Macrowine 2021
IVES 9 IVES Conference Series 9 Pesticide removal in wine with a physical treatment by molecular sieving

Pesticide removal in wine with a physical treatment by molecular sieving

Abstract

All along the winemaking process, conditioning and aging, wine is susceptible to be contaminated by different molecules. Contaminations can have various origins, related to wine microorganisms or as a result of an exogenous contamination. The aforementioned contamination of the wine can be caused by the migration of molecules from the materials in contact with the wine or by a contamination from exogenous molecules present in the air. Regardless of the source of the contamination, mainly two types of consequences can be observed. First, it could be a risk of organoleptic defects resulting in a loss of the wine quality and a deep change in its typicity. Second contaminants may be harmful on human health. Beyond these aspects, with the emergence of regulations and commercial requirements, these contaminants can also influence negatively the commercial image of the contaminated wine. Among the exogenous contaminants of the wines, pesticides are the family molecules on which the general public is conversant about. Even if there is no proven toxicological risk associated with the presence of pesticide residues in the wines, this issue is a major concern for consumers and producers. Recently several articles were published in France and indicated a widespread contamination of wines from conventional or organic wines. These articles also highlight the lack of official Maximum Residue Limit for wine. It is also reported that, among the residues detected, many molecules are possible or probable carcinogens, toxic for the development or the reproduction, endocrine disruptors or neurotoxic. Few physical processes are currently available to remove pesticide residues from wine. Based on that observation, the objective of this study was to evaluate the ability of a new physical treatment of wine by molecular sieving with Zeolites to remove pesticide residues. Zeolites are already widely used in water or air treatment applications. Natural Zeolites are low cost abundant resources. These are crystalline aluminosilicates. One of the main characteristics of these solids is the development of regular pore size in the microporous domain. According to their preparation, they have physicochemical properties such as cation exchange, molecular sieving, catalysis, and adsorption. This article describes the selection of a Zeolite able to remove a great variety of pesticides used in vine growing. The results of a treatment trial done on a red wine contaminated with 21 pesticides frequently detected in wines are also presented. All the molecules are removed with an elimination yield higher than 90%. Their removal is influenced by the Zeolite concentration. Our first trials also indicate no influence of such a treatment on red wine key physico-chemical parameters and aromas. Further tests will be performed on other types of wine and the influence of Zeolites treatment on the perception of winetasters will be investigated.

Publication date: May 17, 2024

Issue: Macrowine 2016

Type: Poster

Authors

Arnaud Massot*, Céline Franc, Fabrice Meunier, Gilles De Revel, Laurent Riquier, Martine Mietton-Peuchot

*Amarante Process

Contact the author

Tags

IVES Conference Series | Macrowine | Macrowine 2016

Citation

Related articles…

How pressing techniques affect must composition and wine quality of Pinot blanc

This study investigates how the sensory profile of Pinot Blanc is affected from different maceration and pressing techniques. Grapes were sourced from four vineyards in the village Tramin in South Tyrol. For the experiment 200 kg of grapes from each vineyard site were hand picked the day before harvest for the commercial winery took place. Grapes were stored over night at 4°C, homogenized and processed in the experimental winery at Laimburg research centre the day after harvest. Four different pressing techniques were applied in duplicates of 100kg each.

Comprehensive exploration of wine aroma-related compounds as promoted by alternative vinification procedures in case of Zelen (Vitis vinifera L.) grapes processing

Not only vintner’s decisions in the vineyard, but also winemaker’s choices of technology approaches in the cellar play a significant role in the final wine style and quality. Whereas traditional technologies within chosen terroir are quite well explored and thus somehow predictable, there is no proper knowledge available on possible outcomes in case of implementing novel, alternative winemaking strategies. To reveal their effects on wine aroma compounds and sensory characteristics, two alternative strategies
(cryoextraction or addition of whole grape berries during last stages of fermentation) were compared to classical Vipava valley winemaking approach as normally used for an autochthonous variety Zelen. After separate vinification and bottling, all the experimental wines were subjected to semiquantitative metabolic profiling of volatile compounds (VOCs) by means of GC/MS and were then also sensorialy evaluated by pre-trained panel.

HEAT BERRY : Sensitivity of berries ripening to higher temperature and impact on phenolic compounds in wine

The grapevine is an important economical crop that is very sensitive to climate changes and microclimate. The observations made during the last decades at a vineyard scale all concur to show the impact of climate change on vine physiology, resulting in accelerated phenology and earlier harvest (Jones and Davis 2000). It is well-known that berry content is affected by the ambient temperature. While the first experiences were primarily conducted on the impact of temperature on anthocyanin accumulation in the grape, few studies have focused on others component of phenolic metabolism, such as tannins.

Comparison of various storage conditions to preserve polyphenols in red-grape pomace

Red grape pomace, a waste from wine production, can be valorised by extracting polyphenols, high-added value compounds used in cosmetics or oenology. For use at an industrial level, using green extraction techniques, pomace need to be stored before being processed. The aim of this study is to test various storage conditions in order to maintain high level of polyphenols over 180 days, while keeping storage cost economically interesting. In a first step, different storage conditions (ambient temperature or cooled (4°C) temperature, anaerobic (saturation with N2) or aerobic conditions, and addition of sulphur dioxide (SO2)) were compared on small samples (1 kg) packed in plastic pockets. The quality of storage was assessed by following the optical density of the pomace extract at 280 nm (DO 280 expressed as mg/l eq gallic acid), which is an indication of the amount of remaining extractable polyphenols.

The use of cation exchange resins for wine acidity adjustment: Optimization of the process and the effects on tartrate formation and oxidative stability

Acidity adjustments are key to microbial control, sensory quality and wine longevity. Acidification with cation exchange resins -in acid cycle- offers the possibility to reduce the pH by exchanging wine cations, such as potassium (K+), for hydrogen ions (H+). During the exchange process, the removal of potassium and calcium ions contributes to limiting the formation of tartrate salts, thus offering an alternative solution to conventional methods for tartrate stability. Moreover, the reduction of wine pH and the removal of metals catalyzers (e.g. iron) could positively impact the wine’s oxidative stability. Therefore, the aims of this work were (a) to optimize the ion exchange process by testing different volumes and concentrations of sulfuric acid (H2SO4) during the acid cycle, (b) evaluate the effects of the ion exchange process on the formation of tartrate salts, and (c) analyze the oxidative stability of the treated wines.