IVAS 2022 banner
IVES 9 IVES Conference Series 9 IVAS 9 IVAS 2022 9 Impact of dosage sugar-type and ageing on finished sparkling wine composition and development of Maillard reaction-associated compounds

Impact of dosage sugar-type and ageing on finished sparkling wine composition and development of Maillard reaction-associated compounds

Abstract

The Maillard reaction (MR) is a non-enzymatic reaction between reducing sugars and amino acids, resulting in the production of volatile and flavour-active compounds. Existing MR research primarily addresses thermally processed foods, whereas limited studies have evaluated low-temperature MR environments including sparkling wine. Sparkling wine is produced in low temperature conditions (15 ± 3°C), with low pH (pH 3-3.4) and high acidity (titratable acidity 7-12 g/L) 1. Various MR species including furans, acryl amides, and heterocyclic amines have been identified in aged sparkling wines and contribute to roasted, caramel, and nutty aromas 2–4. The aim of this research was to investigate the composition of finished sparkling wine during 18-months of ageing by measuring the formation of target MR-associated compounds and the relative levels of precursor species (amino acids, reducing sugars). Variable liqueur de dosage sugar-types were assessed for their impact on MR-associated compounds during ageing. Liqueur de dosage (composed of sugar, wine, and SO2) is an addition made post-disgorgement, and these sugars may degrade or interact with amino acids, thereby influencing the formation of MR compounds. To the best of our knowledge, no prior literature has investigated the role of Liqueur de dosage in the MR. In this research, six dosage sugar treatments were evaluated including D-glucose, D-fructose, sucrose (cane-derived), sucrose (beet-derived), maltose, and commercial rectified grape must concentrate (RCGM), in addition to a zero-dosage/control (no sugar added). Treatments were carried out on 2015 vintage sparkling wine (3 years on lees; 59% Chardonnay, 41% Pinot Noir) produced by Niagara College Teaching Winery in Niagara-on-the-Lake, ON. Dosage treatments were prepared from the sparkling wine base to approximately 6 g/L residual sugar. Bottles were sealed with cork closures and cellared on-site at the Cool Climate Oenology & Viticulture Institute with environmental controls for temperature and humidity. At intervals of 0, 9 and 18-months post-dosage addition, triplicate bottles of each wine were chemically analyzed. MR-associated products were quantified by HS-SPME-GC-MS. Precursors including sugars and amino acids were quantified by enzymatic assay and NMR techniques, respectively, and sugar purity was determined by HPLC. After 18 months of aging post-disgorging, four MRPs showed concentration differences (p < 0.05) between dosage sugar treatments (ethyl 3-mercaptopropionate, furfuryl ethyl ether, 2-ethylthiazole, and 2-furyl methyl ketone). Changes in sugar and amino acid content during ageing were used to relate changes in MR compound formation with precursor consumption. This study establishes the effect of dosage sugar-type on the formation of volatile MR compounds in traditional method sparkling wines during ageing.

References

1. Kemp, B.; Alexandre, H.; Robillard, B.; Marchal, R. J. Agric. Food Chem. 2015, 63 (1), 19–38. 
2. Le Menn, N.; Marchand, S.; De Revel, G.; Demarville, D.; Laborde, D.; Marchal, R. J. Agric. Food Chem. 2017, 65 (11), 2345–2356. 
3. Keim, H.; De Revel, G.; Marchand, S.; Bertrand, A. J. Agric. Food Chem. 2002, 50 (21), 5803–5807. 
4. Marchand, S.; Almy, J.; de Revel, G. J. Food Sci. 2011, 76 (6), 861-868.

DOI:

Publication date: June 23, 2022

Issue: IVAS 2022

Type: Article

Authors

Charnock Hannah1, Pickering Gary J.1,2,3,4, Kemp Belinda S.1,2

1Department of Biological Sciences, Faculty of Mathematics & Science, Brock University, 1812 Sir Isaac Brock Way, St. Catharines, ON, Canada, L2S 3A1
2Cool Climate Oenology & Viticulture Institute, Brock University, 1812 Sir Isaac Brock Way, St. Catharines, ON, Canada, L2S 3A1
3National Wine and Grape Industry Center, Charles Sturt University, McKeown Drive, Wagga Wagga, NSW 2678, Australia
4Sustainability Research Centre, University of the Sunshine Coast, 90 Sippy Downs Drive, Sippy Downs, QLD 4556, Australia

Contact the author

Keywords

sparkling wine, Maillard reaction, time-course ageing

Tags

IVAS 2022 | IVES Conference Series

Citation

Related articles…

Towards a regional mapping of vine water status based on crowdsourcing observations

Monitoring vine water status is a major challenge for vineyard management because it influences both yield and harvest quality. It is also a challenge at the territorial scale for identifying periods of high water restriction or zones regularly impacted by water stress. This information is of major importance for defining collective strategies, anticipating harvest logistic or applying for irrigation authorisation. At this spatial scale, existing tools and methods for monitoring vine water status are few and often require strong assumptions (e.g. water balance model). This paper proposes to consider a collaborative collection of observations by winegrowers and wine industry stakeholders (crowdsourcing) as an interesting alternative. Indeed, it allows the collection of a large number of field observations while pooling the collection effort. However, the feasibility of such a project and its interest in monitoring vine water status at regional scale has never been tested.

The objective of this article is to explore the possibility of making a regional map of vine water status based on crowdsourcing observations. It is based on the study of the free mobile application ApeX-Vigne, which allows the collection of observations about vine shoot growth. This information is easy to collect and can be considered, under certain conditions, as a proxy for vine water status. This article presents the first results obtained from the nearly 18,000 observations collected by winegrowers and wine industry stakeholders during 2019, 2020 and 2021 seasons. It presents the vine shoot growth maps obtained at regional scale and their evolution over the three vintages studied. It also proposes an analysis of the factors that favoured the number of observations collected and those that favoured their quality. These results open up new perspectives for monitoring vine water status at a regional scale but above they provide references for other crowdsourcing projects in viticulture.

Climate, Viticulture, and Wine … my how things have changed!

The planet is warmer than at any time in our recorded past and increasing greenhouse emissions and persistence in the climate system means that continued warming is highly likely. Climate change has already altered the basic framework of growing grapes for wine production worldwide and will likely continue to do so for years to come. The wine sector can continue to play an important role in leading the agricultural sector in addressing climate change. From developing on…

Elevational range shifts of mountain vineyards: Recent dynamics in response to a warming climate

Increasing temperatures worldwide are expected to cause a change in spatial distribution of plant species along elevational gradients and there are already observable shifts to higher elevations as a consequence of climate change for many species. Not only naturally growing plants, but also agricultural cultivations are subject to the effects of climate change, as the type of cultivation and the economic viability depends largely on the prevailing climatic conditions. A shift to higher elevations therefore represents a viable adaptation strategy to climate change, as higher elevations are characterized by lower temperatures. This is especially important in the case of viticulture because a certain wine-style can only be achieved under very specific climatic conditions. Although there are several studies investigating climatic suitability within winegrowing regions or longitudinal shifts of winegrowing areas, little is known about how fast vineyards move to higher elevations, which may represent a viable strategy for winegrowers to maintain growing conditions and thus wine-style, despite the effects of climate change. We therefore investigated the change in the spatial distribution of vineyards along an elevational gradient over the past 20 years in the mountainous wine-growing region of Alto Adige (Italy). A dataset containing information about location and planting year of more than 26000 vineyard parcels and 30 varieties was used to perform this analysis. Preliminary results suggest that there has been a shift to higher elevations for vineyards in general (from formerly 700m to currently 850 m a.s.l., with extreme sites reaching 1200 m a.s.l.), but also that this development has not been uniform across different varieties and products (i.e. vitis vinifera vs hybrid varieties and still vssparkling wines). This is important for climate change adaptation as well as for rural development. Mountain areas, especially at mid to high elevations, are often characterized by severe land abandonment which can be avoided to some degree if economically viable and sustainable land management strategies are available.

Upscaling the integrated terroir zoning through digital soil mapping: a case study in the Designation of Origin Campo de Borja

homogeneous zones by intersecting several partial zonings of major factors that influence vineyard growth. Each of them follows specific process from their corresponding disciplines. Soil zoning specifically refers to a Soil Resource Inventory map that has traditionally been generated by conventional soil mapping methods. These methods have shortcomings in reaching fine cartographic and categorical details and involve significant expenses, which undermines their applicability. A new framework named Digital Soil Mapping has introduced quantitative models by statistical techniques to establish soil-landscape relationships and is able to provide intensive scale cartography.

In the present study, a microzoning at 1:10.000 scale is generated from an initial zoning, where the conventional soil map with polytaxic map units is replaced by a new one from digital techniques that disaggregates them. The comparison between the zonings considers a quantitative evaluation of capability for each Homogeneous Terroir Unit by means of the Viticultural Quality Index and its categorization based on its distribution by map. The spatial intersection of both maps gives rise to a confusion matrix in which the flows of class variations after the substitution are assessed.

The results show a five-fold increase in the number of Homogeneous Terroir Units identified and a larger differentiation among them, evidenced by a wider range in the capability index distribution. Both elements are accompanied by an increase in the detection of areas of higher potential within previously undervalued uniform zones.These features are a direct effect of the improvements brought by Digital Soil Mapping techniques and would verify the advantages of their implementation in the Integrated Terroir zoning. Eventually, such new highly detailed terroir units would benefit precision viticulture and sustainable management practices.

Climate change impacts: a multi-stress issue

With the aim of producing premium wines, it is admitted that moderate environmental stresses may contribute to the accumulation of compounds of interest in grapes. However the ongoing climate change, with the appearance of more limiting conditions of production is a major concern for the wine industry economic. Will it be possible to maintain the vineyards in place, to preserve the current grape varieties and how should we anticipate the adaptation measures to ensure the sustainability of vineyards? In this context, the question of the responses and adaptation of grapevine to abiotic stresses becomes a major scientific issue to tackle. An abiotic stress can be defined as the effect of a specific factor of the physico-chemical environment of the plants (temperature, availability of water and minerals, light, etc.) which reduces growth, and for a crop such as the vine, the yield, the composition of the fruits and the sustainability of the plants. Water stress is in many minds, but a systemic vision is essential for at least two reasons. The first reason is that in natural environments, a single factor is rarely limiting, and plants have to deal with a combination of constraints, as for example heat and drought, both in time and at a given time. The second reason is that plants, including grapevine, have central mechanisms of stress responses, as redox regulatory pathways, that play an important role in adaptation and survival. Here we will review the most recent studies dealing with this issue to provide a better understanding of the grapevine responses to a combination of environmental constraints and of the underlying regulatory pathways, which may be very helpful to design more adapted solutions to cope with climate change.