Macrowine 2021
IVES 9 IVES Conference Series 9 Light-struck taste in white wine: enological approach for its prevention

Light-struck taste in white wine: enological approach for its prevention

Abstract

Light-struck taste is a defect prevalent in white wines bottled in clear glass light-exposed for a considerable amount of time leading to a loss of color and appearance of sulfur-like odors. The reaction involves riboflavin (RF), a highly photosensitive compound that undergoes to intermolecular photoreduction by the uptake of two electron equivalents from an external donor, the methionine. The reaction includes different steps forming methional which is extremely unstable and decomposes to methane thiol and acrolein. The reaction of two molecules of methane thiol yields dimethyl disulfide. Methane thiol is highly volatile, has a low perception threshold (2 to 10 µg/L in wine) and confers aroma-like rotten eggs or cabbage. Dimethyl disulfide is less volatile, but the perception threshold is still low (30 µg/L) and has an aroma impression of cooked cabbage or onion. However, if light contact, at certain wavelengths, is avoided the reaction does not happen. The riboflavin is released by the yeast and its level up to 100 ppb is considered safe for the appearance and perception of this defect. In this study, fermentation trials of must were carried out by using 15 commercial yeast strains monitoring the fermentation trend, as well. The degradation kinetic was evaluated in both model solution and white wine exposed to light in the absorption wavelengths of RF (370 and 440 nm). Different clarifying agents and adjuvants were tested including different types of bentonite and carbon, and zeolite. Moreover, preliminary tests were performed on provoking the light-struck taste by illuminating a model solution added with gallic and ellagic tannins from oak, gall, grape seeds and skin, and glutathione, ascorbic acid and phenylalanine. The RF production by yeast was confirmed and it is a characteristic strain-dependent. Its concentration ranged 30-50 ppb, except for one strain which released 180 ppb. No correlation between the fermentation rate and the RF production was found. The selection of the yeast strain seemed to play a key role for the final concentration of RF in wine. RF disappeared after only 2 hours of illumination in both model solution and white wine. RF decay followed a 1st order reaction kinetic and the half-life time was doubled in case of white wine. Such a difference could be due to the matrix. Among the clarifying agents, all the bentonites tested (100 g/hL) led to a reduction of RF up to 60%. A lower decrease was found by using the zeolite (30%). The carbon showed the highest decrease of RF (90%). Lower RF reduction in terms of both concentration and decay rate was observed in white wine with all the clarifying agents investigated. However, in white wine, the treatment with carbon was the most effective and the “safe concentration” was reached after 2 hours adding 5 g/hL of carbon. The preliminary results on provoking the light-struck taste suggested the tannin extracts and glutathione could limit the appearance of this defect.

Publication date: May 17, 2024

Issue: Macrowine 2016

Type: Poster

Authors

Daniela Fracassetti*, Antonio Tirelli

*Univ. degli Studi di Milano

Contact the author

Tags

IVES Conference Series | Macrowine | Macrowine 2016

Citation

Related articles…

Cover crops influence on soil N availability and grapevine N status, and its relationship with biogenic

The type of soil management, tillage versus cover crops, can modify the soil microbial activity, which causes the mineralization of organic N to NO3–N and, therefore, may change the soil NO3–N availability in vineyard. The soil NO3–N availability could influence the grapevine nutritional status and the grape amino acid composition. Amino acids are precursors of biogenic amines, compounds mainly formed during the malolactic fermentation. Biogenic amines have negative effects on consumer health and on the wine organoleptic quality. The objective was to study if the effect of conventional tillage and two different cover crops (leguminous versus gramineous) on grapevine N status, could relate to the wine biogenic amines composition.

Glutathione content evolution during spontaneous alcoholic fermentations of Sangiovese grapes

Glutathione is a tripeptide (γ-Glu-Cys-Gly), which can occur in grapes, in must and in wine prevalently in the reduced form as well as in the oxidized form as glutathione disulfide. The importance of the reduced form of glutathione lies in its antioxidant activity. In must, it limits browning by reducing o-quinones produced by polyphenol oxidase activity on hydroxycinnamic acids; in wine, it exerts a protective effect on various aromatic compounds. Glutathione concentration in wine is lower than in grape juice and variable as it depends on several factors, ranging from the native content of grapes to winemaking technique.

Update knowledge about the presence of condensed tannins in grapes and their contributions to astringency perception

Condensed tannin is a principle group of polyphenol compounds derived from grape, greatly contributing to the bioactivity and the sensory perception of wine. Condensed tannins present as a heterogeneous mixture in nature involving various degrees of both polymerization and galloylation. Even though multiple attempts focusing on fractionation of grape condensed tannins by solid-phase have been conducted over the past decades, few individual tannins have been purified and identified. Hence, our knowledge on grape and wine condensed tannin moleculars has to be limited at the several known monomeric, dimeric and trimeric proanthocyanidins

Impact of smoke exposure on the chemical composition of grapes

Vineyard exposure to smoke can lead to grapes and wine which exhibit objectionable smoky and ashy aromas and flavours, more commonly known as ‘smoke taint’ [1, 2]. In the last decade, significant bushfires have occurred around the world, including near wine regions in Australia, Canada, South Africa and the USA, as a consequence of the warmer, drier conditions associated with climate change. Considerable research has subsequently been undertaken to determine the chemical, sensory and physiological consequences of grapevine exposure to smoke. The sensory attributes associated with smoke-tainted wine have been linked to the presence of several smoke-derived volatile phenols, such as guaiacols, syringols and cresols [2].

Accumulation of polyphenols in Barbera and Nebbiolo leaves during the vegetative season

Grapevine berries produce thousands of secondary metabolites of diverse chemical nature that have been largely detailed in the past due to their importance for defining wine quality. The wide Vitis vinifera diversity, resulting in thousands of different varieties well detailed in many studies regarding berries, is still not investigated in vegetative organs, leaves in particular. Deepening knowledge related to this aspect could be of great interest for many reasons (for example the possibility of using leaf extract for pharmaceutical, cosmetic and nutrition purposes) but, above all, for understanding the susceptibility of different grapevine varieties to pathogens.