IVAS 2022 banner
IVES 9 IVES Conference Series 9 IVAS 9 IVAS 2022 9 Assessment of Mineral Elements in Wine Spirits Aged with Chestnut Wood

Assessment of Mineral Elements in Wine Spirits Aged with Chestnut Wood

Abstract

The mineral composition of wine spirit (WS) is of relevant interest due to its potential effect on physicochemical stability, sensory characteristics, and safety.1 Calcium (Ca) and iron (Fe) can form insoluble compounds, negatively affecting the WS clarity. Transition metals, e.g. Fe and copper (Cu), seem to play an important catalytic role on oxidation reactions involving phenolic compounds and other substrates for oxidation in WS. Other elements such as Cu, zinc (Zn), arsenic (As), cadmium (Cd) and lead (Pb), are of concern due to their toxicological or physiological properties. The ageing of WS is traditionally performed in wooden barrels. In spite of the high quality achieved by the WS, this is a time-consuming and costly ageing technology, among other drawbacks. For these reasons, in recent years, special attention has been devoted to alternative ageing technologies, namely the application of wood fragments to WS kept in stainless steel, often combined with micro-oxygenation (MOX). Having in mind that wood ash main inorganic components are potassium (K), Ca and magnesium (Mg), but also sodium (Na) and Fe, the potential transference of these and other metals to the WS during ageing is expected. However, in spite of substantial understanding of the organic extractable compounds, little has been published on mineral elements extraction from wood to WS and even to wine, 2,3 and with the exception of a recent study of the authors focused on Fe and Cu, no data is available for chestnut wood.4 This study, developed within the Project Oxyrebrand (https://projects.iniav.pt/oxyrebrand/index.php/pt/), aimed to examine the effect of WS’s ageing with chestnut wood (Castanea sativa Mill.), considering traditional and alternative technologies, on the beverage mineral composition. A wine distillate was aged in 250 L chestnut barrels (traditional ageing) and in 50 L glass demijohns with chestnut wood staves combined with three levels of MOX and nitrogen application (alternative ageing technology), with two replicates. Sampling was carried out after 3 weeks, 2, 6, 9 and 12 months of ageing, and the WS was assessed in terms of mineral elements composition by adapting an Q-ICP-MS semi-quantitative method previously developed and validated. 5 A full mass spectrum (m/z = 6–240, omitting the mass ranges 16–18; 40, 41, 211–229) was obtained by full mass range scanning. ANOVA was performed to examine the influence of the ageing modality and ageing time on the mineral composition. At the end of the ageing essay, and for most part of the elements, no significant differences between WS from different ageing modalities were found. Ageing time had significant effect on most of the elements, with different trends and distinct magnitude of changes being observed, depending on the element. In general, the concentrations of the mineral elements found in the WS were quite low, which is positive from the WS quality point of view.

References

1 Catarino S., Curvelo-Garcia A.S., Bruno de Sousa R., 2008. Contaminant elements in wines: A review. Ciência Téc. Vitiv., 23, 3-19.
2 Pilet A., Bruno de Sousa R., Ricardo-da-Silva J.M., Catarino S., 2019. Barrel-to-barrel variation of phenolic and mineral composition of red wine. Bio Web Conf., 12,  02011.
3 Kaya A., Bruno de Sousa R., Curvelo-Garcia A.S., Ricardo-da-Silva J.R., Catarino S., 2017. Effect of wood aging on mineral composition and wine 87Sr/86Sr isotopic ratio. J. Agric. Food Chem., 65, 4766-4776.
4 Canas S., Danalache F., Anjos O., Fernandes T.A., Caldeira I., Santos N., Fargeton N., Boissier B., Catarino S., 2020. Behaviour of Low Molecular Weight Compounds, Iron and Copper of Wine Spirit Aged with Chestnut Staves under Different Levels of Micro-Oxygenation. Molecules, 25, 5266.
5 Catarino S., Curvelo-Garcia A.S., Bruno de Sousa, R., 2006. Measurements of contaminant elements of wines by inductively coupled plasma mass spectrometry: a comparison of two calibration approaches. Talanta, 70, 1073–1080.

DOI:

Publication date: June 23, 2022

Issue: IVAS 2022

Type: Poster

Authors

Catarino Sofia1,2, Vasiliki Thanasi1, Ofélia Anjos3,4,5, Tiago A. Fernandes6,7, Ilda Caldeira8,9, Laurent Fargeton10, Benjamin Boissier10 and Sara Canas8,9

1LEAF-Linking Landscape, Environment, Agriculture and Food-Research Center, Associated Laboratory TERRA, Instituto Superior de Agronomia, Universidade de Lisboa

2CEFEMA – Center of Physics and Engineering of Advanced Materials, Instituto Superior Técnico, Universidade de Lisboa
3Instituto Politécnico de Castelo Branco, Quinta da Senhora de Mércules
4CEF, Instituto Superior de Agronomia, Universidade de Lisboa, Tapada da Ajuda
5Centro de Biotecnologia de Plantas da Beira Interior
6CQE, Centro de Química Estrutural, Associação do Instituto Superior Técnico para a Investigação e Desenvolvimento (IST-ID), Universidade de Lisboa
7DCeT – Departamento de Ciências e Tecnologia, Universidade Aberta
8Instituto Nacional de Investigação Agrária e Veterinária, Quinta de Almoínha
9MED – Mediterranean Institute for Agriculture, Environment and Development, Instituto de formação avançada, Universidade de Évora
10Vivelys, Domaine du Chapître

Contact the author

Keywords

wine spirit ageing, mineral composition, chestnut wood, barrel, micro-oxygenation

Tags

IVAS 2022 | IVES Conference Series

Citation

Related articles…

Heatwaves and grapevine yield in the Douro region, crop model simulations

Heatwaves or extreme heat events can be particularly harmful to agriculture. Grapevines grown in the Douro winemaking region are particularly exposed to this threat, due to the specificities of the already warm and dry climatic conditions. Furthermore, climate change simulations point to an increase in the frequency of occurrence of these extreme heat events, therefore posing a major challenge to winegrowers in the Mediterranean type climates. The current study focuses on the application of the STICS crop model to assess the potential impacts of heatwaves in grapevine yields over the Douro valley winemaking region. For this purpose, STICS was applied to grapevines using high-resolution weather, soil and terrain datasets over the Douro. To assess the impact of heatwaves, the weather dataset (1989-2005) was artificially modified, generating periods with anomalously high temperatures (+5 ºC), at certain onset dates and with specific durations (from 5 to 9 days). The model was run with this modified weather dataset and results were compared to the original unmodified runs. The results show that heatwaves can have a very strong impact on grapevine yields, strongly depending on the onset dates and duration of the heatwaves. The highest negative impacts may result in a decrease in the yield by up to -35% in some regions. Despite some uncertainties inherent to the current modelling assessment, the present study highlights the negative impacts of heatwaves on viticultural yields in the Douro region, which is critical information for stakeholders within the winemaking sector for planning suitable adaptation measures.

Towards adaptation to climate change in Rioja: Quality evaluation of wines obtained from Grenache x Tempranillo selections

The wine sector is of great relevance and tradition in Mediterranean countries, however, it may be most susceptible to climate change. In recent years, wine production is facing changes worldwide, both at environmental as well as commercial levels, due to global warming and the shift in consumers’ preferences. Wine growers and wine makers are in search of solutions that allow to face these new challenges. One of the most promising initiatives in the long term is the introduction of new plant materials, specifically intraspecific hybridizations between premium varieties that may improve traditional germplasm in its adaptation to climate change. These inter-varietal crosses have the potential to generate quality wines, whilst maintaining the regional typicity, and constitute an attractive alternative for the consumer due to their sensory attributes. In this study, we have evaluated wines from 29 intraspecific Garnacha x Tempranillo hybrids in two different locations, with the aim to assess their oenological potential and sensory attributes. Thirteen of the selections were white and 16 were red. Microvinifications were conducted with two or three replications depending on grape availability. Conventional oenological parameters were determined for all wines. The sensory evaluation and hedonic scores were given by five experts. Red selections obtained higher quality scores than white ones. Among the white selections with higher quality scores, GT-41 Varea and GT-159 Varea outstand, due to their high total acidity and high malic acid content. Regarding red selections, GT-57 Varea and GT-57 UR were perceived as higher in quality, highlighted for their moderate alcoholic and high anthocyanin content. Our results indicate that intraspecific hybridization may be a powerful tool for adapting traditional cultivars to climate change in Rioja.

Local ancient grapevine cultivars to face future viticulture

Among the different strategies to cope with the negative impacts of climate change on viticulture, the exploitation of genetic diversity is one of the most promising to adapt to new conditions and maintain wine production and quality. One of the biggest concerns in the context of climate change is to improve water use efficiency (WUE). In this way, the use of genotypes that present a better response to drought and high WUE is a key issue. In this work, physiological performance analysis was conducted to compare the water deficit stress (WDS) responses of local and widespread grapevines cultivars. Leaf gas exchange, water use efficiency (WUE) at different levels (leaf and long-term WUE (∆13C)), leaf osmotic adjustment and other water relations parameters were determined in plants under well-watered and WDS conditions alongside assessment of the levels of foliar hormones concentrations. Results denote that local cultivars displayed better physiological performance under WDS as compared to the widely-distributed ones. he results corroborate the hypothesis that better stomatal control allows increasing leaf WUE under drought as occurred in the local Callet cv.; but the minority local cultivar Escursac cv. showed high WUE under both treatments. In this case, high WUE can be related to maintaining higher photosynthetic activity under drought. The different mechanisms underlying the better performance under WDS and high WUE of minority local cultivars are discussed.

Inhibition of Oenococcus oeni during alcoholic fermentation by a selected Lactiplantibacillus plantarum strain

The use of selected cultures of the species Lactiplantibacillus plantarum in Oenology has grown in prominence in recent years. While initial applications of this species centred very much around malolactic fermentation (MLF), there is strong evidence to show that certain strains can be harnessed for their bio-protective effects. Unwanted spontaneous MLF during alcoholic fermentation (AF), driven by rogue Oenococcus oeni, is a winemaking deviation that is very difficult to manage when it occurs. This work set out to determine the efficacy of one particular strain of Lactiplantibacillus plantarum(Viniflora® NoVA™ Protect), against this problem in Cabernet Sauvignon must. The work was carried out at commercial scale and in a winery environment and compared the bio-protective culture with the more traditional approach of reducing must pH by the addition of tartaric acid. The combination of both was also investigated. The concentration of both Oenococcus oeni and Lactiplantibacillus plantarum was determined using qPCR. The adventitious Oenococcus oeni showed the most growth during AF in the control wine, whereas in the wines treated with Lactiplantibacillus plantarum a bacteriostatic effect against this species was observed. This effect was comparable to the wines treated with tartaric acid. This has particular commercial relevance for controlling the flora in musts with high pH, or when the addition of tartaric acid is either not permitted or is prohibitive for other reasons.

The combined effects of climate, soils, and deficit irrigation on yield and quality of Touriga Nacional under high atmospheric demand in the Douro Region

Global warming is one of the biggest environmental, social and economic threats in several viticultural regions. In the Douro Valley, changes are expected in the coming years, namely an increase in temperature and a decrease in precipitation. These changes are likely to have consequences for the production and quality of wine.
The aim of this study was to explore the effects of different soil characteristics combined with several deficit irrigation strategies, managed throughout ETc references and predawn leaf water potentials thresholds, on physiology, yield, and qualitative attributes on the Touriga Nacional variety under years of mild to severe water and heat stress.
The studies were conducted over seven years (2015 to 2021) in two plots of a commercial vineyard located at Quinta do Ataíde (Symington Family Estates) planted in 2011 and 2014 at 170 meters elevation, growing under three water regimes: non-irrigated (NI) and two deficit irrigation strategies (30% and 60% ETc) assessed weekly by Ψpd. The site has an annual rainfall below 500 mm, with high atmospheric demand. Climate data was collected from a weather station, located on site. Berry ripening was followed weekly for fruit analysis. At harvest, yield, vigour and pruning weight per vine were determined from 90 vines by treatment. Each season at veraison the NDVI Index was accessed by a drone. The soils physic-chemistry in the experimental blocs were analysed and grouped by SWHC. Delta C-13 analyses were also performed per treatment in two years.Irrigation had a positive effect on yield per vine, mostly due to an increase in berry and cluster weight, and fertility index through the years. A significant increase in sugar content, colour and phenols was observed with deficit irrigation in some years, but vine vigour related to soil characteristics had by far the greatest impact on quality.