Macrowine 2021
IVES 9 IVES Conference Series 9 Light-struck taste in white wine: enological approach for its prevention

Light-struck taste in white wine: enological approach for its prevention

Abstract

Light-struck taste is a defect prevalent in white wines bottled in clear glass light-exposed for a considerable amount of time leading to a loss of color and appearance of sulfur-like odors. The reaction involves riboflavin (RF), a highly photosensitive compound that undergoes to intermolecular photoreduction by the uptake of two electron equivalents from an external donor, the methionine. The reaction includes different steps forming methional which is extremely unstable and decomposes to methane thiol and acrolein. The reaction of two molecules of methane thiol yields dimethyl disulfide. Methane thiol is highly volatile, has a low perception threshold (2 to 10 µg/L in wine) and confers aroma-like rotten eggs or cabbage. Dimethyl disulfide is less volatile, but the perception threshold is still low (30 µg/L) and has an aroma impression of cooked cabbage or onion. However, if light contact, at certain wavelengths, is avoided the reaction does not happen. The riboflavin is released by the yeast and its level up to 100 ppb is considered safe for the appearance and perception of this defect. In this study, fermentation trials of must were carried out by using 15 commercial yeast strains monitoring the fermentation trend, as well. The degradation kinetic was evaluated in both model solution and white wine exposed to light in the absorption wavelengths of RF (370 and 440 nm). Different clarifying agents and adjuvants were tested including different types of bentonite and carbon, and zeolite. Moreover, preliminary tests were performed on provoking the light-struck taste by illuminating a model solution added with gallic and ellagic tannins from oak, gall, grape seeds and skin, and glutathione, ascorbic acid and phenylalanine. The RF production by yeast was confirmed and it is a characteristic strain-dependent. Its concentration ranged 30-50 ppb, except for one strain which released 180 ppb. No correlation between the fermentation rate and the RF production was found. The selection of the yeast strain seemed to play a key role for the final concentration of RF in wine. RF disappeared after only 2 hours of illumination in both model solution and white wine. RF decay followed a 1st order reaction kinetic and the half-life time was doubled in case of white wine. Such a difference could be due to the matrix. Among the clarifying agents, all the bentonites tested (100 g/hL) led to a reduction of RF up to 60%. A lower decrease was found by using the zeolite (30%). The carbon showed the highest decrease of RF (90%). Lower RF reduction in terms of both concentration and decay rate was observed in white wine with all the clarifying agents investigated. However, in white wine, the treatment with carbon was the most effective and the “safe concentration” was reached after 2 hours adding 5 g/hL of carbon. The preliminary results on provoking the light-struck taste suggested the tannin extracts and glutathione could limit the appearance of this defect.

Publication date: May 17, 2024

Issue: Macrowine 2016

Type: Poster

Authors

Daniela Fracassetti*, Antonio Tirelli

*Univ. degli Studi di Milano

Contact the author

Tags

IVES Conference Series | Macrowine | Macrowine 2016

Citation

Related articles…

Influence of toasting oak wood on ellagitannin structures

Ellagitannins (ETs) have been reported to be the main phenolic compounds found in oak wood. These compounds, belonging to the hydrolysable tannin class of polyphenols, are esters of hexahydroxydiphenic acid (HHDP) and a polyol, usually glucose or quinic acid. They own their name to their capacity to be hydrolysed and liberate ellagic acid and they have an impact on astringency and bitterness sensation, which is strongly dependant on their structure. The toasting phase is particularly crucial in barrels fabrication and influences wood composition.

Determination of metallic elements in Chilean wines by atomic absorption spectroscopy and inductively coupled plasma–mass spectrometry

The chemical composition of wines depends on series of variables such as the type of grape, edaphoclimatic conditions, and viticulture and winemaking practices employed during production. Metallic elements play a significant role during winemaking (e.g. as catalysts of oxidation reactions) and have been previously employed for the classification of wines according to provenance. In this work, we focused on the analysis of metallic elements (K, Na, Ca, Zn, Cu, Fe, Mg, Mn, Ni, Cr, Al, Pb, Cd, Hg, Se, Co, Sn and As) in 145 Chilean wine samples (102 reds and 43 white wines), of seven grape varieties, and five of the major wine producing regions in Chile.

Cover crops influence on soil N availability and grapevine N status, and its relationship with biogenic

The type of soil management, tillage versus cover crops, can modify the soil microbial activity, which causes the mineralization of organic N to NO3–N and, therefore, may change the soil NO3–N availability in vineyard. The soil NO3–N availability could influence the grapevine nutritional status and the grape amino acid composition. Amino acids are precursors of biogenic amines, compounds mainly formed during the malolactic fermentation. Biogenic amines have negative effects on consumer health and on the wine organoleptic quality. The objective was to study if the effect of conventional tillage and two different cover crops (leguminous versus gramineous) on grapevine N status, could relate to the wine biogenic amines composition.

Analysis of the oenological potentials of different oak forests in Hungary

Like France, Hungary has many oak forests used for making barrels since many years. But if the differences between the woods of the North, the East and the South-West forests of France are well known, this is probably not the case of Hungarian forests. However taking into account the essential differences of climates and soils, differences must be significant and the general name “Hungarian oak” must not have any real meaning. We have studied precisely (determination of concentrations of volatile and non-volatile wood compounds, anatomical criteria, measurement of antioxidant capacity) of oaks collected from northeastern Hungary and others collected from the Danube valley in the northwest of the country.

How pressing techniques affect must composition and wine quality of Pinot blanc

This study investigates how the sensory profile of Pinot Blanc is affected from different maceration and pressing techniques. Grapes were sourced from four vineyards in the village Tramin in South Tyrol. For the experiment 200 kg of grapes from each vineyard site were hand picked the day before harvest for the commercial winery took place. Grapes were stored over night at 4°C, homogenized and processed in the experimental winery at Laimburg research centre the day after harvest. Four different pressing techniques were applied in duplicates of 100kg each.