Macrowine 2021
IVES 9 IVES Conference Series 9 Long-term sensorial and compositional effects of copper fining on the wine containing ‘reductive’ and ‘tropical’ volatile sulfur compounds

Long-term sensorial and compositional effects of copper fining on the wine containing ‘reductive’ and ‘tropical’ volatile sulfur compounds

Abstract

The aim of this study was to investigate long-term sensorial and compositional effects of copper addition to the white wine naturally high in varietal thiol levels, with added volatile sulfur compounds [hydrogen sulfide (H2S) and methanethiol (MeSH)]. The novelty of this study lies in the inclusion of sensory analysis at each time point by using Check-All-That-Apply and Descriptive Analysis methods to evaluate the sensory interaction between ‘reductive’ thiols and tropical thiols after copper fining. The Chenin Blanc wine was used as control (base) wine to which combinations of 40 µg/L H2S and 20 µg/L of MeSH were added, followed by an addition of 0,3 mg/L of copper to selected samples. The wine samples were stored for 24 hours, 6 weeks and 1 year. At each time point chemical analysis of varietal thiols, volatile sulfur compounds and copper levels were performed. The chemical results after 1 year of wine storage, showed a significant increase in the levels of varietal thiol 3-sulfanylhexanol (3-SH) and a decrease of 3-sulfanylhexyl acetate (3-SHA) concentration levels. However, a significant loss of 3-SH occurred in all the copper treated wines after 1 year of storage. On the other hand, the decrease of 3-SHA levels over time was less influenced by copper treatment, but rather due to acid hydrolyses and a subsequent increase in 3-SH (Makhotkina & Kilmartin, 2012). The presence of copper seem to further increase levels of bound- H2S in wine samples, which after 1 year of storage amounted to more than 25 µg/L. Chemical analysis of MeSH showed the significant increase in free and bound MeSH after 1 year of storage in wine samples spiked with MeSH. However, the addition of copper to the MeSH-spiked samples resulted in significant decrease of free and bound MeSH. The most significant sensory impact of the addition of H2S and MeSH to control wine was the suppression effect on “fruitiness” of wine after 24 hours which after 6-weeks and 1-year wine storage period decreased, potentially due to wine matrix absorption of H2S and MeSH (Nikolantonaki & Waterhouse, 2012). Sensory results after 1 year of wine storage showed that “guava”, a “tropical” attribute, was not suppressed with the addition of H2S and MeSH and low doses of “reductive” aromas deriving from H2S and MeSH in wine might even contributed to its sensory perception. Copper additions mainly decreased the perception of “guava” after 1 year. In contrast, the “passionfruit”, also a “tropical” attribute, was slightly suppressed when H2S and MeSH were present. The perception of the ester-derived attributes namely “peach” and “banana” increased in the samples containing copper after 1 year of storage, suggesting that a decrease of the 3-SH varietal thiol due to copper addition may enhance the perception of ester-derived aromas in wine.

DOI:

Publication date: September 14, 2021

Issue: Macrowine 2021

Type: Article

Authors

Matija Lesković

*South African Grape and Wine Research Institute/Department Viticulture and Oenology, University of Stellenbosch, Private Bag X1, Matieland (Stellenbosch) 7602, South Africa,Marlize BEKKER † Jeanne BRAND * Allie KULCSAR † Wessel DU TOIT * *South African Grape and Wine Research Institute/Department Viticulture and Oenology, University of Stellenbosch, Private Bag X1, Matieland (Stellenbosch) 7602, South Africa † The Australian Wine Research Institute, P.O. Box 197, Glen Osmond, South Australia, 5064.

Contact the author

Keywords

varietal thiols, volatile sulfur compounds, wine copper fining, ‘reductive’ and ‘tropical’ volatile sulfur compounds, copper fining and wine storage, wine sensory analysis

Citation

Related articles…

Different soil types and relief influence the quality of Merlot grapes in a relatively small area in the Vipava Valley (Slovenia) in relation to the vine water status

Besides location and microclimatic conditions, soil plays an important role in the quality of grapes and wine. Soil properties influence…

Geospatial trends of bioclimatic indexes in the topographically complex region of Barolo DOCG

Barolo DOCG is an economically important wine producing region in Northwest Italy. It is a small region of approximately 70 km2 gross area. The topography is very complex with steep sloped hills ranging in elevation from below 200 m to 550 m. Barolo DOCG wine is made exclusively from the Nebbiolo grape. Bioclimatic indexes are often used in viticulture to gain a better understanding of broader climate trends which can be compared temporally and geographically. These indexes are also used for identifying potential phenological timing, growing region suitability, and potential risks associated with expected climatic changes. Understanding how topography influences bioclimatic indexes can help with understanding of mesoscale climate behaviour leading to improved decision making and risk management strategies. The average monthly maximum and minimum temperatures, the Cool Night Index, the Huglin Index, and the monthly diurnal range (from July to October) were calculated using data from 45 weather stations within a 40 km radius of the Barolo DOCG growing area between the years 1996 and 2019. Linear and multiple regression models were developed using independent variables (elevation, aspect, slope) extracted from a digital elevation model to identify significant relationships. Bioclimatic indexes were then kriged with external drift using independent variables that showed significant relationships with the bioclimatic index using a 100 m resolution grid. The maximum monthly temperatures and the Huglin Index showed consistent significant negative relationships with elevation in all years. The minimum monthly temperatures showed no relationship with elevation but in some months a small but significant relationship was observed with aspect. Due to the lack of a relationship between minimum monthly temperatures and elevation compared to the significant relationship between maximum monthly temperatures and elevation, monthly diurnal range had a negative relationship with elevation.

Late frost protection in Champagne

Probably one of the most counterintuitive impacts of climate change on vine is the increased frequency of late frost. Champagne, due to its septentrional position is historically and regularly affected by this meteorological hazard. Champagne has therefore developed a strong experience in frost protection with first experiments dating from the end of 19th century. Frost protection can be divided in two parts: passive and active. Passive protection includes all the methods that do not seek to modify the vine’s environment or resistance at the time of frost. The most iconic passive protection in Champagne is the establishment of the individual reserve. This reserve allows to stock a certain quantity of clear wine during a surplus year to compensate a meteorological hazard like frost during the following years. Other common passive methods are the control of planting area (walls, bushes, topography), the choice of grape variety, late pruning, or the impact of grass cover and tillage. Active frost protection is also divided in two parts. Most of the existing techniques tend to modify vine’s environment. Most of the time they provide warmth (candles, heaters, windmills, heating cables…), or stabilise bud’s temperature above a lethal threshold (water sprinkling). The other way to actively fight is to enhance the resistance of buds to frost (elicitors). The Comité Champagne evaluates frost protection methods following three main axes: the efficiency, the profitability, and the environmental impact through a lifecycle assessment. This study will present the results on both passive and active protection following these three axes.

Modeling island and coastal vineyards potential in the context of climate change

Climate change impacts regional and local climates, which in turn affects the world’s wine regions. In the short term, these modifications rises issues about maintaining quality and style of wine, and in a longer term about the suitability of grape varieties and the sustainability of traditional wine regions. Thus, adaptation to climate change represents a major challenge for viticulture. In this context, island and coastal vineyards could become coveted areas due to their specific climatic conditions. In regions subject to warming, the proximity of the sea can moderate extremes temperatures, which could be an advantage for wine. However, coastal and island areas are particular prized spaces and subject to multiple pressures that make the establishment or extension of viticulture complex.
In this perspective, it seems relevant to assess the potentialities of coastal and island areas for viticulture. This contribution will present a spatial optimization model that tends to characterize most suitable agroclimatic patterns in historical or emerging vineyards according to different scenarios. Thanks to an in-depth bibliography a global inventory of coastal and insular vineyards on a worldwide scale has been realized. Relevant criteria have been identified to describe the specificities of these vineyards. They are used as input data in the optimization process, which will optimize some objectives and spatial aspects. According to a predefined scenario, the objectives are set in three main categories associated with climatic characteristics, vineyards characteristics and management strategies. At the end of this optimization process, a series of maps presents the different spatial configurations that maximize the scenario objectives.

Evaluation of climate change impacts at the Portuguese Dão terroir over the last decades: observed effects on bioclimatic indices and grapevine phenology

In the last decades the growers of the Portuguese Dão winegrowing region (center of Portugal) are experiencing changes in climate that are influencing either grape phenology berry health and ripening. Aiming to study the relationships between climate indices (CI), seasonal weather and grapevine phenology, in this work long-term climate and phenological data collected at the experimental vineyard of the Portuguese Dão research centre between 1958 and 2019 (61 years) for the red variety Touriga Nacional, was analyzed. The trends over time for the classical temperature-based indices (Growing Season Temperature – GST -, Growing Degree Days – GDD, Huglin Index – HI and Cool Night Index – CI) presented a significantly positive slope while the Dryness Index (DI) showed a negative trend over the last 61 years. Regarding grapevine phenology, an average advance of 4.5 days per decade in the harvest day was observed throughout the last 61 years. Consequently, the weather conditions during the ripening period have changed, showing an increasing trend over time in the average temperature (higher magnitude in the maximum than in the minimum temperature) and a decrease in the accumulated rainfall. A regression analysis showed that ~50% of harvest date variability over years was explained by the temperature-based indices variability. These observed effects of climate change on bioclimatic indices and corresponding anticipation of harvest date can still be considered advantageous for the Dão terroir as it allows to achieve an optimal berry ripening before the common equinox rains and, therefore, avoid the potential negative impacts of the rainfall on berry health and composition.