Macrowine 2021
IVES 9 IVES Conference Series 9 Correlations between N,S,O-heterocycle levels and age of Champagne base wines

Correlations between N,S,O-heterocycle levels and age of Champagne base wines

Abstract

Champagne regulation allows winegrowers to stock small amounts of still wines in order to compensate vintages’ quality shifts mainly due to climate variations. According to their technical requirements and house style some Champagne producers (commonly named “Champagne houses”) use these stored wines in the blend in order to introduce an element of complexity. These wines possess the particularity of being aged on fine lees in thermo-regulated stainless steel tanks. The Champagne house of Veuve Clicquot Ponsardin has several wines stored this way. The oldest of these wines dates back to 1988. The role of lees and ageing in a low-pH (<=3) as in Champagne leads to several modifications of wine composition1. Lees are known to affect wine redox potential and liberate protein and free amino acids. These conditions combined with extended ageing result in the required environment for the Maillard chemical reaction whose aromatic molecules including sulphur, oxygen and nitrogen heterocycles (such as thiazole, furan and pyrazines derivatives) may have a sensory impact on wine2. The 50 mono-varietal wines aged from 1 to 28 years, have been provided by Veuve Clicquot Ponsardin wherein some wines aromatic heterocycles were determined by the SPME-GC-MS method3. To identify any possible correlation between these aromatic compounds end their precursors, 21 amino acids were determined by HPLC-fluorimetry method4. The most interesting result highlights a strong correlation between certain heterocycle concentrations and age of wine. That suggests these compounds as potential indicators of lees ageing. As such they can be considered as potential key compounds of the bouquet of aged Champagnes. The principle outcome of these assays has revealed for the first time in Champagne base wines that aromatic heterocycles concentration are correlated with wine age.

1. Alexandre, H. & Guilloux-Benatier, M. Yeast autolysis in sparkling wine – A review. Aust. J. Grape Wine Res. 12, 119–127 (2006). 2. Marchand, S., De Revel, G. & Bertrand, A. Approaches to wine aroma: Release of aroma compounds from reactions between cysteine and carbonyl compounds in wine. J. Agric. Food Chem. 48, 4890–4895 (2000). 3. Burin, V. M., Marchand, S., De Revel, G. & Bordignon-Luiz, M. T. Development and validation of method for heterocyclic compounds in wine: Optimization of HS-SPME conditions applying a response surface methodology. Talanta 117, 87–93 (2013). 4. Pripis-Nicolau, L., De Revel, G., Marchand, S., Beloqui, A. A. & Bertrand, A. Automated HPLC method for the measurement of free amino acids including cysteine in musts and wines; first applications. J. Sci. Food Agric. 81, 731–738 (2001).

Publication date: May 17, 2024

Issue: Macrowine 2016

Type: Poster

Authors

Nicolas Le Menn*, Delphine Laborde, DEMARVILLE Dominique, Gilles De Revel, Richard Marchal, Stéphanie Marchand

*ISVV

Contact the author

Tags

IVES Conference Series | Macrowine | Macrowine 2016

Citation

Related articles…

Glutathione content evolution during spontaneous alcoholic fermentations of Sangiovese grapes

Glutathione is a tripeptide (γ-Glu-Cys-Gly), which can occur in grapes, in must and in wine prevalently in the reduced form as well as in the oxidized form as glutathione disulfide. The importance of the reduced form of glutathione lies in its antioxidant activity. In must, it limits browning by reducing o-quinones produced by polyphenol oxidase activity on hydroxycinnamic acids; in wine, it exerts a protective effect on various aromatic compounds. Glutathione concentration in wine is lower than in grape juice and variable as it depends on several factors, ranging from the native content of grapes to winemaking technique.

How do different oak treatment affect the sensory composition of Chenin blanc wines over time?

Wooden barrels have been the preferred method for oak maturation for wines, but the use of alternative oak products, such as staves and oak chips have increased in South Africa due to lower production costs. This study investigated the effect of different oak products used during fermentation and ageing on the sensory profile, degree of liking and perceived quality of a South African Chenin blanc wine. The different wine treatments included an unoaked tank control wine, wines matured in 5th fill barrels, wines matured in new barrels from three different cooperages, and wines matured in 5th fill barrels with stave inserts from two different cooperages.

HEAT BERRY : Sensitivity of berries ripening to higher temperature and impact on phenolic compounds in wine

The grapevine is an important economical crop that is very sensitive to climate changes and microclimate. The observations made during the last decades at a vineyard scale all concur to show the impact of climate change on vine physiology, resulting in accelerated phenology and earlier harvest (Jones and Davis 2000). It is well-known that berry content is affected by the ambient temperature. While the first experiences were primarily conducted on the impact of temperature on anthocyanin accumulation in the grape, few studies have focused on others component of phenolic metabolism, such as tannins.

Ageing of Sauvignon Blanc white wines with Specific Inactivated Dry Yeasts: Effect on physical and chemical characteristics

Del Barrio-Galán, R.a, b, Gómez-Parrini, A.a, Peña-Neira, A.b a Lallemand Inc. Chile y Compañía Limitada, Rosario Norte 407, piso 6, Las condes, Santiago, Chile b Department of Agro-Industry and Enology, Faculty of Agronomical Sciences, University of Chile, Post Office Box 1004, Santa Rosa 11315, La Pintana, Santiago, Chile It is well known that polysaccharides, mainly mannoproteins, play an important role on physical, chemical and sensory quality of wines. The ageing of white wines on lees is used in order to release higher amounts of polysaccharides by the autolytic processes in order to obtain higher-quality wines. However, this technique is too slow, because the temperature and pH conditions are not the most suitable for this process. In addition, it can also involve certain disadvantages such as a greater demand on winery resources, a longer period of wine storage, the appearance of reduction notes and some microbiological alterations.

Elicitors used as a tool to increase stilbenes in grapes and wines

The economic importance of grapevine as a crop plant makes Vitis vinífera a good model system to study the improvement of the nutraceutical properties of food products (Vezulli et al. 2007). Stilbenes in general, and trans-resveratrol in particular, have been reported to be responsible for various beneficial effects. Resveratrol´s biological properties include antibacteria and antifungal effects, as well as cardioprotective, neuroprotective and anticâncer actions (Guerrero et al. 2010 ). Stilbenes can be induced by biotic and abiotic elicitors since they are phytoalexins (Bavaresco et al. 2001).