IVAS 2022 banner
IVES 9 IVES Conference Series 9 IVAS 9 IVAS 2022 9 Fermentative volatile compounds and chromatic characteristics can contribute to Italian white wines diversity

Fermentative volatile compounds and chromatic characteristics can contribute to Italian white wines diversity

Abstract

Perceived aroma plays an important role in wine quality, and it depends mainly on the volatile composition. Volatile organic compounds (VOCs) from grapes and those formed during winemaking are involved in the sensory complexity of wines. In aroma-neutral winegrape varieties, the winemaking process itself, and particularly alcoholic fermentation (AF), impacts strongly on the organoleptic characteristics of wines due to the formation of volatile alcohols, acids, and esters. In addition, phenolic compounds could contribute not only to the wine color but also to VOCs evolution during AF.
The main aim of the present study was to evaluate the differences in the concentration of fermentative VOCs among varieties from different Italian geographical zones. For this aim, 246 monovarietal white wines (vintage 2019) from 18 varieties cultivated in 9 different Italian regions were selected. Fermentative alcohols, acids, and esters were extracted by LLME and analyzed by GC-MS. Standard physico-chemical parameters, total polyphenol index, DPPH antioxidant activity, and chromatic characteristics including absorbance at 420 nm and CIELab coordinates were also determined.
Fermentative VOCs are ascribed to the management of FA, therefore the differences observed could be due to both the grape juice composition and the several factors driving FA (yeasts, nutrients, temperature). The results obtained show that fermentative compounds allow to differentiate some monovarietal wines. Albana wines were characterized by the highest average concentrations of total fermentative VOCs, particularly alcohols and ethyl esters, the latter reaching the highest value also in Fiano, Greco, and Pallagrello bianco. In turn, Fiano and Pallagrello showed the highest concentrations of aromatic alcohols. Falanghina and Vermentino wines contained the highest amount of acetates whereas Fiano was the richest in methyl esters. Gewürztraminer wines were the most abundant in volatile acids, followed by Ribolla gialla, Vermentino, Garganega, and Pinot grigio. In addition, Müller Thurgau and Verdicchio wines showed the lowest concentrations of total fermentative VOCs, particularly alcohols. Nosiola wines were characterized by the lowest abundance in acids and acetates, while Pinot grigio and Müller Thurgau wines contained the lowest amount of ethyl and methyl esters, respectively.
Regarding chromatic and phenolic characteristics, Pallagrello and Albana wines were characterized by the highest total phenolic content and antioxidant activity, but also were the darkest wines showing the highest value of b* color coordinate (yellowish). Conversely, Pinot grigio wines showed the lowest antioxidant activity and total phenolic compound concentration. Pinot grigio and Cortese wines had the lightest color and the lowest contribution of the yellow color component (b* coordinate and absorbance at 420 nm).

Acknowledgments: MIUR project PRIN n. 2017RXFFRR.

DOI:

Publication date: June 24, 2022

Issue: IVAS 2022

Type: Poster

Authors

Río Segade Susana1, Škrab Domen1, Paissoni Maria Alessandra1, Giacosa Simone1, Luzzini Giovanni2, Ugliano Maurizio2, Piergiovanni Maurizio3, Mattivi Fulvio3, Marangon Matteo4, Curioni Andrea4, Parpinello Giuseppina P.5, Versari Andrea5, Piombino Paola5, Moio Luigi5, Gerbi Vincenzo1 and Rolle Luca1

1Department of Agricultural, Forest and Food Sciences (DISAFA), University of Torino
2Department of Biotechnology, University of Verona, Italy
3Centre Agriculture Food Environment (C3A), University of Trento, Italy
4Department of Agronomy, Food, Natural Resources, Animals and Environment (DAFNAE), University of Padova, Italy
5Department of Agricultural Sciences, University of Naples Federico II, Italy

Contact the author

Keywords

volatile compounds, color characteristics, antioxidant potential, white wines, differentiation

Tags

IVAS 2022 | IVES Conference Series

Citation

Related articles…

Climate change impacts: a multi-stress issue

With the aim of producing premium wines, it is admitted that moderate environmental stresses may contribute to the accumulation of compounds of interest in grapes. However the ongoing climate change, with the appearance of more limiting conditions of production is a major concern for the wine industry economic. Will it be possible to maintain the vineyards in place, to preserve the current grape varieties and how should we anticipate the adaptation measures to ensure the sustainability of vineyards? In this context, the question of the responses and adaptation of grapevine to abiotic stresses becomes a major scientific issue to tackle. An abiotic stress can be defined as the effect of a specific factor of the physico-chemical environment of the plants (temperature, availability of water and minerals, light, etc.) which reduces growth, and for a crop such as the vine, the yield, the composition of the fruits and the sustainability of the plants. Water stress is in many minds, but a systemic vision is essential for at least two reasons. The first reason is that in natural environments, a single factor is rarely limiting, and plants have to deal with a combination of constraints, as for example heat and drought, both in time and at a given time. The second reason is that plants, including grapevine, have central mechanisms of stress responses, as redox regulatory pathways, that play an important role in adaptation and survival. Here we will review the most recent studies dealing with this issue to provide a better understanding of the grapevine responses to a combination of environmental constraints and of the underlying regulatory pathways, which may be very helpful to design more adapted solutions to cope with climate change.

Impact of geographical location on the phenolic profile of minority varieties grown in Spain. II: red grapevines

Because terroir and cultivar are drivers of wine quality, is essential to investigate theirs effects on polyphenolic profile before promoting the implantation of a red minority variety in a specific area. This work, included in MINORVIN project, focuses in the polyphenolic profile of 7 red grapevines minority varieties of Vitis vinifera L. (Morate, Sanguina, Santafe, Terriza Tinta Jeromo Tortozona Tinta) and Tempranillo) from six typical viticulture Spanish areas: Aragón (A1), Cataluña (A2), Castilla la Mancha (A3), Castilla –León (A4), Madrid (A5) and Navarra (A6) of 2020 season. Polyphenolic substances were extracted from grapes. 35 compounds were identified and quantified (mg subtance/kg fresh berry) by HPLC and grouped in anthocyanins (ANT) flavanols (FLAVA), flavonols (FLAVO), hydroxycinnamic (AH), benzoic (BA) acids and stilbenes (ST). Antioxidant activity (AA, mmol TE /g fresh berry) was determined by DPPH method. The results were submitted to a two-way ANOVA to investigate the influence of variety, area and their interaction for each polyphenolic family and cluster analysis was used to construct hierarchical dendrograms, searching the natural groupings among the samples. Sanguina (A3) had the most of total polyphenols while Tempranillo (A5) those of ANT. Sanguina (A2) and (A3) reached the highest values of FLAVO, FLAVA and AA. These two last samples had also the maximum of AA. The effect cultivar and area were significant for all polyphenolic families analyzed. A high variability due to variety (>50%) was observed in FLAVA and the maximum value of variability due to growing area was detected in AA (86.41%), ANT and FLAVO (51%); the interaction variety*zone was significant only for ANT, FLAVO, EST and AA. Finally, dendrograms presented five cluster: i) Sanguina (A2); ii) Sanguina (A3); iii) Tempranillo (A5); iv) Tempranillo (A3); Terriza (A3,A5), Morate (A5,A6); v) Santafé (A1,A6); Tortozona tinta (A1,A3,A6); Tinta Jeromo (A3,A4).

Influence of weather and climatic conditions on the viticultural production in Croatia

The research includes an analysis of the impact of weather conditions on phenological development of the vine and grape quality, through monitoring of four experimental cultivars (Chardonnay, Graševina, Merlot and Plavac mali) over two production years. In each experimental vineyard, which were evenly distributed throughout the regions of Slavonia and The Croatian Danube, Croatian Uplands,

‘Cabernet Sauvignon’ (Vitis vinifera L.) berry skin flavonol and anthocyanin composition is affected by trellis systems and applied water amounts

Trellis systems are selected in wine grape vineyards to mainly maximize vineyard yield and maintain berry quality. This study was conducted in 2020 and 2021 to evaluate six commonly utilized trellis systems including a vertical shoot positioning (VSP), two relaxed VSPs (VSP60 and VSP80), a single high wire (SH), a high quadrilateral (HQ), and a guyot (GY), combined with three levels of irrigation regimes based on different crop evapotranspiration (ETc) replacements, including a 25% ETc, 50% ETc, and 100% ETc. The results indicated SH yielded the most fruits and accumulated the most total soluble solids (TSS) at harvest in 2020, however, it showed the lowest TSS in the second season. In 2020, SH and HQ showed higher concentrations in most of the anthocyanin derivatives compared to the VSPs. Similar comparisons were noticed in 2021 as well. SH and HQ also accumulated more flavonols in both years compared to other trellis systems. Overall, this study provides information on the efficacy of trellis systems on grapevine yield and berry flavonoid accumulation in a currently warming climate.

Vineyards and clay minerals: multi-technique analytical approach and correlations with soil properties

Purpose of this research is to quantitatively assess the mineral component of vineyard soils, with particular attention to the mineralogical analysis of clays, which represent an element of high importance in the vineyard culture as well as in general agriculture. An X-ray diffraction (XRD) / thermogravimetric (TG) multi-technique analytical approach was developed, tested on soil samples taken from vineyards around the world. This codified analytical procedure was necessary to obtain precise qualitative and quantitative mineralogical data, globally comparable to distinguish the geopedological identity of the vineyards. Soil samples from vineyards of various locations were analysed, in very different geological conditions. The bulk-rock quantitative phase analysis (QPA) was obtained by the Rietveld method while the detailed composition of the clay-sized fraction was determined by modelling of the oriented X-ray diffraction patterns. The research provided a precise classification of the mineral component of soils, distinguishing the mineral phases of the clays and the so-called mixed-layer clay minerals. We found that the content in mixed layers can be directly correlated with the water retention and the cation exchange capacity ​​of the soil, while the presence of other clayey minerals and phyllosilicates in this research did not affect this CEC parameter, which codes the fertility level of the soils. The study demonstrates that terroir, in particular soils formed in complex or very different geological conditions, can only be effectively interpreted by properly analysing its mineral phases, in particular the mixed-layer clay component. These are characteristic abiotic ecological indicators, which may have specific eco-physiological influences on the plant.