IVAS 2022 banner
IVES 9 IVES Conference Series 9 IVAS 9 IVAS 2022 9 Impact of dosage sugar-type and ageing on finished sparkling wine composition and development of Maillard reaction-associated compounds

Impact of dosage sugar-type and ageing on finished sparkling wine composition and development of Maillard reaction-associated compounds

Abstract

The Maillard reaction (MR) is a non-enzymatic reaction between reducing sugars and amino acids, resulting in the production of volatile and flavour-active compounds. Existing MR research primarily addresses thermally processed foods, whereas limited studies have evaluated low-temperature MR environments including sparkling wine. Sparkling wine is produced in low temperature conditions (15 ± 3°C), with low pH (pH 3-3.4) and high acidity (titratable acidity 7-12 g/L) 1. Various MR species including furans, acryl amides, and heterocyclic amines have been identified in aged sparkling wines and contribute to roasted, caramel, and nutty aromas 2–4. The aim of this research was to investigate the composition of finished sparkling wine during 18-months of ageing by measuring the formation of target MR-associated compounds and the relative levels of precursor species (amino acids, reducing sugars). Variable liqueur de dosage sugar-types were assessed for their impact on MR-associated compounds during ageing. Liqueur de dosage (composed of sugar, wine, and SO2) is an addition made post-disgorgement, and these sugars may degrade or interact with amino acids, thereby influencing the formation of MR compounds. To the best of our knowledge, no prior literature has investigated the role of Liqueur de dosage in the MR. In this research, six dosage sugar treatments were evaluated including D-glucose, D-fructose, sucrose (cane-derived), sucrose (beet-derived), maltose, and commercial rectified grape must concentrate (RCGM), in addition to a zero-dosage/control (no sugar added). Treatments were carried out on 2015 vintage sparkling wine (3 years on lees; 59% Chardonnay, 41% Pinot Noir) produced by Niagara College Teaching Winery in Niagara-on-the-Lake, ON. Dosage treatments were prepared from the sparkling wine base to approximately 6 g/L residual sugar. Bottles were sealed with cork closures and cellared on-site at the Cool Climate Oenology & Viticulture Institute with environmental controls for temperature and humidity. At intervals of 0, 9 and 18-months post-dosage addition, triplicate bottles of each wine were chemically analyzed. MR-associated products were quantified by HS-SPME-GC-MS. Precursors including sugars and amino acids were quantified by enzymatic assay and NMR techniques, respectively, and sugar purity was determined by HPLC. After 18 months of aging post-disgorging, four MRPs showed concentration differences (p < 0.05) between dosage sugar treatments (ethyl 3-mercaptopropionate, furfuryl ethyl ether, 2-ethylthiazole, and 2-furyl methyl ketone). Changes in sugar and amino acid content during ageing were used to relate changes in MR compound formation with precursor consumption. This study establishes the effect of dosage sugar-type on the formation of volatile MR compounds in traditional method sparkling wines during ageing.

References

1. Kemp, B.; Alexandre, H.; Robillard, B.; Marchal, R. J. Agric. Food Chem. 2015, 63 (1), 19–38. 
2. Le Menn, N.; Marchand, S.; De Revel, G.; Demarville, D.; Laborde, D.; Marchal, R. J. Agric. Food Chem. 2017, 65 (11), 2345–2356. 
3. Keim, H.; De Revel, G.; Marchand, S.; Bertrand, A. J. Agric. Food Chem. 2002, 50 (21), 5803–5807. 
4. Marchand, S.; Almy, J.; de Revel, G. J. Food Sci. 2011, 76 (6), 861-868.

DOI:

Publication date: June 23, 2022

Issue: IVAS 2022

Type: Article

Authors

Charnock Hannah1, Pickering Gary J.1,2,3,4, Kemp Belinda S.1,2

1Department of Biological Sciences, Faculty of Mathematics & Science, Brock University, 1812 Sir Isaac Brock Way, St. Catharines, ON, Canada, L2S 3A1
2Cool Climate Oenology & Viticulture Institute, Brock University, 1812 Sir Isaac Brock Way, St. Catharines, ON, Canada, L2S 3A1
3National Wine and Grape Industry Center, Charles Sturt University, McKeown Drive, Wagga Wagga, NSW 2678, Australia
4Sustainability Research Centre, University of the Sunshine Coast, 90 Sippy Downs Drive, Sippy Downs, QLD 4556, Australia

Contact the author

Keywords

sparkling wine, Maillard reaction, time-course ageing

Tags

IVAS 2022 | IVES Conference Series

Citation

Related articles…

How distinctive are single vineyard Gewürztraminer musts and wines from Alto Adige (Italy) based on untargeted analysis, sensory profiling, and chemometric elaboration?

Vitis vinifera L. ‘Gewürztraminer’ is a historical grape variety of Alto Adige (Südtirol), Italy, which is widely grown in the area of Tramin an der Weinstraße, but is also grown globally. It produces highly aromatic wines that are strongly influenced by the terroir of the vineyard sites where they are grown. This study looked at musts and young wines from ‘Gewürztraminer’ grapes harvested in seven distinct vineyards near Tramin and then processed at Cantina di Termeno, minimizing winemaking protocol variability. Samples were profiled using bidimensional gas chromatography–time-of-flight mass spectrometry, liquid chromatography coupled to electrochemical detection, and near-IR spectrometry. The data were subjected to Principle Component Analysis and Hierarchical Clustering Analysis. Sensory discriminant testing was undertaken using the sorting method with a semi-trained panel, and the data were processed using Multidimensional Scaling. Seven must/wine pairs could be distinguished based on their untargeted volatilome profiles and on sensory evaluation. As expected, there were greater differences in the volatile compounds between the wines than between the musts. The wines from vineyards 4 and 5 were nonetheless quite homogenous in terms of chemical and sensory analyses, as were the wines from vineyards 1 and 3. For the phenolic profile, differences were noted between the musts and wines of vineyards 2, 3, and 4, but the musts from vineyards 5 and 7 were similar. Sensory analysis showed the wines from vineyards 6 and 7 to be distinct from the rest. These results reinforce that the composition of ‘Gewürztraminer’ musts and wines is strongly determined by vineyard site, even in a small geographic area with high variability of the terroir (soil and microclimate), and that these differences are apparent in the flavours and aromas of the finished wines. Further confirmation would require a larger sample of wines, preferably from several vintages.

Towards adaptation to climate change in Rioja: Quality evaluation of wines obtained from Grenache x Tempranillo selections

The wine sector is of great relevance and tradition in Mediterranean countries, however, it may be most susceptible to climate change. In recent years, wine production is facing changes worldwide, both at environmental as well as commercial levels, due to global warming and the shift in consumers’ preferences. Wine growers and wine makers are in search of solutions that allow to face these new challenges. One of the most promising initiatives in the long term is the introduction of new plant materials, specifically intraspecific hybridizations between premium varieties that may improve traditional germplasm in its adaptation to climate change. These inter-varietal crosses have the potential to generate quality wines, whilst maintaining the regional typicity, and constitute an attractive alternative for the consumer due to their sensory attributes. In this study, we have evaluated wines from 29 intraspecific Garnacha x Tempranillo hybrids in two different locations, with the aim to assess their oenological potential and sensory attributes. Thirteen of the selections were white and 16 were red. Microvinifications were conducted with two or three replications depending on grape availability. Conventional oenological parameters were determined for all wines. The sensory evaluation and hedonic scores were given by five experts. Red selections obtained higher quality scores than white ones. Among the white selections with higher quality scores, GT-41 Varea and GT-159 Varea outstand, due to their high total acidity and high malic acid content. Regarding red selections, GT-57 Varea and GT-57 UR were perceived as higher in quality, highlighted for their moderate alcoholic and high anthocyanin content. Our results indicate that intraspecific hybridization may be a powerful tool for adapting traditional cultivars to climate change in Rioja.

Geospatial trends of bioclimatic indexes in the topographically complex region of Barolo DOCG

Barolo DOCG is an economically important wine producing region in Northwest Italy. It is a small region of approximately 70 km2 gross area. The topography is very complex with steep sloped hills ranging in elevation from below 200 m to 550 m. Barolo DOCG wine is made exclusively from the Nebbiolo grape. Bioclimatic indexes are often used in viticulture to gain a better understanding of broader climate trends which can be compared temporally and geographically. These indexes are also used for identifying potential phenological timing, growing region suitability, and potential risks associated with expected climatic changes. Understanding how topography influences bioclimatic indexes can help with understanding of mesoscale climate behaviour leading to improved decision making and risk management strategies. The average monthly maximum and minimum temperatures, the Cool Night Index, the Huglin Index, and the monthly diurnal range (from July to October) were calculated using data from 45 weather stations within a 40 km radius of the Barolo DOCG growing area between the years 1996 and 2019. Linear and multiple regression models were developed using independent variables (elevation, aspect, slope) extracted from a digital elevation model to identify significant relationships. Bioclimatic indexes were then kriged with external drift using independent variables that showed significant relationships with the bioclimatic index using a 100 m resolution grid. The maximum monthly temperatures and the Huglin Index showed consistent significant negative relationships with elevation in all years. The minimum monthly temperatures showed no relationship with elevation but in some months a small but significant relationship was observed with aspect. Due to the lack of a relationship between minimum monthly temperatures and elevation compared to the significant relationship between maximum monthly temperatures and elevation, monthly diurnal range had a negative relationship with elevation.

Impact of climate variability and change on grape yield in Italy

Viticulture is entangled with weather and climate. Therefore, areas currently suitable for grape production can be challenged by climate change. Winegrowers in Italy already experiences the effect of climate change, especially in the form of warmer growing season, more frequent drought periods, and increased frequency of weather extremes.
The aim of this study is to investigate the impact of climate variability and change on grape yield in Italy to provide winegrowers the information needed to make their business more sustainable and resilient to climate change. We computed a specific range of bioclimatic indices, selected by the International Organisation of Vine and Wine (OIV), and correlated them to grape yield data. We have worked in collaboration with some wine consortiums in northern and central Italy, which provided grape yield data for our analysis.
Using climate variables from the E-OBS dataset we investigate how the bioclimatic indices changed in the past, and the impact of this change on grape productivity in the study areas. The climate impact on productivity is also investigated by using high-resolution convection-permitting models (CPMs – 2.2 horizontal resolution), with the purpose of estimating productivity in future emission scenarios. The CPMs are likely the best available option for this kind of impact studies since they allow a better representation of small-scale processes and features, explicitly resolve deep convection, and show an improved representation of extremes. In our study, we also compare CPMs with regional climate models (RCMs – 12 km horizontal resolution) to assess the added value of high-resolution models for impact studies. Further development of our study will lead to assessing the future suitability for vine cultivation and could lead to the construction of a statistical model for future projection of grape yield.

Organic recycled mulches in sustainable viticulture: assessment of spontaneous plants communities and weed coverage

In recent years, developing more efficient and sustainable viticulture management has been essential due to the impact of climate change in semiarid regions. For this reason, the use of recycled organic mulching (ROM) in the vineyard has become an interesting strategy to cope with water stress, isolated soil from extreme temperatures and improving soil humidity, control the presence of weeds and therefore reduce the inputs of herbicides and improve soil fertility. This work aimed to analyse the effect of three different organic mulches [straw (S), grape pruning debris (GPD) and spent mushroom compost (SMC)] and two traditional soil management techniques [herbicide (H) and interrow (IN)] on weed coverage and the spontaneous plant communities’ presence. Data sampling was collected throughout the vine vegetative cycle of 2021 in La Rioja, Spain. The different soil management techniques had a clear effect on weed coverage and his development during the vine vegetative cycle. SMC and H were the treatments with the highest and the lowest coverage percentage, respectively. IN had a delayed weed emergence at the beginning of the vine vegetative cycle, but finally it reached maximum values nearby SMC. GPD and S had similar effects on weed emergence, reaching 25-30% of the maximum coverage values. A total of 29 herbaceous species were identified during the vegetative cycle, some of them very isolated and occasional. Principal component analysis (PCAs) showed a good association between spontaneous species and treatments, furthermore, specific species-treatment associations were found. Moreover, three clear groups of herbaceous communities were identified by cluster analysis. This study provides interesting information about the effect of different alternative soil management on herbaceous plant coverage and weed species communities which could contribute to making more sustainable viticulture.