The taste of color: how grape anthocyanin fractions affect in-mouth perceptions

L’objectif de l’étude était de connaître le rôle du climat sur les aspects phénologiques du cépage « Moscato bianco » dans les différentes zones de production du vin Moscato d’Asti aocg en Piemonte (Italie) et ses effets sur l’époque de vendange. La représentation cartographique ( échelle 1 :25000) de exposition, altitude, climat, index

The inherent variability of Nature poses challenges for researchers to draw clear conclusions from field experiments. Identifying and assessing adaptations to climate change requires agronomic field trials.

Several classes of flavonoids, such as anthocyanins, flavonols, flavanols and flavones, undergo a slow H/D exchange on aromatic ring A, leading to full deuteration at positions C(6) and C(8). Within the flavanol class, H-C(6) and H-C(8) of catechin and epicatechin are slowly exchanged in D2O to the corresponding deuterated analogues; even quercetin, a relevant flavonol representative, shows the same behaviour in a D2O/DMSOd6 1:1 solution. Detailed kinetic measurements of these H/D scrambling processes are here reported by exploiting the time-dependent changes of their peak areas in the 1H-NMR spectra taken at different temperatures. A unifying reaction mechanism is also proposed based on our detailed kinetic observations, even taking into account pH and solvent effects. Molecular modelling and QM calculations were also carried out to shed more light on several molecular details of the proposed mechanism.

In the actual scenario of climate change, optimization of water usage is becoming critical in sustainable viticulture. Most of the current approaches to assess grapevine water status and drive irrigation scheduling are either destructive, time and labour consuming and monitor a small, limited number of plants. This work presents a novel methodology using a contactless, miniaturized, low-cost NIR spectrometer to monitor the vineyard water status variability from a moving vehicle, to provide reliable information towards precision irrigation.

l Veneto, come è noto, rappresenta una delle estensioni di superfici a vigneto più importanti in Italia e nell’Europa stessa. Il paesaggio viticolo fino ad oggi è stato ampiamente letto nelle sue componenti