Macrowine 2021
IVES 9 IVES Conference Series 9 Correlations between N,S,O-heterocycle levels and age of Champagne base wines

Correlations between N,S,O-heterocycle levels and age of Champagne base wines

Abstract

Champagne regulation allows winegrowers to stock small amounts of still wines in order to compensate vintages’ quality shifts mainly due to climate variations. According to their technical requirements and house style some Champagne producers (commonly named “Champagne houses”) use these stored wines in the blend in order to introduce an element of complexity. These wines possess the particularity of being aged on fine lees in thermo-regulated stainless steel tanks. The Champagne house of Veuve Clicquot Ponsardin has several wines stored this way. The oldest of these wines dates back to 1988. The role of lees and ageing in a low-pH (<=3) as in Champagne leads to several modifications of wine composition1. Lees are known to affect wine redox potential and liberate protein and free amino acids. These conditions combined with extended ageing result in the required environment for the Maillard chemical reaction whose aromatic molecules including sulphur, oxygen and nitrogen heterocycles (such as thiazole, furan and pyrazines derivatives) may have a sensory impact on wine2. The 50 mono-varietal wines aged from 1 to 28 years, have been provided by Veuve Clicquot Ponsardin wherein some wines aromatic heterocycles were determined by the SPME-GC-MS method3. To identify any possible correlation between these aromatic compounds end their precursors, 21 amino acids were determined by HPLC-fluorimetry method4. The most interesting result highlights a strong correlation between certain heterocycle concentrations and age of wine. That suggests these compounds as potential indicators of lees ageing. As such they can be considered as potential key compounds of the bouquet of aged Champagnes. The principle outcome of these assays has revealed for the first time in Champagne base wines that aromatic heterocycles concentration are correlated with wine age.

1. Alexandre, H. & Guilloux-Benatier, M. Yeast autolysis in sparkling wine – A review. Aust. J. Grape Wine Res. 12, 119–127 (2006). 2. Marchand, S., De Revel, G. & Bertrand, A. Approaches to wine aroma: Release of aroma compounds from reactions between cysteine and carbonyl compounds in wine. J. Agric. Food Chem. 48, 4890–4895 (2000). 3. Burin, V. M., Marchand, S., De Revel, G. & Bordignon-Luiz, M. T. Development and validation of method for heterocyclic compounds in wine: Optimization of HS-SPME conditions applying a response surface methodology. Talanta 117, 87–93 (2013). 4. Pripis-Nicolau, L., De Revel, G., Marchand, S., Beloqui, A. A. & Bertrand, A. Automated HPLC method for the measurement of free amino acids including cysteine in musts and wines; first applications. J. Sci. Food Agric. 81, 731–738 (2001).

Publication date: May 17, 2024

Issue: Macrowine 2016

Type: Poster

Authors

Nicolas Le Menn*, Delphine Laborde, DEMARVILLE Dominique, Gilles De Revel, Richard Marchal, Stéphanie Marchand

*ISVV

Contact the author

Tags

IVES Conference Series | Macrowine | Macrowine 2016

Citation

Related articles…

Identification of caffeic acid as a major component of Moscatel wine protein sediment

Proteins play a significant role in the colloidal stability and clarity of white wines [1]. However, under conditions of high temperatures during storage or transportation, the proteins themselves can self-aggregate into light-dispersing particles causing the so-called protein haze [2]. Formation of these unattractive precipitates in bottled wine is a common defect of commercial wines, making them unacceptable for sale [3]. Previous studies identified the presence of phenolic compounds in the natural precipitate of white wine [4], contributing to the hypothesis that these compounds could be involved in the mechanism of protein haze formation.

Analysis of the oenological potentials of different oak forests in Hungary

Like France, Hungary has many oak forests used for making barrels since many years. But if the differences between the woods of the North, the East and the South-West forests of France are well known, this is probably not the case of Hungarian forests. However taking into account the essential differences of climates and soils, differences must be significant and the general name “Hungarian oak” must not have any real meaning. We have studied precisely (determination of concentrations of volatile and non-volatile wood compounds, anatomical criteria, measurement of antioxidant capacity) of oaks collected from northeastern Hungary and others collected from the Danube valley in the northwest of the country.

The challenge of quality in sulphur dioxide free wines: natural polyphenol alternatives

Sulphur dioxide (SO2) seems indispensable in winemaking because of its properties. However, a current increasing concern about its allergies effects in food product has addressed the international research efforts on its replacement. This supposes a sufficient knowledge of its properties and conditions of use. Several studies compared SO2 properties against new alternatives that are supposed to overcome SO2 disadvantages. Firstly, the state of art on SO2 wine replacements is revised, and secondly, the last promising results using natural enriched polyphenol extracts are shown.

A preliminary study of clonal selection in cv. Viura in relation to varietal aroma profile

Viura is a synonym for Macabeo and currently it is the most widely planted white grape variety in D.O.Ca. Rioja, with 3,569 ha, representing 84% of the white grape cultivated area. It is a generous-yielding grape, presenting low values of titratable acidity and with large and compact clusters which makes it susceptible to Botrytis cinerea. Thus, this variety not always satisfies the wine grower’s prospects. Nowadays, the available plant material is scarce, moreover, it was selected on the basis of other quality criteria, not currently requested.

Use of computational modelling for selecting adsorbents for improved fining of wine

The occurrence of faults and taints in wine, such as those caused by microbial spoilage or various taints, have resulted in significant financial losses to wine producers. The wine industry commits significant financial resources towards fining and taint removal processes each year. Fining involves the addition of one or more adsorptive substrates to juice or wine to bind certain components, thus reducing their concentration [1]. However, these processes are often not selective and can also remove desirable flavour and aroma compounds.