IVAS 2022 banner
IVES 9 IVES Conference Series 9 IVAS 9 IVAS 2022 9 Effect of alcoholic strength on the phenolic and furfural compounds of Brandy de Jerez aged in Sherry Casks®

Effect of alcoholic strength on the phenolic and furfural compounds of Brandy de Jerez aged in Sherry Casks®

Abstract

Brandy is a spirit drink produced from wine spirit aged for at least six months in oak casks with a capacity of less than 1000 L and minimum alcohol by volume (ABV) of 36%. During the aging process, physicochemical and sensory changes take place. Manifested by colour, flavour or aroma variations that improve the quality of the initial distillate. Influenced by several factors related with aging process itself and the characteristics of casks: botanical origin, volume, toasting degree, previous usage and pre-treatments, like the wine-seasoning process.Casks that have previously contained a Sherry wine (Fino, Oloroso, etc) gives rise to the so-called Sherry Cask®. The characteristics of Sherry Casks depends on the Sherry wine previously contained. They contribute during brandy aging with compounds from the wood, as well as with those from the wine that were retained in the wood’s pores. Potential extraction of these compounds is influenced by alcoholic strength. Traditionally, distillates are aged at between 50-70% ABV, although in some wineries at the alcoholic strength for consumption. Moreover, alcoholic strength has a direct impact on the logistics of the winery. An aging process with distillates of a higher alcoholic strength allows to obtain a greater volume of the final product (36% ABV) with less barrels required for the process. Barrels represent an immobilised asset for the wineries that has a direct impact on the production costs. Due to its importance, this work aims to study the influence of alcoholic strength on the composition of phenolic compounds in brandies aged for 12 months in Sherry Cask.Methods: A distillate at 77% ABV was hydrated with demineralised water to reach the different alcoholic strengths to be tested: 40%, 55% and 68% ABV. Brandies were aged in American oak (Quercus alba) casks, medium toast, with a capacity of 500 L and seasoned by 18% ABV Oloroso Sherry wine for 3 years. Distillates and Sherry Casks were supplied by Bodegas Fundador SLU, belonging to GI of Brandy de Jerez. Each test was carried out in duplicate, two barrels for each alcoholic strength, following a static aging process and samples were taken periodically to follow their evolution, showing in this study results up 12 months. The phenolic and furfural compounds were quantified by UHPLC. The results are expressed in mg/L 100% vol. alcohol in order to the different alcoholic strengths could be compared. Results: Brandies aged with lower alcoholic strength lead to a greater accumulation of phenolic compounds. In general, between 40 and 55% ABV there are no differences, while at 68% ABV lower values are obtained. This difference is more marked in phenolic acids (Gallic, Ellagic, Syringic and Vanillic acids) and furanic aldehydes (Furfural, 5-methylfurfural, 5-HMF) than in phenolic aldehydes (Vanillin, Syringaldehyde, Coniferaldehyde, Sinapaldehyde). For phenolics from wine-seasoning higher values was found for 40% ABV (Caffeic and Coumaric acids).

DOI:

Publication date: June 24, 2022

Issue: IVAS 2022

Type: Poster

Authors

Butrón Benítez Daniel1, Valcárcel-Muñoz Manuel J.2, García-Moreno M. Valme1, Guerrero-Chanivet María1,2 and Guillén-Sánchez Dominico A.1

1Department of Analytical Chemistry, Faculty of Science, IVAGRO. University of Cádiz.
2Bodegas Fundador S.L.U.

Contact the author

Keywords

Brandy, alcoholic strengths, ageing, phenolics, Sherry Cask

Tags

IVAS 2022 | IVES Conference Series

Citation

Related articles…

Ecophysiological performance of Vitis rootstocks under water stress

The use of rootstocks tolerant to soil water deficit is an interesting strategy to cope with limited water availability. Currently, several nurseries are breeding new genotypes, but the physiological basis of its responses under water stress are largely unknown. To this end, an ecophysiological assessment of the conventional 110-Richter (110R) and SO4, and the new M1 and M4 rootstocks was carried out in potted ungrafted plants. During one season, these Vitis genotypes were grown under greenhouse conditions and subjected to two water regimes, well-watered and water deficit. Water potentials of plants under water deficit down to < -1.4 MPa, and net photosynthesis (AN) <5 μmol m-2 s-1 did not cause leaf oxidative stress damage compared to well-watered conditions in any of the genotypes. The antioxidant capacity was sufficient to neutralize the mild oxidative stress suffered. Under both treatments, gravimetric differences in daily water use were observed among genotypes, leading to differences in the biomass of root, shoot and leaf. Under well-watered conditions, SO4 and 110R were the most vigorous and M1 and M4 the least. However, under water stress, SO4 exhibited the greatest reduction in biomass while M4 showed the lowest. Remarkably, under these conditions, SO4 reached the least negative stem water potential (Ψstem), while M1 reduced stomatal conductance (gs) and AN the most. In addition, SO4 and M1 genotypes also showed the highest and lowest hydraulic conductance values, respectively. Our results suggest that there are differences in water use regulation among genotypes, not only attributed to differences in stomatal regulation or intrinsic water use efficiency at the leaf level. Therefore, because no differences in canopy-to-root ratio were achieved, it is hypothesized that xylem vessel anatomical differences may be driving the reported differences among rootstocks performance. Results demonstrate that each Vitis rootstock differs in its ecophysiological responses under water stress.

Phenolic extraction and dissolved oxygen concentration during red wines fermentations with Airmixig M.I.™

During red wine fermentation, the extraction of phenolics compounds and sufficient oxygen provision are critical for wine quality [1,2]. In this trial, we aimed at evaluating the kinetics of phenolic extraction and dissolved oxygen during red wine fermentations using the airmixing system. Twenty lots of red grape musts were fermented in 300.000 L tanks, equipped with airmixing, using two injection regimes (i.e., high and low intensity, and high and low daily frequency). An oxygen analyzer was introduced into the tanks in order to record the concentration of dissolved oxygen over time.

Grapevine gas exchange responses to combined variations of leaf water, nitrogen and carbon status – a case of study of fungi tolerant varieties

In the context of climate change and the need to reduce inputs, optimising photosynthesis and grapevine performance requires a better understanding of the interactions between water status, nitrogen availability, and source-sink relationships.

Irrigation frequency: variation and agronomic and qualitative effects on cv. Tempranillo in the D. O. Ribera del Duero

The application of irrigation in vineyard cultivation continues to be a highly debated aspect in terms of the quantity and distribution of water throughout the vegetative growth period.

Optimizing protocol for a rapid and cost effective DNA isolation for Marker Assisted Selection pipeline

Grapevine is a plant that holds significant socioeconomic importance due to its production of grapes for fresh consumption, wines, and juices. However, climate changes and susceptibility to diseases pose a threat to the quality and yield of these products. The breeding of new genotypes that are resistant/tolerant to biotic and abiotic stresses is essential to overcome the impact of climate changes. In this regard, Marker-assisted selection (MAS), which uses DNA markers, is a crucial tool in breeding programs. The efficiency and economy of this method depend on finding rapid DNA isolation methods.