Macrowine 2021
IVES 9 IVES Conference Series 9 Long-term sensorial and compositional effects of copper fining on the wine containing ‘reductive’ and ‘tropical’ volatile sulfur compounds

Long-term sensorial and compositional effects of copper fining on the wine containing ‘reductive’ and ‘tropical’ volatile sulfur compounds

Abstract

The aim of this study was to investigate long-term sensorial and compositional effects of copper addition to the white wine naturally high in varietal thiol levels, with added volatile sulfur compounds [hydrogen sulfide (H2S) and methanethiol (MeSH)]. The novelty of this study lies in the inclusion of sensory analysis at each time point by using Check-All-That-Apply and Descriptive Analysis methods to evaluate the sensory interaction between ‘reductive’ thiols and tropical thiols after copper fining. The Chenin Blanc wine was used as control (base) wine to which combinations of 40 µg/L H2S and 20 µg/L of MeSH were added, followed by an addition of 0,3 mg/L of copper to selected samples. The wine samples were stored for 24 hours, 6 weeks and 1 year. At each time point chemical analysis of varietal thiols, volatile sulfur compounds and copper levels were performed. The chemical results after 1 year of wine storage, showed a significant increase in the levels of varietal thiol 3-sulfanylhexanol (3-SH) and a decrease of 3-sulfanylhexyl acetate (3-SHA) concentration levels. However, a significant loss of 3-SH occurred in all the copper treated wines after 1 year of storage. On the other hand, the decrease of 3-SHA levels over time was less influenced by copper treatment, but rather due to acid hydrolyses and a subsequent increase in 3-SH (Makhotkina & Kilmartin, 2012). The presence of copper seem to further increase levels of bound- H2S in wine samples, which after 1 year of storage amounted to more than 25 µg/L. Chemical analysis of MeSH showed the significant increase in free and bound MeSH after 1 year of storage in wine samples spiked with MeSH. However, the addition of copper to the MeSH-spiked samples resulted in significant decrease of free and bound MeSH. The most significant sensory impact of the addition of H2S and MeSH to control wine was the suppression effect on “fruitiness” of wine after 24 hours which after 6-weeks and 1-year wine storage period decreased, potentially due to wine matrix absorption of H2S and MeSH (Nikolantonaki & Waterhouse, 2012). Sensory results after 1 year of wine storage showed that “guava”, a “tropical” attribute, was not suppressed with the addition of H2S and MeSH and low doses of “reductive” aromas deriving from H2S and MeSH in wine might even contributed to its sensory perception. Copper additions mainly decreased the perception of “guava” after 1 year. In contrast, the “passionfruit”, also a “tropical” attribute, was slightly suppressed when H2S and MeSH were present. The perception of the ester-derived attributes namely “peach” and “banana” increased in the samples containing copper after 1 year of storage, suggesting that a decrease of the 3-SH varietal thiol due to copper addition may enhance the perception of ester-derived aromas in wine.

DOI:

Publication date: September 14, 2021

Issue: Macrowine 2021

Type: Article

Authors

Matija Lesković

*South African Grape and Wine Research Institute/Department Viticulture and Oenology, University of Stellenbosch, Private Bag X1, Matieland (Stellenbosch) 7602, South Africa,Marlize BEKKER † Jeanne BRAND * Allie KULCSAR † Wessel DU TOIT * *South African Grape and Wine Research Institute/Department Viticulture and Oenology, University of Stellenbosch, Private Bag X1, Matieland (Stellenbosch) 7602, South Africa † The Australian Wine Research Institute, P.O. Box 197, Glen Osmond, South Australia, 5064.

Contact the author

Keywords

varietal thiols, volatile sulfur compounds, wine copper fining, ‘reductive’ and ‘tropical’ volatile sulfur compounds, copper fining and wine storage, wine sensory analysis

Citation

Related articles…

Climate change projections to support the transition to climate-smart viticulture

The Earth’s system is undergoing major changes through a wide range of spatial and temporal scales as a response to growing anthropogenic radiative forcing, which is pushing the whole system far beyond its natural variability. Sources of greenhouse gases largely exceed their sinks, thus leading to a strengthened greenhouse effect. More energy is thereby being supplied to the system, with inevitable shifts in climatic patterns and weather regimes. Over the last decades, these modifications have been manifested in the full statistical distributions of the atmospheric variables, with dramatic changes in the frequency and intensity of extremes. Natural hazards, such as severe droughts, floods, forest fires, or heatwaves, are being triggered by extreme atmospheric events worldwide, thus threatening human activities. Viticultculture is not only exposed to changing climates but is also highly vulnerable, as grapevine phenology and physiological development are strongly controlled by atmospheric conditions. Therefore, the assessment of climate change projections for a given region is critical for climate change adaptation and risk reduction in viticulture. By adopting timely and suitable measures, the future sustainability and resiliency of the sector can be fostered. Climate-grapevine chain modelling is an essential tool for better planning and management. However, the accuracy of the resulting projections is limited by many uncertainties that must be duly taken into account when transferring knowledge to stakeholders and decision-makers. Climate-smart viticulture will comprise ensembles of locally tuned strategies, envisioning both adaptation and mitigation, assisted by emerging technologies and decision-support systems.

Under-vine management effects on grapevine production, soil properties and plant communities in South Australia

Under-vine (UV) management has traditionally consisted of synthetic herbicide use to limit competition between weeds and grapevines. With growing global interest towards non-synthetic chemical use, this study aimed to capture the effects of alternative UV management at two commercial Shiraz vineyards in South Australia, where the sole management variables were UV management since 2016. In adjacent treatment blocks, cultivation (CU) was compared to spontaneous vegetation (SV) in McLaren Vale (MV), and herbicide was compared to SV in Eden Valley (EV). Soil water infiltration rates were slower and grapevine stem water potential was lower in CU compared to SV in MV, with the latter having a plant community dominated by soursob (Oxalis pes-caprae) during winter; while in EV, there was little separation between the treatments. Yields were affected at both sites, with SV being higher in MV and HE being higher in EV. In MV, the only effect on grape must was a lower 13C:12C isotope ratio in CU, indicating greater grapevine water stress. In the grape must at EV, SV had higher total soluble solids, total phenolics, anthocyanins, and yeast available nitrogen; and lower pH and titratable acidity. Pruning weights were not affected by the treatments in MV, while they were higher in HE at EV. Assessments revealed that the differing soil types at the two sites were likely the main determinants of the opposing production outcomes associated with UV management. In the silty loam soil of MV, the higher yields in SV were likely due to more plant-available water, as a potential result of the continuous soil bio-pores formed by winter UV vegetation. Conversely, in the loamy sand soils of EV with a lower cation exchange capacity, the lower yields and pruning weights in SV suggest the UV vegetation competed significantly with the grapevines for available water and nutrients.

Extreme canopy management for vineyard adaptation to climate change: is it a good idea?

Climate change constitutes an enormous challenge for humankind and for all human activities, viticulture not being an exception. Long-term strategic changes are probably needed the most, but growers also need to deal with short-term changes: summers that are getting progressively warmer, earlier harvest dates and higher pH in musts and wines. In the last 10-15 years, a relevant corpus of research is being developed worldwide in order to evaluate to which extent extreme canopy management operations, aimed at reducing leaf area and, thus, limiting the source to sink ratio, could be useful to delay ripening. Although extreme canopy management can result in relevant delays in harvest dates, longer term studies, as well as detailed analysis of their implications on carbohydrate reserves, bud fertility and future yield are desirable before these practices can be recommended.

How distinctive are single vineyard Gewürztraminer musts and wines from Alto Adige (Italy) based on untargeted analysis, sensory profiling, and chemometric elaboration?

Vitis vinifera L. ‘Gewürztraminer’ is a historical grape variety of Alto Adige (Südtirol), Italy, which is widely grown in the area of Tramin an der Weinstraße, but is also grown globally. It produces highly aromatic wines that are strongly influenced by the terroir of the vineyard sites where they are grown. This study looked at musts and young wines from ‘Gewürztraminer’ grapes harvested in seven distinct vineyards near Tramin and then processed at Cantina di Termeno, minimizing winemaking protocol variability. Samples were profiled using bidimensional gas chromatography–time-of-flight mass spectrometry, liquid chromatography coupled to electrochemical detection, and near-IR spectrometry. The data were subjected to Principle Component Analysis and Hierarchical Clustering Analysis. Sensory discriminant testing was undertaken using the sorting method with a semi-trained panel, and the data were processed using Multidimensional Scaling. Seven must/wine pairs could be distinguished based on their untargeted volatilome profiles and on sensory evaluation. As expected, there were greater differences in the volatile compounds between the wines than between the musts. The wines from vineyards 4 and 5 were nonetheless quite homogenous in terms of chemical and sensory analyses, as were the wines from vineyards 1 and 3. For the phenolic profile, differences were noted between the musts and wines of vineyards 2, 3, and 4, but the musts from vineyards 5 and 7 were similar. Sensory analysis showed the wines from vineyards 6 and 7 to be distinct from the rest. These results reinforce that the composition of ‘Gewürztraminer’ musts and wines is strongly determined by vineyard site, even in a small geographic area with high variability of the terroir (soil and microclimate), and that these differences are apparent in the flavours and aromas of the finished wines. Further confirmation would require a larger sample of wines, preferably from several vintages.

Grapevine yield estimation in a context of climate change: the GraY model

Grapevine yield is a key indicator to assess the impacts of climate change and the relevance of adaptation strategies in a vineyard landscape. At this scale, a yield model should use a number of parameters and input data in relation to the information available and be able to reproduce vineyard management decisions (e.g. soil and canopy management, irrigation). In this study, we used data from six experimental sites in Southern France (cv. Syrah) to calibrate a model of grapevine yield limited by water constraint (GraY). Each yield component (bud fertility, number of berries per bunch, berry weight) was calculated as a function of the soil water availability simulated by the WaLIS water balance model at critical phenological phases. The model was then evaluated in 10 grapegrowers’ plots, covering a diversity of biophysical and technical contexts (soil type, canopy size, irrigation, cover crop). We identified three critical periods for yield formation: after flowering on the previous year for the number of bunches and berries, around pre-veraison and post-veraison of the same year for mean berry weight. Yields were simulated with a model efficiency (EF) of 0.62 (NRMSE = 0.28). Bud fertility and number of berries per bunch were more accurately simulated (EF = 0.90 and 0.77, NRMSE = 0.06 and 0.10, respectively) than berry weight (EF = -0.31, NRMSE = 0.17). Model efficiency on the on-farm plots reached 0.71 (NRMSE = 0.37) simulating yields from 1 to 8 kg/plant. The GraY model is an original model estimating grapevine yield evolution on the basis of water availability under future climatic conditions.  It allows to evaluate the effects of various adaptation levers such as planting density, cover crop management, fruit/leaf ratio, shading and irrigation, in various production contexts.