Macrowine 2021
IVES 9 IVES Conference Series 9 Effect of post-harvest ozone treatments on the skin phenolic composition and extractability of red winegrapes cv Nebbiolo and Barbera

Effect of post-harvest ozone treatments on the skin phenolic composition and extractability of red winegrapes cv Nebbiolo and Barbera

Abstract

Wine industry is looking forward for innovative, safe and eco-friendly antimicrobial products allowing the reduction of chemical treatments in the grape defense and the winemaking process that can affect negatively the quality of the product. Ozone has been tested in food industry giving good results in preventing fungi and bacteria growth on a wide spectrum of vegetables and fruits, due to its oxidant activity and ability to attack numerous cellular constituents. Ozone leaves no chemical residues on the food surface, decomposing itself rapidly in oxygen. Gaseous ozone has been already tested for table grapes storage and on wine grapes during withering. In particular, ozone has been suggested as phenolic compounds elicitor, stimulating chemical defense mechanisms such as the synthesis of polyphenols, and as enhancer of cellular membrane and cell walls degradation phenomena. Phenolic compounds are strongly linked to the red wine quality, and their extraction depends on the grape variety, winemaking technique and cell wall degradation. In this work, Vitis vinifera L. cv Nebbiolo and Barbera, chosen for their different anthocyanin profiles, were post-harvest treated for 24 and 72 hours with gaseous ozone (30 µL/L). Untreated samples were used as control with the aim of investigating possible indirect physico-chemical effects of this sanitizing treatment on berry skin phenolic composition. Skin phenolic extractability was assessed during maceration (6, 24, 48, 96, 168 and 240 hours) using a wine-like solution, particularly for total anthocyanins (TA), proanthocyanidins (PRO) and flavanols reactive to vanillin (FRV), and anthocyanin profiles were also determined. Ozone did not affect significantly the final extraction yield of TA, PRO and FRV in Barbera; although anthocyanin extractability was higher in control rather than in ozone-treated samples during the first stages of maceration. Otherwise, Nebbiolo was positively influenced by the treatment because ozone increased significantly TA extraction (68.6, 64.2 and 59.9% for 24 hours ozone-treated berries, 72 hours ozone-treated berries and control samples, respectively). PRO and FRV extractability also showed an increase in both ozone-treated samples compared to the control (+8.6-9.1% for PRO and +7.3-11.7% for FRV). No significant differences were found among treatments for individual anthocyanins, whereas the variety and maceration time strongly affected the anthocyanin profile. In our experimental conditions, ozone enhanced phenolic compounds extractability in Nebbiolo grapes while it did not show significant effects on Barbera. Therefore, the use of ozone as sanitizing agent in the red varieties winemaking process can be considered because it did not negatively affect the extractability of skin anthocyanins and flavanols.

Publication date: May 17, 2024

Issue: Macrowine 2016

Type: Poster

Authors

Maria Alessandra Paissoni*, Cristian Carboni, Fabrizio Torchio, Francesco Cravero, Kalliopi Rantsiou, Luca Cocolin, Luca Rolle, Pierre-Louis Teissedre, Simone Giacosa, Susana Río Segade, Vasileios Englezos, Vincenzo Gerbi

*Università di Torino

Contact the author

Tags

IVES Conference Series | Macrowine | Macrowine 2016

Citation

Related articles…

Impact of heating must before fermentation on Chardonnay wines

Prefermentation steps of white winemaking are very important for controlling the stability and the sensory attributes of wines. Usually musts are clarified by cold settling to prevent the start of the fermentation, before racking big lees and thus limiting the appearance of vegetable or reduction off flavour while favouring an aromatic expression with low turbidity. Besides, to reach the protein stability, some white wines further require a bentonite fining, sometimes associated with negative effects on the sensory quality. This study aims to know the impact of musts heating after pressing on a Chardonnay wine in northern conditions by comparison with a classic cold racking of the must.

Intelligent article to control the internal pressure in continue in bottles

An intelligent packaging might, among others, provide information and allow monitoring of the quality of the packed product or its surrounding environment. A recent project on micro-flow wine bottles closed with aluminium screw cap and tightness liner, highlighted the importance of monitoring the internal overpressure continuously, in real-time and at least for 72 hours, since the internal pressure on the tightness liner and the micro-flow are related. Real-time and continuous measurements are not the standard methods of measurement of the overpressure, yet. The most used equipment for the determination of the pressure in wine bottle is the aphrometer, a destructive device that supplies a single value of pressure.

Prevention of wine oxidation during barrel aging: an innovative method to measure antioxidant

Wine oxidation is a problem that affects the freshness, the aromatic profile, the colour and also the mouthfeel of the wine. It mainly concerns white wines. Oxygen interactions with wine compounds lead to the phenomena cited above that are responsible for the depreciation of these wines. Barrel aging is a crucial step in the wine process because it allows many modifications as wine enrichment, colour stabilization, clarification and also a slow oxygenation of the wine. Effects of the oak barrel have to be known to prevent oxidation of the wine. We have been interested in the main antioxidant compounds released by oak barrels to the wine and we have developed an innovative method to reach directly these antioxidant compounds at the oak stave surface.

Red wine substituted esters involved in fruity aromatic expression: an enantiomeric approach to understand their sensory impact and their pathway formation

Among red wines ethyl esters, those from short hydroxylated and branched-chain aliphatic acids constitute a family with a particular behavior and sensory importance. They have been previously discussed in the literature [1] and recent studies have established that some of them were strongly involved in of red wines’ fruity aroma [2]. As some among them have an asymmetrical carbon atom, it seemed important to separate their different enantiomers to obtain an accurate assessment of their organoleptic impact. Three chiral esters have been identified, presenting alkyl and/or hydroxyle substituants: ethyl 2-hydroxy-4-methylpentanoate, ethyl 2-methylbutanoate, and ethyl 3-hydroxybutanoate.

Wood from barrique: release of phenolic compounds and permeability to oxygen

Chemical and sensory changes occurring in red wine during ageing in oak barrique are due to the slow and gradual entrance of oxygen along with a release of ellagic tannin from the wood. Though oxygen can enter the cask through the bunghole, it is not clear the role of permeation through the wood staves as well as the amount of oxygen entering by permeation. The distribution of the released ellagic tannins in the wine ageing is also unknown. The oxygen passing through the bunghole may have a different wine ageing effect compared to the oxygen permeating through the wooden staves owing to the uneven ellagic tannin concentration throughout the wine.