Macrowine 2021
IVES 9 IVES Conference Series 9 Supramolecular approaches to the study of the astringency elicited by wine phenolic compounds

Supramolecular approaches to the study of the astringency elicited by wine phenolic compounds

Abstract

The objective of this study is to review the scientific evidences and to advance into the knowledge of the molecular mechanisms of astringency. Astringency has been described as the drying, roughing and puckering sensation perceived when some food and beverages are tasted (1). The main, but possibly not the only, mechanism for the astringency is the precipitation of salivary proteins (2,3). Between phenolic compounds found in red wines, flavan-3-ols are the group usually related to the development of this sensation. Other compounds, phenolic or not, like anthocyanins, polysaccharides and mannoproteins could act modifying or modulating astringency perception by hindering the interaction between flavanols and salivary proteins either because of their interaction with the flavanols or because of their interaction with the salivary proteins. Furthermore, the possible existence of synergism on astringency between phenolic substances (4) has recently arisen. Salivary proteins have been grouped in six main classes: histatins, statherin, cystatins, and proline-rich proteins (acidic, basic and glycosylated) (5). The possible existence of selective interactions between different types of wine phenolic compounds and different salivary protein classes could be responsible for the observed synergisms. To obtain further insights into the interactions between these compounds and salivary proteins that could explain the synergistic effect observed, we have studied the interactions between flavanols and salivary proteins by quenching of fluorescence and HPLC-DAD. Quenching constants calculated and chromatographic profiles obtained could partially explain the synergisms observed in the sensory evaluation of wine phenolic compounds. Furthermore, the effect of the presence of other molecular species, in particular anthocyanins, in the interactions between flavanols and salivary proteins has also been studied. Results obtained confirm the existence of interactions between anthocyanins and salivary proteins which could hinder the interaction between flavanols and salivary proteins, affecting the perceived astringency.

References 1. Gawel, R.; Iland, P. G.; Francis, I. L. Food Quality and Preference 2001, 12, 83-94. 2. de Freitas, V.; Mateus, N. Current Organic Chemistry 2012, 16, 724-746. 3. Scollary, G. R.; Pasti, G.; Kallay, M.; Blackman, J.; Clark, A. C. Trends in Food Science & Technology 2012, 27, 25-36. 4. Ferrer-Gallego, R.; Henández-Hierro, J.M.; Rivas-Gonzalo, J.C.; Escribano-Bailón, M.T. Food Research International 2014, 62, 1100-1107 (). 5. Humphrey, S. P.; Williamson, R. T. Journal of Prosthetic Dentistry 2001, 85, 162-169. Acknowledgement Thanks are due to Spanish MINECO for financial support (AGL2014-58486-C2-1-R)

Publication date: May 17, 2024

Issue: Macrowine 2016

Type: Poster

Authors

Teresa Escribano-Bailon*, Alba Ramos-Pineda, Cristina Alcalde-Eon, Ignacio García Estévez, Julian Rivas-Gonzalo, Monserrat Dueñas

*University of Salamanca

Contact the author

Tags

IVES Conference Series | Macrowine | Macrowine 2016

Citation

Related articles…

The effect of cropload on the volatile aroma characteristics of ‘Beihong’ and ‘Beimei’ red wine

Beihong and Beimei were bred as winemaking cultivars released by Institute of Botany, the Chinese Academy of Sciences in 2008. The cultivars are selected from the population of ‘Muscat Hamburg’ (Vitis vinifera) ×V. amurensis. They are extended to most provinces in North of China because they have strong resistance to cold and disease and need not be buried in soil in winter. To better understand the effect of cropload on volatile compounds during wine-making, we surveyed volatiles composition and content of different cropload level in 3-years-old ‘Beihong’ and ‘Beimei’ vines which planted in east foot of Helan mountain of Ningxia (EHN).

Evaluation of Polarized Projective Mapping as a possible tool for attributing South African Chenin blanc dry wine styles

Multiple Factor Analysis (MFA) According to the Chenin blanc Association of South Africa, there are three recognized dry wine styles, Fresh and Fruity (FF), Rich and Ripe Unwooded (RRU), and Rich and Ripe Wooded (RRW), classically attributed with the help of sensory evaluation. One of the “rapid methods” has drawn our attention for the purpose of simplifying and making style attribution for large sample sets, evaluated during different sessions, more robust. Polarized Projective Mapping (PPM) is a hybrid of Projective Mapping (PM) and Polarised Sensory Positioning (PSP). It is a reference-based method in which poles
(references) are used for the evaluation of similarities and dissimilarities between samples.

Merging fast sensory profiling with non-targeted GC-MS analysis for multifactorial experimental wine making

Wine aroma is influenced by several viticultural and oenological factors. In this study we used experimental wine making in a full factorial design to determine the impact of grapevine age, must turbidity, and yeast strain on the aroma of Vitis vinifera L. cv. Riesling wines. A recently developed, non-targeted SPME-GC-MS fingerprinting approach for wine volatiles was used. This approach includes the segmentation and mathematical transformation of chromatograms in combination with Parallel Factor Analysis (PARAFAC) and subsequent deconvolution of important chromatogram segments.

To a better understanding of the impact of vine nitrogen status on volatile thiols from plot to transcriptome level

Volatile thiols contribute largely to the organoleptic characteristics and typicity of Sauvignon blanc wines. Among this family of odorous compounds, 3-sulfanylhexan-1-ol (3SH) and 4-methyl-4-sulfanylpentan-2-one (4MSP) have a major impact on wine flavor. These thiols are formed during alcoholic fermentation by the yeast from odorless and non-volatile precursors found in the berry and the must. The effect of vine nitrogen status on 3SH and 4MSP in Sauvignon blanc wine and on the glutathionylated and cysteinylated precursors of 3SH (Glut-3SH and Cys-3SH) was investigated in this study.

Impact of sulfur compounds to the antioxidant stability of white wines

The chemical mechanisms involved in oxidation/reduction potential of wine during winemaking and aging are affecting its color, aroma and taste. Chemical oxidation is one of the major causes of development of off-flavors during ageing1. Thus, the chemical changes in wine during storage should be controlled to ensure the sensory quality of the product and avoid consumer rejection that will compromise the economic value of the product. The 1-hydroxyethyl radical has been recognized as the key radical intermediate in the oxidative reactions in wine2. Based on the kinetic study of POBN-1-hydroxyethyl spin adduct formation in wines initiated via the Fenton reaction, a novel tool was recently developed in our laboratory to quantify the resistance of wines against oxidation3.