Macrowine 2021
IVES 9 IVES Conference Series 9 Pesticide removal in wine with a physical treatment by molecular sieving

Pesticide removal in wine with a physical treatment by molecular sieving

Abstract

All along the winemaking process, conditioning and aging, wine is susceptible to be contaminated by different molecules. Contaminations can have various origins, related to wine microorganisms or as a result of an exogenous contamination. The aforementioned contamination of the wine can be caused by the migration of molecules from the materials in contact with the wine or by a contamination from exogenous molecules present in the air. Regardless of the source of the contamination, mainly two types of consequences can be observed. First, it could be a risk of organoleptic defects resulting in a loss of the wine quality and a deep change in its typicity. Second contaminants may be harmful on human health. Beyond these aspects, with the emergence of regulations and commercial requirements, these contaminants can also influence negatively the commercial image of the contaminated wine. Among the exogenous contaminants of the wines, pesticides are the family molecules on which the general public is conversant about. Even if there is no proven toxicological risk associated with the presence of pesticide residues in the wines, this issue is a major concern for consumers and producers. Recently several articles were published in France and indicated a widespread contamination of wines from conventional or organic wines. These articles also highlight the lack of official Maximum Residue Limit for wine. It is also reported that, among the residues detected, many molecules are possible or probable carcinogens, toxic for the development or the reproduction, endocrine disruptors or neurotoxic. Few physical processes are currently available to remove pesticide residues from wine. Based on that observation, the objective of this study was to evaluate the ability of a new physical treatment of wine by molecular sieving with Zeolites to remove pesticide residues. Zeolites are already widely used in water or air treatment applications. Natural Zeolites are low cost abundant resources. These are crystalline aluminosilicates. One of the main characteristics of these solids is the development of regular pore size in the microporous domain. According to their preparation, they have physicochemical properties such as cation exchange, molecular sieving, catalysis, and adsorption. This article describes the selection of a Zeolite able to remove a great variety of pesticides used in vine growing. The results of a treatment trial done on a red wine contaminated with 21 pesticides frequently detected in wines are also presented. All the molecules are removed with an elimination yield higher than 90%. Their removal is influenced by the Zeolite concentration. Our first trials also indicate no influence of such a treatment on red wine key physico-chemical parameters and aromas. Further tests will be performed on other types of wine and the influence of Zeolites treatment on the perception of winetasters will be investigated.

Publication date: May 17, 2024

Issue: Macrowine 2016

Type: Poster

Authors

Arnaud Massot*, Céline Franc, Fabrice Meunier, Gilles De Revel, Laurent Riquier, Martine Mietton-Peuchot

*Amarante Process

Contact the author

Tags

IVES Conference Series | Macrowine | Macrowine 2016

Citation

Related articles…

On the losses of dissolved CO2 from laser-etched champagne glasses under standard tasting conditions

Under standard champagne tasting conditions, the complex interplay between the level of dissolved CO2 found in champagne, its temperature, the glass shape, and the bubbling rate, definitely impacts champagne tasting by modifying the neuro-physico-chemical mechanisms responsible for aroma release and flavor perception. Based on theoretical principles combining heterogeneous bubble nucleation, ascending bubble dynamics and mass transfer equations, a global model is proposed (depending on various parameters of both the wine and the glass itself), which quantitatively provides the progressive losses of dissolved CO2 from laser-etched champagne glasses.

Identification of green, aggressive and hard character of wines by a chemo-sensory directed methodology

With climate change, it is progressively more often to obtain grapes with an acceptable content in sugars or acids but with immature tannins described as green, aggressive or hard (noted as GAH onwards). During winemaking, the oenologist has to make decisions related to the elaboration of such grapes based mainly on empirical experience, given the lack of objective criteria to this concern. An increase in the chemical and sensory knowledge of immature tannins would allow managing this GAH character of grapes with the maximum possible efficiency during winemaking processes. The present work aims at isolating and identifying the group of compounds responsible for the GAH character present in wines.

Technological possibilities of grape marc cell walls as wine fining agent. Effect on wine phenolic composition

Fining is a technique that is used to remove unwanted wine components that affect clarification, astringency, color, bitterness, and aroma. Fining involves the addition of adsorptive or reactive material in order to reduce or eliminate the presence of certain less desirable wine components and to ensure that a wine remains in a particular stable state for a given period of time Recently concerns have been raised about the addition of animal proteins, such as gelatin, to wine due to the disease known as bovine spongiform encephalopathy (Mad Cow disease). Although the origin of gelatins has been moved to porcine, winemakers are asking for substitute products with properties and application protocols similar to the traditional animal-derived ones, making the use of plant-derived proteins in fining a practically viable possibility. As a consequence, various fining agents derived from plants have been proposed, including proteins from cereals, legumes, and potato.

Analysis of the oenological potentials of different oak forests in Hungary

Like France, Hungary has many oak forests used for making barrels since many years. But if the differences between the woods of the North, the East and the South-West forests of France are well known, this is probably not the case of Hungarian forests. However taking into account the essential differences of climates and soils, differences must be significant and the general name “Hungarian oak” must not have any real meaning. We have studied precisely (determination of concentrations of volatile and non-volatile wood compounds, anatomical criteria, measurement of antioxidant capacity) of oaks collected from northeastern Hungary and others collected from the Danube valley in the northwest of the country.

Removal of Fumonisin B1 and B2 from red wine using polymeric substances

The Ability of PVPP (Polyvinylpolypyrrolidone), PVP-DEGMA-TAIC (copolimerization of N-vinyl-2-pyrrolidinone with ethylene glycol dimethacrylate and triallyl isocyanurate) and PAEGDMA
(poly(acrylamide-co-ethylene glycol dimethacrylate)) polymers was tested as removal agents for Fumonisin B1 (FB1) and Fumonisin B2 (FB2) from model solutions and red wine. The polymers removal capacity was checked at three different resident times (2, 8 and 24 hours of contact time between the polymer and the sample), showing no differences in the percentage of FB1 and FB2 removal. Then, different polymer concentrations (1, 5 and 10 mg mL-1) were tested in model solution with and without phenolics (i.e. gallic acid and 4-methylcatechol).