Macrowine 2021
IVES 9 IVES Conference Series 9 LC-MS based metabolomics discriminates premium from varietal chilean Cabernet Sauvignon cv. Wines

LC-MS based metabolomics discriminates premium from varietal chilean Cabernet Sauvignon cv. Wines

Abstract

Aim of the study was to investigate the metabolomic differences between Chilean Cabernet Sauvignon wines, divided according to their quality in two main groups: “Varietal” and “Premium”, and to point out metabolites tentative markers of their chemical signature and sensorial quality. Initially, 150 (50 x 3 biological replicates) experimental wines were produced by the same semi-industrial process, which covered 8 different Chilean valleys. The wine classification made by experts, divided the wines into two major groups (“Varietal” and “Premium”) and four subgroups (two for each major group). All the samples were analyzed according to a robust LC-MS based untargeted work-flow (Arapitsas et al 2018), and the proposed minimum reporting standards for chemical analysis of the Metabolomics Standards Initiative (Sumner et al 2007). The produced big-dataset was based on 7633 features for ESI- mode analysis and 9258 for ESI+ mode. After the quality control of the data, were found 150 tentative markers. The annotation of the markers was achieved by using the internal library, external databases and literature information. Between the Chilean Cabernet Sauvignon quality tentative markers were annotated N-compounds (e.g. peptides), stilbenoids, flavanols, anthocyanins and sulfonated compounds. In conclusion, this study allowed us to find metabolomic pathways and chemical reactions, and therefore propose new hypothesis, which could open new frontiers for the understanding of the Chilean Cabernet Sauvignon quality and terroir effect and provide new tools for the enology of precision in Chile.

DOI:

Publication date: September 24, 2021

Issue: Macrowine 2021

Type: Article

Authors

Vania Sáez,  Álvaro González, Panagiotis Arapitsas. 

Fondazione Edmund Mach.,Doreen Schober. Center for Research, and Innovation, Chile.  Fondazione Edmund Mach, Italy.

Contact the author

Keywords

cabernet sauvignon; quality; metabolomics; stilbenoids; anthocyanins; peptides; terroir

Citation

Related articles…

Aroma typicity of Timorasso wines: influence of ageing on volatile organic compounds and sensory descriptors

‘Timorasso’ is an autochthonous white grape variety from southern Piedmont (Italy) used for producing wines in the Colli Tortonesi product designation of origin (PDO). Over the last decade, there has been a notable rise in its production, due to the increased interest of wine enthusiasts who prized its wine distinctive ageing notes [1].

Terroir characterization from cv. Merlot and Sauvignon plots follow-up within the scope of wine-production : “Vins de Pays Charentais” in the Cognac eaux-de-vie vineyard area

Dans les études des terroirs, il est souvent délicat d’établir des zonages et de mesurer les effets de l’environnement sur les vins. Avec plus d’un million d’hectares dans l’aire d’appellation délimitée, le terroir du célèbre vignoble de Cognac est bien connu pour ces eaux-de-vie et ainsi divisé en 6 crus.

Within vineyard temperature structure and variability in the umpqua valley of Oregon

Climate influences viticulture and wine production at various scales with the majority of attention given to regional characteristics that define the general varieties that can be grown and the wine styles that can be produced.

Novel analytical technologies for wine fingerprinting in and beyond the laboratory

For characterization, sensory designing and authentication rapid analytical technologies have become available. Some, like Proton Transfer Reaction Mass Spectrometry allow a rapid spectrum of the volatile compounds of wines. Combined with chemometrics wines can be characterized. The same approach can be used to calculate the results of virtual mixtures and allow formulation of constant quality blends. Other new techniques and portable devices based on spectroscopy allow measurements on production sites and in grocery stores, even for the smart consumer. We will present some examples of the application of these techniques for authentication of wines, both in the laboratory and on site.

From vineyard to a glass of wine: the effect of abscisic acid application on mouhtaro, a rare autochthonous variety of greece

In a context of a sustainable viticulture, a new uprising strategy to improve grape and wine composition (or quality) is the exogenous application of plant activators(Gil-Muñoz et al., 2017)