Macrowine 2021
IVES 9 IVES Conference Series 9 Colour assessment of port wines using colorimetric and spectrophotometric methods

Colour assessment of port wines using colorimetric and spectrophotometric methods

Abstract

Colour is an important quality parameter in wines and is the result of a complex mixture of pigments (including anthocyanins and their derivatives, quinones, xanthyllium compounds, etc.). Red wine colour changes over time as pigments react between themselves and with other wine macromolecules (particularly polyphenols). During wine tasting, colour is normally assessed on the outer rim of the wine profile in a tilted glass, since most wines are too opaque to be analysed in the middle of the glass. Therefore, depending on the depth of observation considered, the perception of wine colour can be different. The precise measurement of wine colour is usually done using molecular (UV-VIS) spectrophotometric methods. In the current official (OIV) method, the transmittance spectrum of a particular sample is measured and used to calculate CIE L*a*b* parameters, which define a single (predominant) colour for a particular wine. Reflectance colorimetry is an alternative well-established method for measuring colour in foodstuffs, which can also be used in transparent samples (such as wines) as long as a reflective background is used. In this work, a reflectance colorimeter was used to measure CIE L*a*b* colour parameters of Port wine samples of different categories at different depths, in Petri dishes. The obtained results were compared with the parameters obtained using the OIV method. Representative profiles of Lightness (L*), Hue (H*) and Chroma (C*) vs. wine depths were obtained using Port wine samples from different categories and ages. Wines from the same category exhibited similar colour (depth) profiles, with Tawny-styled wines showing a more linear profile than Ruby-styled wines regarding the L* and H* parameters. Good correlations between the colorimetric and OIV methods were obtained for the L* (Ruby:R >= 0.97; Tawny:R > 0.86) and H* parameters (Ruby:R >= 0.90; Tawny >= 0.91) with the C* parameter giving inferior results, particularly in Tawny-style wines (Ruby:R >= 0.87; Tawny >= 0.29). The results suggest the colorimetric method can be used as an alternative to the OIV method for estimating the L* and H* parameters (the most important for wine colour definition), being quicker and more informative.

Publication date: May 17, 2024

Issue: Macrowine 2016

Type: Poster

Authors

Francisco Silva*, Bento Amaral, Cristina Silva, Francisco Campos, Manuel Ferreira, Natalia Ribeiro, Tomas Simões

*Escola Sup. Biotecnologia – UCP

Contact the author

Tags

IVES Conference Series | Macrowine | Macrowine 2016

Citation

Related articles…

The effect of Nitrogen and Sulphur foliar applications in hot climates

ine nitrogen deficiency can negatively influence the aroma profile and ageing potential of white wines. Canopy management can alter vine microclimate, affect the nitrogen availability and influence the response of leaf senescence. Increasing the nitrogen availability to vines can increase the Yeast Assimilable Nitrogen (YAN) levels in harvested fruit and wine. Studies show that foliar nitrogen and sulphur applications at véraison, on low YAN Sauvignon blanc grapes have an effect on the level of amino acids (Jreij et al. 2009) and on S-containing compounds such as glutathione and thiols (Lacroux et al. 2008), which in turn can influence the formation of major volatiles and the aroma profile of the wine.

Full automation of oenological fermentations and its application to the processing of must containing high sugar or acetic acid concentrations

Climate change and harvest date decisions have led to the evolution of must quality over the last decades. Increases in must sugar concentrations are among the most obvious consequences, quantitatively. Saccharomyces cerevisiae is a robust and acid tolerant organism. These properties, its sugar to ethanol conversion rate and ethanol tolerance make it the ideal production organism for wine fermentations. Unfortunately, high sugar concentrations may affect S. cerevisiae and lead to growth inhibition or yeast lysis, and cause sluggish or stuck fermentations. Even sublethal conditions cause a hyperosmotic stress response in S. cerevisiae which leads to increased formation of fermentation by-products, including acetic acid, which may exceed legal limits in some wines.

Accumulation of polyphenols in Barbera and Nebbiolo leaves during the vegetative season

Grapevine berries produce thousands of secondary metabolites of diverse chemical nature that have been largely detailed in the past due to their importance for defining wine quality. The wide Vitis vinifera diversity, resulting in thousands of different varieties well detailed in many studies regarding berries, is still not investigated in vegetative organs, leaves in particular. Deepening knowledge related to this aspect could be of great interest for many reasons (for example the possibility of using leaf extract for pharmaceutical, cosmetic and nutrition purposes) but, above all, for understanding the susceptibility of different grapevine varieties to pathogens.

Interest and impact of PVP/PVI (Polyvinylpyrrolidone/ Polyvinylimidazole) on winemaking and final quality of wines

Céline Sparrow a, Christophe Morge a, a SOFRALAB SAS, 79, av. A.A. Thévenet – CS 11031 – 51530 Magenta, France Consumers’ health and security force authorities to limit, in wine as in others food industry products, the concentration in « dangerous » molecules. Therefore the legal limit in heavy metals keeps on decreasing. As per proof EU regulation just decrease the stain concentration in wine from 0,2 to 0,15 mg/l. Certain changes , such as sodium arsenite treatment in vines, disappearance of brass in wineries to the benefit of stainless steel, limit even more the concentration of heavy metals in wines. But the use of copper derivates in vines treatments is difficult to replace. In the case of wine and its elaboration, the problem is even more complex. Indeed, regulation forces the wine producers to control the concentration of certain heavy metals in final wines.

Impact of smoke exposure on the chemical composition of grapes

Vineyard exposure to smoke can lead to grapes and wine which exhibit objectionable smoky and ashy aromas and flavours, more commonly known as ‘smoke taint’ [1, 2]. In the last decade, significant bushfires have occurred around the world, including near wine regions in Australia, Canada, South Africa and the USA, as a consequence of the warmer, drier conditions associated with climate change. Considerable research has subsequently been undertaken to determine the chemical, sensory and physiological consequences of grapevine exposure to smoke. The sensory attributes associated with smoke-tainted wine have been linked to the presence of several smoke-derived volatile phenols, such as guaiacols, syringols and cresols [2].