Macrowine 2021
IVES 9 IVES Conference Series 9 Colour assessment of port wines using colorimetric and spectrophotometric methods

Colour assessment of port wines using colorimetric and spectrophotometric methods

Abstract

Colour is an important quality parameter in wines and is the result of a complex mixture of pigments (including anthocyanins and their derivatives, quinones, xanthyllium compounds, etc.). Red wine colour changes over time as pigments react between themselves and with other wine macromolecules (particularly polyphenols). During wine tasting, colour is normally assessed on the outer rim of the wine profile in a tilted glass, since most wines are too opaque to be analysed in the middle of the glass. Therefore, depending on the depth of observation considered, the perception of wine colour can be different. The precise measurement of wine colour is usually done using molecular (UV-VIS) spectrophotometric methods. In the current official (OIV) method, the transmittance spectrum of a particular sample is measured and used to calculate CIE L*a*b* parameters, which define a single (predominant) colour for a particular wine. Reflectance colorimetry is an alternative well-established method for measuring colour in foodstuffs, which can also be used in transparent samples (such as wines) as long as a reflective background is used. In this work, a reflectance colorimeter was used to measure CIE L*a*b* colour parameters of Port wine samples of different categories at different depths, in Petri dishes. The obtained results were compared with the parameters obtained using the OIV method. Representative profiles of Lightness (L*), Hue (H*) and Chroma (C*) vs. wine depths were obtained using Port wine samples from different categories and ages. Wines from the same category exhibited similar colour (depth) profiles, with Tawny-styled wines showing a more linear profile than Ruby-styled wines regarding the L* and H* parameters. Good correlations between the colorimetric and OIV methods were obtained for the L* (Ruby:R >= 0.97; Tawny:R > 0.86) and H* parameters (Ruby:R >= 0.90; Tawny >= 0.91) with the C* parameter giving inferior results, particularly in Tawny-style wines (Ruby:R >= 0.87; Tawny >= 0.29). The results suggest the colorimetric method can be used as an alternative to the OIV method for estimating the L* and H* parameters (the most important for wine colour definition), being quicker and more informative.

Publication date: May 17, 2024

Issue: Macrowine 2016

Type: Poster

Authors

Francisco Silva*, Bento Amaral, Cristina Silva, Francisco Campos, Manuel Ferreira, Natalia Ribeiro, Tomas Simões

*Escola Sup. Biotecnologia – UCP

Contact the author

Tags

IVES Conference Series | Macrowine | Macrowine 2016

Citation

Related articles…

Impact of smoke exposure on the chemical composition of grapes

Vineyard exposure to smoke can lead to grapes and wine which exhibit objectionable smoky and ashy aromas and flavours, more commonly known as ‘smoke taint’ [1, 2]. In the last decade, significant bushfires have occurred around the world, including near wine regions in Australia, Canada, South Africa and the USA, as a consequence of the warmer, drier conditions associated with climate change. Considerable research has subsequently been undertaken to determine the chemical, sensory and physiological consequences of grapevine exposure to smoke. The sensory attributes associated with smoke-tainted wine have been linked to the presence of several smoke-derived volatile phenols, such as guaiacols, syringols and cresols [2].

The effect of Nitrogen and Sulphur foliar applications in hot climates

ine nitrogen deficiency can negatively influence the aroma profile and ageing potential of white wines. Canopy management can alter vine microclimate, affect the nitrogen availability and influence the response of leaf senescence. Increasing the nitrogen availability to vines can increase the Yeast Assimilable Nitrogen (YAN) levels in harvested fruit and wine. Studies show that foliar nitrogen and sulphur applications at véraison, on low YAN Sauvignon blanc grapes have an effect on the level of amino acids (Jreij et al. 2009) and on S-containing compounds such as glutathione and thiols (Lacroux et al. 2008), which in turn can influence the formation of major volatiles and the aroma profile of the wine.

Novel analytical technologies for wine fingerprinting in and beyond the laboratory

For characterization, sensory designing and authentication rapid analytical technologies have become available. Some, like Proton Transfer Reaction Mass Spectrometry allow a rapid spectrum of the volatile compounds of wines. Combined with chemometrics wines can be characterized. The same approach can be used to calculate the results of virtual mixtures and allow formulation of constant quality blends. Other new techniques and portable devices based on spectroscopy allow measurements on production sites and in grocery stores, even for the smart consumer. We will present some examples of the application of these techniques for authentication of wines, both in the laboratory and on site.

Effect of post-harvest ozone treatments on the skin phenolic composition and extractability of red winegrapes cv Nebbiolo and Barbera

Wine industry is looking forward for innovative, safe and eco-friendly antimicrobial products allowing the reduction of chemical treatments in the grape defense and the winemaking process that can affect negatively the quality of the product. Ozone has been tested in food industry giving good results in preventing fungi and bacteria growth on a wide spectrum of vegetables and fruits, due to its oxidant activity and ability to attack numerous cellular constituents. Ozone leaves no chemical residues on the food surface, decomposing itself rapidly in oxygen. Gaseous ozone has been already tested for table grapes storage and on wine grapes during withering.

Evaluation of Polarized Projective Mapping as a possible tool for attributing South African Chenin blanc dry wine styles

Multiple Factor Analysis (MFA) According to the Chenin blanc Association of South Africa, there are three recognized dry wine styles, Fresh and Fruity (FF), Rich and Ripe Unwooded (RRU), and Rich and Ripe Wooded (RRW), classically attributed with the help of sensory evaluation. One of the “rapid methods” has drawn our attention for the purpose of simplifying and making style attribution for large sample sets, evaluated during different sessions, more robust. Polarized Projective Mapping (PPM) is a hybrid of Projective Mapping (PM) and Polarised Sensory Positioning (PSP). It is a reference-based method in which poles
(references) are used for the evaluation of similarities and dissimilarities between samples.