IVAS 2022 banner
IVES 9 IVES Conference Series 9 IVAS 9 IVAS 2022 9 Assessment of Mineral Elements in Wine Spirits Aged with Chestnut Wood

Assessment of Mineral Elements in Wine Spirits Aged with Chestnut Wood

Abstract

The mineral composition of wine spirit (WS) is of relevant interest due to its potential effect on physicochemical stability, sensory characteristics, and safety.1 Calcium (Ca) and iron (Fe) can form insoluble compounds, negatively affecting the WS clarity. Transition metals, e.g. Fe and copper (Cu), seem to play an important catalytic role on oxidation reactions involving phenolic compounds and other substrates for oxidation in WS. Other elements such as Cu, zinc (Zn), arsenic (As), cadmium (Cd) and lead (Pb), are of concern due to their toxicological or physiological properties. The ageing of WS is traditionally performed in wooden barrels. In spite of the high quality achieved by the WS, this is a time-consuming and costly ageing technology, among other drawbacks. For these reasons, in recent years, special attention has been devoted to alternative ageing technologies, namely the application of wood fragments to WS kept in stainless steel, often combined with micro-oxygenation (MOX). Having in mind that wood ash main inorganic components are potassium (K), Ca and magnesium (Mg), but also sodium (Na) and Fe, the potential transference of these and other metals to the WS during ageing is expected. However, in spite of substantial understanding of the organic extractable compounds, little has been published on mineral elements extraction from wood to WS and even to wine, 2,3 and with the exception of a recent study of the authors focused on Fe and Cu, no data is available for chestnut wood.4 This study, developed within the Project Oxyrebrand (https://projects.iniav.pt/oxyrebrand/index.php/pt/), aimed to examine the effect of WS’s ageing with chestnut wood (Castanea sativa Mill.), considering traditional and alternative technologies, on the beverage mineral composition. A wine distillate was aged in 250 L chestnut barrels (traditional ageing) and in 50 L glass demijohns with chestnut wood staves combined with three levels of MOX and nitrogen application (alternative ageing technology), with two replicates. Sampling was carried out after 3 weeks, 2, 6, 9 and 12 months of ageing, and the WS was assessed in terms of mineral elements composition by adapting an Q-ICP-MS semi-quantitative method previously developed and validated. 5 A full mass spectrum (m/z = 6–240, omitting the mass ranges 16–18; 40, 41, 211–229) was obtained by full mass range scanning. ANOVA was performed to examine the influence of the ageing modality and ageing time on the mineral composition. At the end of the ageing essay, and for most part of the elements, no significant differences between WS from different ageing modalities were found. Ageing time had significant effect on most of the elements, with different trends and distinct magnitude of changes being observed, depending on the element. In general, the concentrations of the mineral elements found in the WS were quite low, which is positive from the WS quality point of view.

References

1 Catarino S., Curvelo-Garcia A.S., Bruno de Sousa R., 2008. Contaminant elements in wines: A review. Ciência Téc. Vitiv., 23, 3-19.
2 Pilet A., Bruno de Sousa R., Ricardo-da-Silva J.M., Catarino S., 2019. Barrel-to-barrel variation of phenolic and mineral composition of red wine. Bio Web Conf., 12,  02011.
3 Kaya A., Bruno de Sousa R., Curvelo-Garcia A.S., Ricardo-da-Silva J.R., Catarino S., 2017. Effect of wood aging on mineral composition and wine 87Sr/86Sr isotopic ratio. J. Agric. Food Chem., 65, 4766-4776.
4 Canas S., Danalache F., Anjos O., Fernandes T.A., Caldeira I., Santos N., Fargeton N., Boissier B., Catarino S., 2020. Behaviour of Low Molecular Weight Compounds, Iron and Copper of Wine Spirit Aged with Chestnut Staves under Different Levels of Micro-Oxygenation. Molecules, 25, 5266.
5 Catarino S., Curvelo-Garcia A.S., Bruno de Sousa, R., 2006. Measurements of contaminant elements of wines by inductively coupled plasma mass spectrometry: a comparison of two calibration approaches. Talanta, 70, 1073–1080.

DOI:

Publication date: June 23, 2022

Issue: IVAS 2022

Type: Poster

Authors

Catarino Sofia1,2, Vasiliki Thanasi1, Ofélia Anjos3,4,5, Tiago A. Fernandes6,7, Ilda Caldeira8,9, Laurent Fargeton10, Benjamin Boissier10 and Sara Canas8,9

1LEAF-Linking Landscape, Environment, Agriculture and Food-Research Center, Associated Laboratory TERRA, Instituto Superior de Agronomia, Universidade de Lisboa

2CEFEMA – Center of Physics and Engineering of Advanced Materials, Instituto Superior Técnico, Universidade de Lisboa
3Instituto Politécnico de Castelo Branco, Quinta da Senhora de Mércules
4CEF, Instituto Superior de Agronomia, Universidade de Lisboa, Tapada da Ajuda
5Centro de Biotecnologia de Plantas da Beira Interior
6CQE, Centro de Química Estrutural, Associação do Instituto Superior Técnico para a Investigação e Desenvolvimento (IST-ID), Universidade de Lisboa
7DCeT – Departamento de Ciências e Tecnologia, Universidade Aberta
8Instituto Nacional de Investigação Agrária e Veterinária, Quinta de Almoínha
9MED – Mediterranean Institute for Agriculture, Environment and Development, Instituto de formação avançada, Universidade de Évora
10Vivelys, Domaine du Chapître

Contact the author

Keywords

wine spirit ageing, mineral composition, chestnut wood, barrel, micro-oxygenation

Tags

IVAS 2022 | IVES Conference Series

Citation

Related articles…

Assessment of the impact of actions in the vineyard and its surrounding environment on biodiversity in Rioja Alavesa (Spain)

Traditional viticulture areas have experienced in the last decades an intensification of field practices, linked to an increased use of fertilisers and phytosanitary products, and to a more intensive mechanization and uniformization of the landscape. This change in management has sometimes led to higher rates of soil erosion andloss of soil structure, fertility decline, groundwater contamination, and to an increased pressure of pests and diseases. Additionally, intensification usually leads to a simplification of landscapes, of particular concern in prestigious wine grape regions where the economical revenue encourages the conversion of land use from natural habitats to high value wine grape production. To revert this trend, it is necessary that growers implement actions that promote biodiversity in their vineyards. The aim of this study is to assess the impact of the implementation of cover crops, vegetational corridors, dry stone walls and vineyard biodiversity hotspots estimated through the study of arthropods. The work has been carried out in four vineyards in Rioja Alavesa belonging to Ostatu winery, where these infrastructures were implemented in 2020. The presence and diversity of arthropods was studied by capturing them at different times in the season and at different distances from the infrastructure using pit-fall traps in the soil and yellow, white and blue chromatic traps at the canopy level. This is a preliminary study in which all adult insects were sorted to the taxonomic level of order and Coleoptera were classified to morphospecies. The results obtained show that there is a relationship between the basic characteristics of the vineyard and the arthropods captured, with a positive effect, although also dependent on the vineyard, of the presence of infrastructure.

Combining effect of leaf removal and natural shading on grape ripening under two irrigation strategies in Manto negro (Vitis vinifera L.)

The increasingly frequent heat waves during grape ripening pose challenges for high quality wine grape production. Defoliation is a common practice that can improve the control of diseases in bunches, but also it increases the exposure to sunlight. Grapes exposed to solar radiation reach temperatures over the optimum for berry development and maturation. This makes the development of irrigation and canopy management techniques of great importance to maximize yield and grape quality. A field experiment was carried out during 2021 using Manto negro wine grapes to study the effect of applied irrigation and different light exposure levels on grape quality. Two irrigation treatments were imposed based on the frequency and amount of water doses in a four-block experimental vineyard at Bodega Ribas (Mallorca). Three light exposure treatments were randomly applied in each irrigation plot. The light treatments included exposed clusters from pea size, non-exposed clusters, and shaded clusters after softening. Leaf area index and canopy porosity was estimated every 2 weeks. Midday leaf water potential was measured weekly. Additionally, apparent electrical conductivity was measured between rows to estimate the soil water content variability. Light and temperature sensors were installed at the bunch level to quantify the differences in bunch temperature and light intensity among treatments. The effect of irrigation and cluster light exposure on berry weight, TSS, TA, malic acid, tartaric acid, K+, and pH were analysed at 5 moments along grape ripening. During different heat waves, the natural shading technique decreased the maximum bunch temperature around 10 °C respect to the exposed bunches in both irrigation strategies. The combination of defoliation and shading techniques after softening decreased TSS at harvest and affected most of the quality parameters during the last stages of ripening, showing an interesting technique to delay ripening in warm viticulture areas.

Organic recycled mulches in sustainable viticulture: assessment of spontaneous plants communities and weed coverage

In recent years, developing more efficient and sustainable viticulture management has been essential due to the impact of climate change in semiarid regions. For this reason, the use of recycled organic mulching (ROM) in the vineyard has become an interesting strategy to cope with water stress, isolated soil from extreme temperatures and improving soil humidity, control the presence of weeds and therefore reduce the inputs of herbicides and improve soil fertility. This work aimed to analyse the effect of three different organic mulches [straw (S), grape pruning debris (GPD) and spent mushroom compost (SMC)] and two traditional soil management techniques [herbicide (H) and interrow (IN)] on weed coverage and the spontaneous plant communities’ presence. Data sampling was collected throughout the vine vegetative cycle of 2021 in La Rioja, Spain. The different soil management techniques had a clear effect on weed coverage and his development during the vine vegetative cycle. SMC and H were the treatments with the highest and the lowest coverage percentage, respectively. IN had a delayed weed emergence at the beginning of the vine vegetative cycle, but finally it reached maximum values nearby SMC. GPD and S had similar effects on weed emergence, reaching 25-30% of the maximum coverage values. A total of 29 herbaceous species were identified during the vegetative cycle, some of them very isolated and occasional. Principal component analysis (PCAs) showed a good association between spontaneous species and treatments, furthermore, specific species-treatment associations were found. Moreover, three clear groups of herbaceous communities were identified by cluster analysis. This study provides interesting information about the effect of different alternative soil management on herbaceous plant coverage and weed species communities which could contribute to making more sustainable viticulture.

Modulation of berry composition by different vineyard management practices

High concentration of sugars in grapes and alcohol in wines is one of the consequences of climate change on viticulture production in several wine-growing regions. In order to investigate the possibilities of adaptation of vineyard management practices aimed to reduce the accumulation of sugar during the maturation phase without reducing the accumulation of anthocyanins in grapes, a study with severe shoot trimming, shoot thinning, cluster thinning and date of harvest was conducted on Merlot variety in Istria region (Croatia), under the Mediterranean climate. Four factors which may affect grape maturation and its composition at harvest were investigated in a two-years experiment; severe shoot trimming applied at veraison when >80% of berries changed colour (in comparison to untreated control), shoot thinning (0 and 30%), cluster thinning (0 and 30%), and the date of harvest (early and standard harvest dates). Shoot thinning had no significant impact on berry composition, despite the obtained reduction in yield per vine. Lower Brix in grapes were obtained with earlier harvest date and if no cluster thinning was applied, although at the same time a reduction in the concentration of anthocyanins in berries was observed in these treatments. On the other hand, if severe shoot trimming was applied when >80% of berries changed colour, a reduction of Brix was obtained without a negative impact on berry anthocyanins concentration. We conclude that in cases when undesirably high sugar concentrations at harvest are expected, severe shoot trimming at 80% veraison may effectively be used in order to obtain moderate sugar concentration in berries together with the adequate phenolic composition.

Under-vine management effects on grapevine production, soil properties and plant communities in South Australia

Under-vine (UV) management has traditionally consisted of synthetic herbicide use to limit competition between weeds and grapevines. With growing global interest towards non-synthetic chemical use, this study aimed to capture the effects of alternative UV management at two commercial Shiraz vineyards in South Australia, where the sole management variables were UV management since 2016. In adjacent treatment blocks, cultivation (CU) was compared to spontaneous vegetation (SV) in McLaren Vale (MV), and herbicide was compared to SV in Eden Valley (EV). Soil water infiltration rates were slower and grapevine stem water potential was lower in CU compared to SV in MV, with the latter having a plant community dominated by soursob (Oxalis pes-caprae) during winter; while in EV, there was little separation between the treatments. Yields were affected at both sites, with SV being higher in MV and HE being higher in EV. In MV, the only effect on grape must was a lower 13C:12C isotope ratio in CU, indicating greater grapevine water stress. In the grape must at EV, SV had higher total soluble solids, total phenolics, anthocyanins, and yeast available nitrogen; and lower pH and titratable acidity. Pruning weights were not affected by the treatments in MV, while they were higher in HE at EV. Assessments revealed that the differing soil types at the two sites were likely the main determinants of the opposing production outcomes associated with UV management. In the silty loam soil of MV, the higher yields in SV were likely due to more plant-available water, as a potential result of the continuous soil bio-pores formed by winter UV vegetation. Conversely, in the loamy sand soils of EV with a lower cation exchange capacity, the lower yields and pruning weights in SV suggest the UV vegetation competed significantly with the grapevines for available water and nutrients.