Macrowine 2021
IVES 9 IVES Conference Series 9 Colour assessment of port wines using colorimetric and spectrophotometric methods

Colour assessment of port wines using colorimetric and spectrophotometric methods

Abstract

Colour is an important quality parameter in wines and is the result of a complex mixture of pigments (including anthocyanins and their derivatives, quinones, xanthyllium compounds, etc.). Red wine colour changes over time as pigments react between themselves and with other wine macromolecules (particularly polyphenols). During wine tasting, colour is normally assessed on the outer rim of the wine profile in a tilted glass, since most wines are too opaque to be analysed in the middle of the glass. Therefore, depending on the depth of observation considered, the perception of wine colour can be different. The precise measurement of wine colour is usually done using molecular (UV-VIS) spectrophotometric methods. In the current official (OIV) method, the transmittance spectrum of a particular sample is measured and used to calculate CIE L*a*b* parameters, which define a single (predominant) colour for a particular wine. Reflectance colorimetry is an alternative well-established method for measuring colour in foodstuffs, which can also be used in transparent samples (such as wines) as long as a reflective background is used. In this work, a reflectance colorimeter was used to measure CIE L*a*b* colour parameters of Port wine samples of different categories at different depths, in Petri dishes. The obtained results were compared with the parameters obtained using the OIV method. Representative profiles of Lightness (L*), Hue (H*) and Chroma (C*) vs. wine depths were obtained using Port wine samples from different categories and ages. Wines from the same category exhibited similar colour (depth) profiles, with Tawny-styled wines showing a more linear profile than Ruby-styled wines regarding the L* and H* parameters. Good correlations between the colorimetric and OIV methods were obtained for the L* (Ruby:R >= 0.97; Tawny:R > 0.86) and H* parameters (Ruby:R >= 0.90; Tawny >= 0.91) with the C* parameter giving inferior results, particularly in Tawny-style wines (Ruby:R >= 0.87; Tawny >= 0.29). The results suggest the colorimetric method can be used as an alternative to the OIV method for estimating the L* and H* parameters (the most important for wine colour definition), being quicker and more informative.

Publication date: May 17, 2024

Issue: Macrowine 2016

Type: Poster

Authors

Francisco Silva*, Bento Amaral, Cristina Silva, Francisco Campos, Manuel Ferreira, Natalia Ribeiro, Tomas Simões

*Escola Sup. Biotecnologia – UCP

Contact the author

Tags

IVES Conference Series | Macrowine | Macrowine 2016

Citation

Related articles…

Sensory and nephelometric analysis of tannin fractions obtained by ultrafiltration of red wines

The assessment of red wine mouthfeel relies primarily on the sensory description of its tannic properties. This evaluation could be improved by gaining a better understanding of the physicochemical properties of these tannins. Hence, the objectives of the present study were threefold: (1) to gain an insight into the sensory properties of subpopulations of proanthocyanidic tannins of different molecular sizes obtained through several ultrafiltration steps, (2) to quantify the kinetics of haze formation of these proanthocyanidic tannins in a dynamic polyvinylpyrrolidone (PVP) precipitation test, (3) to determine whether a correlation exists between the sensory and the precipitation data.

Sensory impacts of the obturator used for the Chasselas: study over the time

Many parameters affect the organoleptic characteristics of wine: internal parameters like the chemical composition or polyphenol content and external as for example storage conditions or the type of obturator. The aim of this study was to characterize sensorally the impacts of several type of obturator on a white wine: Chasselas. To determine the organoleptic characteristics of this wine, a quantitative descriptive analysis could be used. But rapid sensory methods were preferred in this project. Indeed these methods are an appropriate alternative to conventional descriptive methods for quickly assessing sensory product discrimination.

Identification, quantification and organoleptic impact of « dried fruit » molecular markers in Merlot and Cabernet Sauvignon grapes and in red wines

The aromas found in young Bordeaux red wines made with Merlot and Cabernet Sauvignon suggest a complex mixture of aromas of fresh red fruits such as cherry or blackberry for Merlot, and strawberry or blackcurrant for Cabernet Sauvignon. The aromas of these wines are closely linked with the maturity of the grapes. The climate change that has occurred during the last decade in Bordeaux has induced changes in the ripening conditions of grape berries. It is now widely admitted that over-ripening of the berries during hot and dry summers results in the development of characteristic flavors reminiscent of cooked fruits (fig, prune). The presence of these overriding odors found in both musts and young wines affects the quality and subtlety of the wine flavor and may shorten its shelf life.

Dissecting the polysaccharide‐rich grape cell wall matrix during the red winemaking process, using high‐throughput and fractionation methods

Limited information is available on grape wall-derived polymeric structure/composition and how this changes during fermentation. Commercial winemaking operations use enzymes that target the polysaccharide-rich polymers of the cell walls of grape tissues to clarify musts and extract pigments during the fermentations. In this study we have assessed changes in polysaccharide composition/ turnover throughout the winemaking process by applying recently developed cell wall profiling approaches to both wine and pomace polysaccharides. The methods included gas chromatography for monosaccharide composition (GC-MS), infra-red (IR) spectroscopy and comprehensive microarray polymer profiling
(CoMPP) using cell wall probes.

Bentonite fining in cold wines: prediction tests, reduced efficiency and possibilities to avoid additional fining treatments

Bentonite fining is widely used to prevent protein haze in white wines. Most wineries use laboratory-scale fining trials to define the appropriate amount of bentonite to be used in the cellar. Those pre-tests need to mimic as much as possible the industrial scale fining procedure to determine the exact amount of bentonite necessary for protein stability. Nevertheless it is frequent that, after fining with the recommended amount of bentonite, wines appear still unstable and need an additional fining treatment. It remains a major challenge to understand why the same wine, fined with the same dosage of the same bentonite, achieves stability in the lab, but not in the cellar.