Macrowine 2021
IVES 9 IVES Conference Series 9 Pesticide removal in wine with a physical treatment by molecular sieving

Pesticide removal in wine with a physical treatment by molecular sieving

Abstract

All along the winemaking process, conditioning and aging, wine is susceptible to be contaminated by different molecules. Contaminations can have various origins, related to wine microorganisms or as a result of an exogenous contamination. The aforementioned contamination of the wine can be caused by the migration of molecules from the materials in contact with the wine or by a contamination from exogenous molecules present in the air. Regardless of the source of the contamination, mainly two types of consequences can be observed. First, it could be a risk of organoleptic defects resulting in a loss of the wine quality and a deep change in its typicity. Second contaminants may be harmful on human health. Beyond these aspects, with the emergence of regulations and commercial requirements, these contaminants can also influence negatively the commercial image of the contaminated wine. Among the exogenous contaminants of the wines, pesticides are the family molecules on which the general public is conversant about. Even if there is no proven toxicological risk associated with the presence of pesticide residues in the wines, this issue is a major concern for consumers and producers. Recently several articles were published in France and indicated a widespread contamination of wines from conventional or organic wines. These articles also highlight the lack of official Maximum Residue Limit for wine. It is also reported that, among the residues detected, many molecules are possible or probable carcinogens, toxic for the development or the reproduction, endocrine disruptors or neurotoxic. Few physical processes are currently available to remove pesticide residues from wine. Based on that observation, the objective of this study was to evaluate the ability of a new physical treatment of wine by molecular sieving with Zeolites to remove pesticide residues. Zeolites are already widely used in water or air treatment applications. Natural Zeolites are low cost abundant resources. These are crystalline aluminosilicates. One of the main characteristics of these solids is the development of regular pore size in the microporous domain. According to their preparation, they have physicochemical properties such as cation exchange, molecular sieving, catalysis, and adsorption. This article describes the selection of a Zeolite able to remove a great variety of pesticides used in vine growing. The results of a treatment trial done on a red wine contaminated with 21 pesticides frequently detected in wines are also presented. All the molecules are removed with an elimination yield higher than 90%. Their removal is influenced by the Zeolite concentration. Our first trials also indicate no influence of such a treatment on red wine key physico-chemical parameters and aromas. Further tests will be performed on other types of wine and the influence of Zeolites treatment on the perception of winetasters will be investigated.

Publication date: May 17, 2024

Issue: Macrowine 2016

Type: Poster

Authors

Arnaud Massot*, Céline Franc, Fabrice Meunier, Gilles De Revel, Laurent Riquier, Martine Mietton-Peuchot

*Amarante Process

Contact the author

Tags

IVES Conference Series | Macrowine | Macrowine 2016

Citation

Related articles…

The commercial yeast strain as a significant source of variance for tyrosol and hydroxytyrosol in white wine

Tyrosol (TYR) and hydroxytyrosol (HYT) are bioactive phenols present in olive oil and wine, basic elements of the Mediterranean diet. TYR is reported in the literature for its interesting antioxidant, cardioprotective and anti-inflammatory properties. In wine, its concentration can reach values as high as about 40 mg/L
[Pour Nikfardjam et al. 2007] but, more frequently, this phenol – derived from yeast metabolism of tyrosine during fermentation – is present at lower levels, generally higher in red wines compared to whites. HYT was measured for the first time by Di Tommaso et al. [1998] in Italian wines – with maximum values of 4.20 mg/L and 1.92 mg/L for red and white wines, respectively – while definitely lower concentrations have been found later in Greek samples.

Accumulation of polyphenols in Barbera and Nebbiolo leaves during the vegetative season

Grapevine berries produce thousands of secondary metabolites of diverse chemical nature that have been largely detailed in the past due to their importance for defining wine quality. The wide Vitis vinifera diversity, resulting in thousands of different varieties well detailed in many studies regarding berries, is still not investigated in vegetative organs, leaves in particular. Deepening knowledge related to this aspect could be of great interest for many reasons (for example the possibility of using leaf extract for pharmaceutical, cosmetic and nutrition purposes) but, above all, for understanding the susceptibility of different grapevine varieties to pathogens.

How do different oak treatment affect the sensory composition of Chenin blanc wines over time?

Wooden barrels have been the preferred method for oak maturation for wines, but the use of alternative oak products, such as staves and oak chips have increased in South Africa due to lower production costs. This study investigated the effect of different oak products used during fermentation and ageing on the sensory profile, degree of liking and perceived quality of a South African Chenin blanc wine. The different wine treatments included an unoaked tank control wine, wines matured in 5th fill barrels, wines matured in new barrels from three different cooperages, and wines matured in 5th fill barrels with stave inserts from two different cooperages.

Impact of industrial-scale serial filtration on macromolecules in red wines

Filtration is a critical step in ensuring the clarity and microbial stability of wine prior to bottling. However the process of filtering potentially reduces red wine quality by removing some of the macromolecules that contribute to the texture of the wine. Commercial red wines, Cabernet Sauvignon (CAS) and Shiraz (SHZ), of two vintages and two grades (premium grade wines from the older vintage: CAS13 and SHZ13; and standard grade wines from a younger vintage: CAS14 and SHZ14) were filtered through industrial-scale commercial filtration units prior to bottling. Samples were taken before and after cross-flow filtration, lenticular filters, 0.65 µm and 0.45 µm pore size nylon membrane filters. The concentration and composition of macromolecules, including tannins and polysaccharides, were measured in all samples as well as particle size distribution and wine colour.

Enological evaluation of the attitude of the grapevine fumin to give varietal wines

Initiatives have been ongoing in recent years to safeguard biodiversity in the oenological sector via a process of enhancement of ancient varieties, under a pressure of a market strongly oriented towards production deriving from native vines of specific geographical zones. In that sense, Aosta Valley
(Italy) has raised the need to preserve and characterize its minority vine varieties which have the potentiality to give varietal wines. Fumin represents the 7% of the production of the region with 16 hectares of vineyards and 753 hectolitres of derived wine. Due to its large phenolic potential, strong astringency and deep colour, it has long been, and is still today, assembled or blended with other varieties as occurs, for example, for the Torrette.