Macrowine 2021
IVES 9 IVES Conference Series 9 Light-struck taste in white wine: enological approach for its prevention

Light-struck taste in white wine: enological approach for its prevention

Abstract

Light-struck taste is a defect prevalent in white wines bottled in clear glass light-exposed for a considerable amount of time leading to a loss of color and appearance of sulfur-like odors. The reaction involves riboflavin (RF), a highly photosensitive compound that undergoes to intermolecular photoreduction by the uptake of two electron equivalents from an external donor, the methionine. The reaction includes different steps forming methional which is extremely unstable and decomposes to methane thiol and acrolein. The reaction of two molecules of methane thiol yields dimethyl disulfide. Methane thiol is highly volatile, has a low perception threshold (2 to 10 µg/L in wine) and confers aroma-like rotten eggs or cabbage. Dimethyl disulfide is less volatile, but the perception threshold is still low (30 µg/L) and has an aroma impression of cooked cabbage or onion. However, if light contact, at certain wavelengths, is avoided the reaction does not happen. The riboflavin is released by the yeast and its level up to 100 ppb is considered safe for the appearance and perception of this defect. In this study, fermentation trials of must were carried out by using 15 commercial yeast strains monitoring the fermentation trend, as well. The degradation kinetic was evaluated in both model solution and white wine exposed to light in the absorption wavelengths of RF (370 and 440 nm). Different clarifying agents and adjuvants were tested including different types of bentonite and carbon, and zeolite. Moreover, preliminary tests were performed on provoking the light-struck taste by illuminating a model solution added with gallic and ellagic tannins from oak, gall, grape seeds and skin, and glutathione, ascorbic acid and phenylalanine. The RF production by yeast was confirmed and it is a characteristic strain-dependent. Its concentration ranged 30-50 ppb, except for one strain which released 180 ppb. No correlation between the fermentation rate and the RF production was found. The selection of the yeast strain seemed to play a key role for the final concentration of RF in wine. RF disappeared after only 2 hours of illumination in both model solution and white wine. RF decay followed a 1st order reaction kinetic and the half-life time was doubled in case of white wine. Such a difference could be due to the matrix. Among the clarifying agents, all the bentonites tested (100 g/hL) led to a reduction of RF up to 60%. A lower decrease was found by using the zeolite (30%). The carbon showed the highest decrease of RF (90%). Lower RF reduction in terms of both concentration and decay rate was observed in white wine with all the clarifying agents investigated. However, in white wine, the treatment with carbon was the most effective and the “safe concentration” was reached after 2 hours adding 5 g/hL of carbon. The preliminary results on provoking the light-struck taste suggested the tannin extracts and glutathione could limit the appearance of this defect.

Publication date: May 17, 2024

Issue: Macrowine 2016

Type: Poster

Authors

Daniela Fracassetti*, Antonio Tirelli

*Univ. degli Studi di Milano

Contact the author

Tags

IVES Conference Series | Macrowine | Macrowine 2016

Citation

Related articles…

Reaction Mechanisms of Copper and Iron with Hydrogen Sulfide and Thiols in Model Wine

Fermentation derived sulfidic off-odors due to hydrogen sulfide (H2S) and low molecular weight thiols are commonly encountered in wine production and removed by Cu(II) fining. However, the mechanism underlying Cu(II) fining remains poorly understood, and generally results in increased Cu concentration that lead to deleterious reactions in finished wine. The present study describes a mechanistic investigation of the iron and copper mediated reaction of H2S, cysteine, 3-sulfanylhexan-1-ol, and 6-sulfanylhexan-1-ol with oxygen. The concentrations of H2S, thiols, oxygen, and acetaldehyde were monitored over time. It was found that Cu(II) was rapidly reduced by both H2S and thiols to Cu(I).

Towards multi-purpose valorisation of polyphenols from grape pomace: Pressurized liquid extraction coupled to purification by membrane processes

Grape by-products (including skins, seeds, stems and vine shoots) are rich in health promoting polyphenols. Their extraction from winery waste and their following purification are of special interest to produce extracts with high added value compounds. Meanwhile, the growing concern over environmental problems associated with economic constraints, require the development of environmentally sustainable extraction technologies. The extraction using semi-continuous subcritical water, as a natural solvent at high temperature and high pressure a technology is promising “green” technology that is environmentally friendly, energy efficient and improve the extraction process in plant tissues.

Flavanol glycosides in grapes and wines : the key missing molecular intermediates in condensed tannin biosynthesis ?

Polyphenols are present in a wide variety of plants and foods such as tea, cacao and grape1. An important sub-class of these compounds is the flavanols present in grapes and wines as monomers (e.g (+)-catechin or (-)-epicatechin), or polymers also called condensed tannins or proanthocyanidins. They have important antioxidant properties2 but their biosynthesis remains partly unknown. Some recent studies have focused on the role of glycosylated intermediates that are involved in the transport of the monomers and may serve as precursors in the polymerization mechanism3, 4. The global objective of this work is to identify flavanol glycosides in grapes or wines, describe their structure and determine their abundance during grape development and in wine.

Metabolomic profile of red non-V. vinifera genotypes

Vitis vinifera L. is the most widely cultivated Vitis species which includes numerous cultivars. Owing to their superior quality of grapes, these cultivars were long considered the only suitable for the production of fine wines. However, the lack of resistance genes in V. vinifera against major grapevine pathogens, requires for its cultivation frequent spraying with large amount of fungicides. Thus, the search for alternative and more sustainable methods to control the grapevine pathogens have brought the breeders to focus their attention on other Vitis species. In fact, wild Vitis genotypes present multiple resistance traits against pathogens, such as powdery mildew, downy mildew and phylloxera.

Influence of inactive dry yeast treatments during grape ripening on postharvest berry skin texture parameters and phenolic compounds extractability

Inactive dry yeast treatments in the vineyard are a tool used with the aim to improve the concentration and quality of secondary metabolites in grapes, leading to a better differentiation of the wines made from grapes differently treated. In this work, a foliar spraying treatment with yeast derivatives specifically designed to be used with the patent pending application technology of Lallemand Inc. Canada (LalVigne® Mature, Lallemand Inc., Montreal, Canada) was tested on Vitis vinifera L. cv. Barbera and Nebbiolo black winegrapes. The aim was to evaluate the effect of this treatment on the phenolic compounds accumulation, the skin physical-mechanical properties and the related phenolic extractability. Prior to analysis, the berries were sorted by flotation in order to evaluate their distribution by density class, and to determine the skin texture parameters of berries with different sugar contents, thus understanding also the ripening effect.