Macrowine 2021
IVES 9 IVES Conference Series 9 Correlations between N,S,O-heterocycle levels and age of Champagne base wines

Correlations between N,S,O-heterocycle levels and age of Champagne base wines

Abstract

Champagne regulation allows winegrowers to stock small amounts of still wines in order to compensate vintages’ quality shifts mainly due to climate variations. According to their technical requirements and house style some Champagne producers (commonly named “Champagne houses”) use these stored wines in the blend in order to introduce an element of complexity. These wines possess the particularity of being aged on fine lees in thermo-regulated stainless steel tanks. The Champagne house of Veuve Clicquot Ponsardin has several wines stored this way. The oldest of these wines dates back to 1988. The role of lees and ageing in a low-pH (<=3) as in Champagne leads to several modifications of wine composition1. Lees are known to affect wine redox potential and liberate protein and free amino acids. These conditions combined with extended ageing result in the required environment for the Maillard chemical reaction whose aromatic molecules including sulphur, oxygen and nitrogen heterocycles (such as thiazole, furan and pyrazines derivatives) may have a sensory impact on wine2. The 50 mono-varietal wines aged from 1 to 28 years, have been provided by Veuve Clicquot Ponsardin wherein some wines aromatic heterocycles were determined by the SPME-GC-MS method3. To identify any possible correlation between these aromatic compounds end their precursors, 21 amino acids were determined by HPLC-fluorimetry method4. The most interesting result highlights a strong correlation between certain heterocycle concentrations and age of wine. That suggests these compounds as potential indicators of lees ageing. As such they can be considered as potential key compounds of the bouquet of aged Champagnes. The principle outcome of these assays has revealed for the first time in Champagne base wines that aromatic heterocycles concentration are correlated with wine age.

1. Alexandre, H. & Guilloux-Benatier, M. Yeast autolysis in sparkling wine – A review. Aust. J. Grape Wine Res. 12, 119–127 (2006). 2. Marchand, S., De Revel, G. & Bertrand, A. Approaches to wine aroma: Release of aroma compounds from reactions between cysteine and carbonyl compounds in wine. J. Agric. Food Chem. 48, 4890–4895 (2000). 3. Burin, V. M., Marchand, S., De Revel, G. & Bordignon-Luiz, M. T. Development and validation of method for heterocyclic compounds in wine: Optimization of HS-SPME conditions applying a response surface methodology. Talanta 117, 87–93 (2013). 4. Pripis-Nicolau, L., De Revel, G., Marchand, S., Beloqui, A. A. & Bertrand, A. Automated HPLC method for the measurement of free amino acids including cysteine in musts and wines; first applications. J. Sci. Food Agric. 81, 731–738 (2001).

Publication date: May 17, 2024

Issue: Macrowine 2016

Type: Poster

Authors

Nicolas Le Menn*, Delphine Laborde, DEMARVILLE Dominique, Gilles De Revel, Richard Marchal, Stéphanie Marchand

*ISVV

Contact the author

Tags

IVES Conference Series | Macrowine | Macrowine 2016

Citation

Related articles…

Anthropogenic factors in modulations of fungal populations from grapes to wines and their repercussions on wine characteristics

The effects of anthropogenic activities on vineyard (different plant protections) and in winery
(pressing/clarification step, addition of sulfur dioxide) on fungal populations from grape to wine were studied. The studied anthropogenic activities modify the fungal diversity. Thus, lower biodiversity of grapes from organic modality was measured for the three vintages considered compared to biodiversity from ecophyto modality and conventional modality. The pressing / clarification steps strongly modify fungal populations and the influence of the winery flora is highlighted.

Study of the content of amino acids and biogenic amines in sparkling red wines

The production of red sparkling wines is lower in Spain in comparison with the winemaking of white or rosé sparkling wines. In red sparkling wine processing it is essential to obtain suitable base wines that should have moderate alcohol content, high acidity, good color values, an adequate mouth-feel and a sweet tannin. Grapes for sparkling wine production have to be harvested at low maturity stages, with lower alcohol contents and higher acidities, which will that the phenolic maturity of the grapes is also low, showing green tannins. This paper analyses different treatments in order to minimize these inconveniences: cold maceration-prefermentation and delestage to elaborate the grapes with lower maturity, must nanofiltration, and the partial osmosis of the wines made from grapes with an adequate maturity degree.

Intelligent article to control the internal pressure in continue in bottles

An intelligent packaging might, among others, provide information and allow monitoring of the quality of the packed product or its surrounding environment. A recent project on micro-flow wine bottles closed with aluminium screw cap and tightness liner, highlighted the importance of monitoring the internal overpressure continuously, in real-time and at least for 72 hours, since the internal pressure on the tightness liner and the micro-flow are related. Real-time and continuous measurements are not the standard methods of measurement of the overpressure, yet. The most used equipment for the determination of the pressure in wine bottle is the aphrometer, a destructive device that supplies a single value of pressure.

Study of the volatil profile of minority white varieties

The genetic material preservation is a priority issue in winemaking research. The recovery of minority grape varieties can control the genetic erosion, contributing also to preserve wine typical characteristics. In D.O.Ca. Rioja (Spain) the number of grown white varieties has been very limited, representing Viura the 91% of the cultivated white grape area in 2005, while the others, Garnacha Blanca and Malvasía riojana, hardly were grown. For this reason, a recovery and characterization study of plant material was carried out in this region. In 2008, the results obtained allowed the authorization of three minority white varieties: Tempranillo Blanco, Maturana Blanca and Turruntés.

Effect of intra‐vineyard ripeness variation on the efficiency of commercial enzymes on berry cell wall deconstruction under winemaking conditions

Intra-vineyard variation grape berry ripening occurs within bunches, between bunches on the same vine and between vines. Although it is assumed that such variation also occurs at the grape berry cell wall level, no study to data has investigated in any depth. Here we have used a intra-vineyard panel design to investigate pooled bunches from six vines (per panel) in the context of a winemaking scenario. The dissected vineyard was harvested by separate panels, where each panel was then subjected to a standard winemaking procedure with or without the addition of three different enzyme preparations for maceration.