Impact of water stress on the phenolic composition of cv. Merlot grapes, in a typical terroir of the La Mancha region (Spain)

Wine is a complex matrix whose composition depends on climatic, agricultural, and winemaking factors, making quality control and authenticity assessment critical in the global market.

The French “Coteaux du Layon” Appellation of Origin has built its Jarne on the production of sweet white wines. A network of experimental plots, based on the “terroir” concept, was established in 1990; it allows for the follow-up of the overripening behaviour of the grapes in relation with the agroviticultural parameters.

The assessment of wine authenticity is of great importance for consumers, producers and regulatory agencies to guarantee the geographical origin of wines and grape variety as well. Since mid-infrared (MIR) spectroscopy with chemometrics represent a suitable tool to ascertain the wine composition, including features associated with the polyphenolic compounds, the aim of this study was to generate MIR spectra of red wines to be exploited for classification of red wines based on the relationship between grape variety and wine composition. Several multivariate data analyses were used, including Principal Component Analysis (PCA), Discriminant Analysis (DA), Support Vector Machine (SVM), and Soft Intelligent Modelling of Class Analogy (SIMCA).

Galloylated flavan-3-ols are a class of polyphenolic compounds present in various plants, including grape seeds. These compounds are formed through the condensation of flavan-3-ols, such as catechins, although the precise mechanism by which gallic acid is incorporated into the molecule remains unclear.

Noble rot sweet wines are reputed wines, traditionally elaborated according to a singular vinification process involving the harvesting of overripe grapes under the action of the ascomycete fungus Botrytis cinerea.