in its lamellar structures strongly influence some properties, like, for instance, the specific surface, the exchange capacity, as well as the adsorption behaviour. The interactions with haze forming proteins, other colloids, as well as aroma compounds and polyphenols would have been to discover as the modulation of wine colloids by an adjuvant severely affects the wine sensory profile. Body Oenologists do not really know on which parameters they have to focus for the choice of the bentonite targeted at gaining both the desired degree of limpidity and stability coupled with the avoiding of undesirable side effects. In this field, the authors have carried out many scientific and technical activities that led to detect: -The proteins targeted by the bentonite; -The endogenous allergenic wine compounds that are removed by bentonite; -The effect of protein origin, content, and pH toward wine colloidal (heat) stability; -The bentonite optimization for red wine fining; -The bentonite side effects on polyphenols and colour; -The interactions with the free- and glycosylated-varietal aroma in musts and wines; -The removal of fermentative aroma according to the wine aging, colloids and protein content; -The adsorption mechanism and modelling of wine aroma compounds onto bentonite. Conclusion The role of bentonite added to settling juices and/or to fining wine was not fully clear. This work collects several studies from authors focusing on the impact of several commercial bentonite samples, used for both juice clarification and wine fining, on the colloids, proteins, polyphenols and aroma compounds of white and red wines. Some parameters of practical value, such as the heat-stability of colloids, the concentration of total and haze-forming proteins, the content of the most relevant varietal and fermentative aroma were assessed to track bentonite effects and to achieve findings that are immediately applicable in the field of oenology.

Publication date: May 17, 2024

Issue: Macrowine 2016

Type: Poster

Authors

Milena Lambri*, Dante Marco De Faveri, Donato Colangelo, Fabrizio Torchio

*UCSC

Contact the author

Tags

IVES Conference Series | Macrowine | Macrowine 2016

Citation

Related articles…

Estimation of chemical age of red wines with the use of Fourier transform infrared spectroscopy (FT-IR) and chemometrics

The color of a red wine is one of the most important parameters of its quality, giving much information on its status, such as the grape variety used or the winemaking style. As the result of a complex equilibrium between different forms of anthocyanins and polymerization reactions which occur over the course of time, color can also serve as an indication of a wines’ age. For this purpose the “chemical age” i and ii indexes have been introduced by Somers in 1977. The chemical age index i measures the color absorbance after the addition of acetaldehyde while chemical index ii provides an indication of how much of the total red pigments are resistant to SO2 bleaching.

A multivariate approach using attenuated total reflectance mid-infrared spectroscopy to measure the surface mannoproteins and β-glucans of yeast cell walls during wine fermentations

Yeast cells possess a cell wall comprising primarily glycoproteins, mannans, and glucan polymers. Several yeast phenotypes relevant for fermentation, wine processing, and wine quality are correlated with cell wall properties. To investigate the effect of wine fermentation on cell wall composition, a study was performed using mid-infrared (MIR) spectroscopy coupled with multivariate methods (i.e., PCA and OPLS-DA). A total of 40 yeast strains were evaluated, including Saccharomyces strains (laboratory and industrial) and non-Saccharomyces species. Cells were fermented in both synthetic MS300 and Chardonnay grape must to stationery phase, processed, and scanned in the MIR spectrum.

Impact of heating must before fermentation on Chardonnay wines

Prefermentation steps of white winemaking are very important for controlling the stability and the sensory attributes of wines. Usually musts are clarified by cold settling to prevent the start of the fermentation, before racking big lees and thus limiting the appearance of vegetable or reduction off flavour while favouring an aromatic expression with low turbidity. Besides, to reach the protein stability, some white wines further require a bentonite fining, sometimes associated with negative effects on the sensory quality. This study aims to know the impact of musts heating after pressing on a Chardonnay wine in northern conditions by comparison with a classic cold racking of the must.

Intelligent article to control the internal pressure in continue in bottles

An intelligent packaging might, among others, provide information and allow monitoring of the quality of the packed product or its surrounding environment. A recent project on micro-flow wine bottles closed with aluminium screw cap and tightness liner, highlighted the importance of monitoring the internal overpressure continuously, in real-time and at least for 72 hours, since the internal pressure on the tightness liner and the micro-flow are related. Real-time and continuous measurements are not the standard methods of measurement of the overpressure, yet. The most used equipment for the determination of the pressure in wine bottle is the aphrometer, a destructive device that supplies a single value of pressure.

Ripening of cv. Cabernet Sauvignon grapes: polysaccharides fractions evolution and phenolic extractability

Polysaccharides and more specifically pectins, make up a significant portion of the cell wall material of the plant cells including the grapes. During the fruit ripening the associated softening is related to the breakdown of the cell wall polysaccharides. During this process, it is expected that polysaccharides that are soluble in red wine will be formed influencing its texture. Anthocyanins are responsible for the wine color and tannins for the astringency, body and bitterness of the wine. In the skins, these compounds are located in the cell vacuoles and the barrier that conditions their extractability is the skin cell wall that may determine the mechanical resistance, the texture and the ease of processing berries. The aim of this work was study the evolution of the polysaccharides and the anthocyanin and tannin extractability during the ripening period in Cabernet Sauvignon grapes, trying to correlate these variables.