Macrowine 2021
IVES 9 IVES Conference Series 9 Correlations between N,S,O-heterocycle levels and age of Champagne base wines

Correlations between N,S,O-heterocycle levels and age of Champagne base wines

Abstract

Champagne regulation allows winegrowers to stock small amounts of still wines in order to compensate vintages’ quality shifts mainly due to climate variations. According to their technical requirements and house style some Champagne producers (commonly named “Champagne houses”) use these stored wines in the blend in order to introduce an element of complexity. These wines possess the particularity of being aged on fine lees in thermo-regulated stainless steel tanks. The Champagne house of Veuve Clicquot Ponsardin has several wines stored this way. The oldest of these wines dates back to 1988. The role of lees and ageing in a low-pH (<=3) as in Champagne leads to several modifications of wine composition1. Lees are known to affect wine redox potential and liberate protein and free amino acids. These conditions combined with extended ageing result in the required environment for the Maillard chemical reaction whose aromatic molecules including sulphur, oxygen and nitrogen heterocycles (such as thiazole, furan and pyrazines derivatives) may have a sensory impact on wine2. The 50 mono-varietal wines aged from 1 to 28 years, have been provided by Veuve Clicquot Ponsardin wherein some wines aromatic heterocycles were determined by the SPME-GC-MS method3. To identify any possible correlation between these aromatic compounds end their precursors, 21 amino acids were determined by HPLC-fluorimetry method4. The most interesting result highlights a strong correlation between certain heterocycle concentrations and age of wine. That suggests these compounds as potential indicators of lees ageing. As such they can be considered as potential key compounds of the bouquet of aged Champagnes. The principle outcome of these assays has revealed for the first time in Champagne base wines that aromatic heterocycles concentration are correlated with wine age.

1. Alexandre, H. & Guilloux-Benatier, M. Yeast autolysis in sparkling wine – A review. Aust. J. Grape Wine Res. 12, 119–127 (2006). 2. Marchand, S., De Revel, G. & Bertrand, A. Approaches to wine aroma: Release of aroma compounds from reactions between cysteine and carbonyl compounds in wine. J. Agric. Food Chem. 48, 4890–4895 (2000). 3. Burin, V. M., Marchand, S., De Revel, G. & Bordignon-Luiz, M. T. Development and validation of method for heterocyclic compounds in wine: Optimization of HS-SPME conditions applying a response surface methodology. Talanta 117, 87–93 (2013). 4. Pripis-Nicolau, L., De Revel, G., Marchand, S., Beloqui, A. A. & Bertrand, A. Automated HPLC method for the measurement of free amino acids including cysteine in musts and wines; first applications. J. Sci. Food Agric. 81, 731–738 (2001).

Publication date: May 17, 2024

Issue: Macrowine 2016

Type: Poster

Authors

Nicolas Le Menn*, Delphine Laborde, DEMARVILLE Dominique, Gilles De Revel, Richard Marchal, Stéphanie Marchand

*ISVV

Contact the author

Tags

IVES Conference Series | Macrowine | Macrowine 2016

Citation

Related articles…

Maturation of Agiorgitiko (Vitis vinifera) red wine on its wine lees: Impact on its phenolic composition

Maturation of wine on lees (often referred as sur lie) is a common practice applied by many winemakers around the world. In the past this method was applied mainly on white and/or sparkling wine production but recently also to red wine production. In our experiment, we matured red wine on wine lees of two origins: a) Light wine lees, collected after the completion of the alcoholic fermentation, b) Heavy lees, collected after the completion of the malolactic fermentation. The lees were free of off-odors and were added in the red wine in percentage 3% and 8%, simulating common winemaking addition. The maturation lasted in total six months and samples were collected for analysis after one, three and six months. During storage the lees were stirred.

Merging fast sensory profiling with non-targeted GC-MS analysis for multifactorial experimental wine making

Wine aroma is influenced by several viticultural and oenological factors. In this study we used experimental wine making in a full factorial design to determine the impact of grapevine age, must turbidity, and yeast strain on the aroma of Vitis vinifera L. cv. Riesling wines. A recently developed, non-targeted SPME-GC-MS fingerprinting approach for wine volatiles was used. This approach includes the segmentation and mathematical transformation of chromatograms in combination with Parallel Factor Analysis (PARAFAC) and subsequent deconvolution of important chromatogram segments.

DNA and type of grain: which factor does better explain sensory differences of sessile and pedunculate oaks?

Sessile oak and pedunculate oak have shown several differences of interest for enological purposes. Tannic and aromatic composition among sessile oak or pedonculate oak has been well studied. Sessile oak is generally more aromatic than pedunculated, while the later is more tannic. This scientific point of view is rarely applied to classify oak in cooperages. Most coopers use the type of grain to distinguish wide and thin grain.

Effect of malolactic fermentation in barrels or stainless steel tanks on wine composition. Influence of the barrel toasting

Ellagitannin, anthocyanin and woody volatile composition of Cabernet Sauvignon wines aged in oak barrels for 12 months was evaluated. Depending on the container where malolactic fermentation (MLF) was carried out, two wine modalities were investigated: wines with MLF carried out in stainless steel tanks and barrel-fermented wines. Three toasting methods (medium toast, MT; medium toast with watering, MTAA; noisette) were considered for ageing of each wine modality. Sensory analyses (triangle and rating tests) were also performed. Two-way ANOVA of the raw experimental data revealed that the toasting method and the container where MLF took place, as well as the interaction between both factors, have a significant influence (p < 0.05) on ellagitannin, anthocyanin and woody volatile profiles of Cabernet Sauvignon wines.

Innovations in the use of bentonite in enology: interactions with grape and wine proteins, colloids, polyphenols and aroma compounds.

The use of bentonite in oenology rounds around the limpidity and the stability that determine consumer acceptability. As a matter of fact, the haze formation in wine reduces its commercial value and makes it unacceptable for sale. Stabilization treatments are, therefore, essential to ensure a long-time limpidity and to forecast the formation of deposits in the bottle. Bentonite that is normally used in oenology for clarifying-fining purpose, shows a natural clay-based mineral structure allowing it to swell and to jelly in water and hence in must and wine.