Macrowine 2021
IVES 9 IVES Conference Series 9 Pesticide removal in wine with a physical treatment by molecular sieving

Pesticide removal in wine with a physical treatment by molecular sieving

Abstract

All along the winemaking process, conditioning and aging, wine is susceptible to be contaminated by different molecules. Contaminations can have various origins, related to wine microorganisms or as a result of an exogenous contamination. The aforementioned contamination of the wine can be caused by the migration of molecules from the materials in contact with the wine or by a contamination from exogenous molecules present in the air. Regardless of the source of the contamination, mainly two types of consequences can be observed. First, it could be a risk of organoleptic defects resulting in a loss of the wine quality and a deep change in its typicity. Second contaminants may be harmful on human health. Beyond these aspects, with the emergence of regulations and commercial requirements, these contaminants can also influence negatively the commercial image of the contaminated wine. Among the exogenous contaminants of the wines, pesticides are the family molecules on which the general public is conversant about. Even if there is no proven toxicological risk associated with the presence of pesticide residues in the wines, this issue is a major concern for consumers and producers. Recently several articles were published in France and indicated a widespread contamination of wines from conventional or organic wines. These articles also highlight the lack of official Maximum Residue Limit for wine. It is also reported that, among the residues detected, many molecules are possible or probable carcinogens, toxic for the development or the reproduction, endocrine disruptors or neurotoxic. Few physical processes are currently available to remove pesticide residues from wine. Based on that observation, the objective of this study was to evaluate the ability of a new physical treatment of wine by molecular sieving with Zeolites to remove pesticide residues. Zeolites are already widely used in water or air treatment applications. Natural Zeolites are low cost abundant resources. These are crystalline aluminosilicates. One of the main characteristics of these solids is the development of regular pore size in the microporous domain. According to their preparation, they have physicochemical properties such as cation exchange, molecular sieving, catalysis, and adsorption. This article describes the selection of a Zeolite able to remove a great variety of pesticides used in vine growing. The results of a treatment trial done on a red wine contaminated with 21 pesticides frequently detected in wines are also presented. All the molecules are removed with an elimination yield higher than 90%. Their removal is influenced by the Zeolite concentration. Our first trials also indicate no influence of such a treatment on red wine key physico-chemical parameters and aromas. Further tests will be performed on other types of wine and the influence of Zeolites treatment on the perception of winetasters will be investigated.

Publication date: May 17, 2024

Issue: Macrowine 2016

Type: Poster

Authors

Arnaud Massot*, Céline Franc, Fabrice Meunier, Gilles De Revel, Laurent Riquier, Martine Mietton-Peuchot

*Amarante Process

Contact the author

Tags

IVES Conference Series | Macrowine | Macrowine 2016

Citation

Related articles…

Characterization of Glycosidically Bound Aroma Compounds of País cv. grapes of different Chilean zones

País grape has been estimated to arrive to Chile almost 500 years ago, being the first strain grown in this country. Traditionally, this grape has been used to mix with other varieties, to produce poor quality wines, but today is beginning to be used in the production of high quality wines. However, very little is known about the chemical characteristics of this variety. The aroma is one of the most important quality attributes of wine. Volatile compounds of this beverage may come from the grape (varietal aromas), from the fermentation process, from the ageing. The aromatic compounds are found in the grape in two forms: as free volatile compounds and as non-volatile compounds. The last ones, are aroma precursors present mainly as glycoconjugates formed by a sugar and an aglycone…

How pressing techniques affect must composition and wine quality of Pinot blanc

This study investigates how the sensory profile of Pinot Blanc is affected from different maceration and pressing techniques. Grapes were sourced from four vineyards in the village Tramin in South Tyrol. For the experiment 200 kg of grapes from each vineyard site were hand picked the day before harvest for the commercial winery took place. Grapes were stored over night at 4°C, homogenized and processed in the experimental winery at Laimburg research centre the day after harvest. Four different pressing techniques were applied in duplicates of 100kg each.

Impact of heating must before fermentation on Chardonnay wines

Prefermentation steps of white winemaking are very important for controlling the stability and the sensory attributes of wines. Usually musts are clarified by cold settling to prevent the start of the fermentation, before racking big lees and thus limiting the appearance of vegetable or reduction off flavour while favouring an aromatic expression with low turbidity. Besides, to reach the protein stability, some white wines further require a bentonite fining, sometimes associated with negative effects on the sensory quality. This study aims to know the impact of musts heating after pressing on a Chardonnay wine in northern conditions by comparison with a classic cold racking of the must.

Correlations between sensory characteristics and colloidal content in dry white wines

Must clarification is an important step occurring just after grape extraction in the elaboration of white wine, consisting in a solid-liquid separation. Traditionally, low must turbidity, around 50-150 NTU, is generally reached in white winemaking in order to prevent reductive aromas and facilitating alcoholic fermentation. Alternatively, a higher turbidity (300 NTU or above) can be sought for reasons such as a better expression of grapes identity (terroir), or for getting a must matrix that could supposedly lead to wines having greater ageing potential.

Impact of varying ethanol and carbonation levels on the odor threshold of 1,1,6-trimethyl-1,2-dihydronaphtalene (petrol off-flavor) and role of berry size and Riesling clones

1,1,6-trimethyl-1,2-dihydronaphtelene (TDN) evokes the odor of “petrol” in wine, especially in the variety Riesling. Increasing UV-radiation due to climate change intensifies formation of carotenoids in the berry skins and an increase of TDN-precursors1. Exploring new viticultural and oenological strategies to limit TDN formation in the future requires precise knowledge of TDN thresholds in different matrices. Thresholds reported in the literature vary substantially between 2 µg/L up to 20 µg/L2,3,4 due to the use of different methods. As Riesling grapes are used for very different wine styles such as dry, sweet or sparkling wines, it is essential to study the impact of varying ethanol and carbonation levels.