Macrowine 2021
IVES 9 IVES Conference Series 9 Light-struck taste in white wine: enological approach for its prevention

Light-struck taste in white wine: enological approach for its prevention

Abstract

Light-struck taste is a defect prevalent in white wines bottled in clear glass light-exposed for a considerable amount of time leading to a loss of color and appearance of sulfur-like odors. The reaction involves riboflavin (RF), a highly photosensitive compound that undergoes to intermolecular photoreduction by the uptake of two electron equivalents from an external donor, the methionine. The reaction includes different steps forming methional which is extremely unstable and decomposes to methane thiol and acrolein. The reaction of two molecules of methane thiol yields dimethyl disulfide. Methane thiol is highly volatile, has a low perception threshold (2 to 10 µg/L in wine) and confers aroma-like rotten eggs or cabbage. Dimethyl disulfide is less volatile, but the perception threshold is still low (30 µg/L) and has an aroma impression of cooked cabbage or onion. However, if light contact, at certain wavelengths, is avoided the reaction does not happen. The riboflavin is released by the yeast and its level up to 100 ppb is considered safe for the appearance and perception of this defect. In this study, fermentation trials of must were carried out by using 15 commercial yeast strains monitoring the fermentation trend, as well. The degradation kinetic was evaluated in both model solution and white wine exposed to light in the absorption wavelengths of RF (370 and 440 nm). Different clarifying agents and adjuvants were tested including different types of bentonite and carbon, and zeolite. Moreover, preliminary tests were performed on provoking the light-struck taste by illuminating a model solution added with gallic and ellagic tannins from oak, gall, grape seeds and skin, and glutathione, ascorbic acid and phenylalanine. The RF production by yeast was confirmed and it is a characteristic strain-dependent. Its concentration ranged 30-50 ppb, except for one strain which released 180 ppb. No correlation between the fermentation rate and the RF production was found. The selection of the yeast strain seemed to play a key role for the final concentration of RF in wine. RF disappeared after only 2 hours of illumination in both model solution and white wine. RF decay followed a 1st order reaction kinetic and the half-life time was doubled in case of white wine. Such a difference could be due to the matrix. Among the clarifying agents, all the bentonites tested (100 g/hL) led to a reduction of RF up to 60%. A lower decrease was found by using the zeolite (30%). The carbon showed the highest decrease of RF (90%). Lower RF reduction in terms of both concentration and decay rate was observed in white wine with all the clarifying agents investigated. However, in white wine, the treatment with carbon was the most effective and the “safe concentration” was reached after 2 hours adding 5 g/hL of carbon. The preliminary results on provoking the light-struck taste suggested the tannin extracts and glutathione could limit the appearance of this defect.

Publication date: May 17, 2024

Issue: Macrowine 2016

Type: Poster

Authors

Daniela Fracassetti*, Antonio Tirelli

*Univ. degli Studi di Milano

Contact the author

Tags

IVES Conference Series | Macrowine | Macrowine 2016

Citation

Related articles…

Interest and impact of PVP/PVI (Polyvinylpyrrolidone/ Polyvinylimidazole) on winemaking and final quality of wines

Céline Sparrow a, Christophe Morge a, a SOFRALAB SAS, 79, av. A.A. Thévenet – CS 11031 – 51530 Magenta, France Consumers’ health and security force authorities to limit, in wine as in others food industry products, the concentration in « dangerous » molecules. Therefore the legal limit in heavy metals keeps on decreasing. As per proof EU regulation just decrease the stain concentration in wine from 0,2 to 0,15 mg/l. Certain changes , such as sodium arsenite treatment in vines, disappearance of brass in wineries to the benefit of stainless steel, limit even more the concentration of heavy metals in wines. But the use of copper derivates in vines treatments is difficult to replace. In the case of wine and its elaboration, the problem is even more complex. Indeed, regulation forces the wine producers to control the concentration of certain heavy metals in final wines.

HEAT BERRY : Sensitivity of berries ripening to higher temperature and impact on phenolic compounds in wine

The grapevine is an important economical crop that is very sensitive to climate changes and microclimate. The observations made during the last decades at a vineyard scale all concur to show the impact of climate change on vine physiology, resulting in accelerated phenology and earlier harvest (Jones and Davis 2000). It is well-known that berry content is affected by the ambient temperature. While the first experiences were primarily conducted on the impact of temperature on anthocyanin accumulation in the grape, few studies have focused on others component of phenolic metabolism, such as tannins.

Impact of glutathione and elemental sulphur juice addition on the volatile thiol production in South African Sauvignon blanc wine

Three compounds, 3-mercaptohexanol (3MH), 3-mercaptohexyl-acetate (3MHA) and 4-mercapto-4-methylpentan-2-one (4MMP), also known as varietal thiols, have been identified to contribute positively to wine aroma and are responsible for the distinct gooseberry, grapefruit, guava and box tree character found in Sauvignon blanc wines. Certain volatile thiol compounds though, can cause off-aromas of onion, garlic, rubber and rotten egg, this group of molecules is known as reductive sulphur compounds (RSC). This study looks into how the addition of sulphur-compounds to Sauvignon blanc juice contributes to the varietal thiol (3MH and 3MHA) concentration and reductive sulphur compound concentration in South African Sauvignon blanc wine.

Foam characteristics of white, rosé and red sparkling wines elaborated by the champenoise method

Contribution Foam is the characteristic that differentiates sparkling wines from still wines, being the first sensory attribute that tasters and consumers perceive and that determines the final quality of sparkling wines [1]. The foaming properties mainly depend on the chemical composition of wines [2-3], and different factors involved in wine composition will have an effect on foam quality. In Spain, the sparkling wine market focuses on the production of white and rosé sparkling wine, with very low production of red sparkling wines. However, this type of wines is elaborated in countries like Australia, South-Africa, Argentina, Italy or Portugal, with a great acceptance by consumers. No studies on the foaming characteristics of red sparkling wines have been found.

Determination of metallic elements in Chilean wines by atomic absorption spectroscopy and inductively coupled plasma–mass spectrometry

The chemical composition of wines depends on series of variables such as the type of grape, edaphoclimatic conditions, and viticulture and winemaking practices employed during production. Metallic elements play a significant role during winemaking (e.g. as catalysts of oxidation reactions) and have been previously employed for the classification of wines according to provenance. In this work, we focused on the analysis of metallic elements (K, Na, Ca, Zn, Cu, Fe, Mg, Mn, Ni, Cr, Al, Pb, Cd, Hg, Se, Co, Sn and As) in 145 Chilean wine samples (102 reds and 43 white wines), of seven grape varieties, and five of the major wine producing regions in Chile.