Macrowine 2021
IVES 9 IVES Conference Series 9 Colour assessment of port wines using colorimetric and spectrophotometric methods

Colour assessment of port wines using colorimetric and spectrophotometric methods

Abstract

Colour is an important quality parameter in wines and is the result of a complex mixture of pigments (including anthocyanins and their derivatives, quinones, xanthyllium compounds, etc.). Red wine colour changes over time as pigments react between themselves and with other wine macromolecules (particularly polyphenols). During wine tasting, colour is normally assessed on the outer rim of the wine profile in a tilted glass, since most wines are too opaque to be analysed in the middle of the glass. Therefore, depending on the depth of observation considered, the perception of wine colour can be different. The precise measurement of wine colour is usually done using molecular (UV-VIS) spectrophotometric methods. In the current official (OIV) method, the transmittance spectrum of a particular sample is measured and used to calculate CIE L*a*b* parameters, which define a single (predominant) colour for a particular wine. Reflectance colorimetry is an alternative well-established method for measuring colour in foodstuffs, which can also be used in transparent samples (such as wines) as long as a reflective background is used. In this work, a reflectance colorimeter was used to measure CIE L*a*b* colour parameters of Port wine samples of different categories at different depths, in Petri dishes. The obtained results were compared with the parameters obtained using the OIV method. Representative profiles of Lightness (L*), Hue (H*) and Chroma (C*) vs. wine depths were obtained using Port wine samples from different categories and ages. Wines from the same category exhibited similar colour (depth) profiles, with Tawny-styled wines showing a more linear profile than Ruby-styled wines regarding the L* and H* parameters. Good correlations between the colorimetric and OIV methods were obtained for the L* (Ruby:R >= 0.97; Tawny:R > 0.86) and H* parameters (Ruby:R >= 0.90; Tawny >= 0.91) with the C* parameter giving inferior results, particularly in Tawny-style wines (Ruby:R >= 0.87; Tawny >= 0.29). The results suggest the colorimetric method can be used as an alternative to the OIV method for estimating the L* and H* parameters (the most important for wine colour definition), being quicker and more informative.

Publication date: May 17, 2024

Issue: Macrowine 2016

Type: Poster

Authors

Francisco Silva*, Bento Amaral, Cristina Silva, Francisco Campos, Manuel Ferreira, Natalia Ribeiro, Tomas Simões

*Escola Sup. Biotecnologia – UCP

Contact the author

Tags

IVES Conference Series | Macrowine | Macrowine 2016

Citation

Related articles…

Evidence for terroir effect associated with botrytisation relatively to compounds implicated in typical aromas of noble rot sweet wines

Recent studies have demonstrated the role of certain lactones, particularly 2-nonen-4-olide, and volatile thiols (3-sulfanylhexan-1-ol) in the over ripped aromas of noble rot sweet wines (Stamatopoulos et al. 2014ab). These compounds are partly formed during the maturation and under the activity of B. cinerea on grapes. This research was carried out in the vineyard of Sauternes with aim to better understand their genesis depending on the grape over-ripening on two different soil types during 3 vintages. Thus, the study was conducted, with the Sémillon grape, during vintages 2012, 2014 & 2015, at 4 stages of over-maturation of the grapes (healthy, pourri plein, pourri roti, pourri roti + 15 days) considering two vineyard plots with different soil characteristics (calcosol & peyrosol) planted with the 315 Sémillon clone and grafted on 101-14 rootstock respectively in 1981 and 1980 and cultivated with the same vineyard management. Volatile lactones were assayed by liquid-liquid extraction followed by GC/MS analysis and the precursors of 3-sulfanylhexanol by an adaptation of the method by Capone et al. 2010 (SPE-
UPLC/FTMS).

HEAT BERRY : Sensitivity of berries ripening to higher temperature and impact on phenolic compounds in wine

The grapevine is an important economical crop that is very sensitive to climate changes and microclimate. The observations made during the last decades at a vineyard scale all concur to show the impact of climate change on vine physiology, resulting in accelerated phenology and earlier harvest (Jones and Davis 2000). It is well-known that berry content is affected by the ambient temperature. While the first experiences were primarily conducted on the impact of temperature on anthocyanin accumulation in the grape, few studies have focused on others component of phenolic metabolism, such as tannins.

Effects of bottle closure type on sensory characteristics of Chasselas wines

Several winemaking operations, such as filtration, pumping, and racking, are known to potentially facilitate the incorporation of atmospheric O2 into the wine. Control of grape must oxidation is one key aspect in the management of white wine aroma expression, color stability and shelf-life extension. On the one hand, controlled must oxidation may help to remove highly reactive phenolic compounds, which otherwise could contribute to premature oxidation. And on the other hand, in certain cases of extreme protection of the must from O2 (e.g. pressing under inert atmosphere), it can help to preserve varietal aromas and natural must antioxidants.

Correlations between N,S,O-heterocycle levels and age of Champagne base wines

Champagne regulation allows winegrowers to stock small amounts of still wines in order to compensate vintages’ quality shifts mainly due to climate variations. According to their technical requirements and house style some Champagne producers (commonly named “Champagne houses”) use these stored wines in the blend in order to introduce an element of complexity. These wines possess the particularity of being aged on fine lees in thermo-regulated stainless steel tanks. The Champagne house of Veuve Clicquot Ponsardin has several wines stored this way.

Effect of nanofiltration on the chemical composition and wine quality

In Enology the conventional processes of filtration for clarification and stabilization are giving place to alternative membrane processes, including nanofiltration (NF). Furthermore, the increased alcohol content in wines recorded in recent years became an important issue for all the main wine producing countries. Among techniques available to the wine industry to reduce the ethanol content, NF is certainly one of the newest. This study is focused on the evaluation of NF influence on wine physical-chemical composition, including mineral content, which in accordance to our best knowledge is a novelty.