Valorization of wine lees for oenological interest by eco-responsible processes

The capture and valorization of fermentative CO2 have been developed for several years by the company w platform for internal uses, notably in the cellars: inerting, cooling, reduction of water consumption, extraction, with aroma valorization. In a context of climatic warming during the vegetative cycle, grapes are currently harvested with a significant sugar concentration, a phenomenon that is expected to intensify in the coming decades. The high alcohol content of the resulting wines goes against the demand of customers who are seeking high-quality wines with less alcohol.

Bois noir (BN) is a cicada-transmitted grapevine disease that today causes up to 50% yield and vine loss in vineyards. It is caused by the phytoplasma Candidatus Phytoplasma solani (16SrXII-A).

The forchlorfenuron (CPPU) application is recommended in table-grape after fruit-set to boost berry sizing, albeit growers also apply CPPU during pre-flowering with controversial advantages. We examined the effect of single (BBCH 15) and double (BBCH 15 and 57) CPPU applications (2.25 mg/L a.s.) in a commercial vineyard. At each time, 75-100 bunches belonging to 6-9 vines were sprayed, and compared with unsprayed (CTRL). Leaf stomatal conductance (gs), cluster stem diameter and length were measured. At harvest, 25 berries/repetition were sampled for chemical composition, BSN incidence was counted (N° necrotic laterals/10 cm of stem) in 40 bunches/repetition. To test the role of air VPD on mineral composition, at BBCH 77, 50 CTRL clusters were bagged to induce a low VPD.

Several classes of flavonoids, such as anthocyanins, flavonols, flavanols and flavones, undergo a slow H/D exchange on aromatic ring A, leading to full deuteration at positions C(6) and C(8). Within the flavanol class, H-C(6) and H-C(8) of catechin and epicatechin are slowly exchanged in D2O to the corresponding deuterated analogues; even quercetin, a relevant flavonol representative, shows the same behaviour in a D2O/DMSOd6 1:1 solution. Detailed kinetic measurements of these H/D scrambling processes are here reported by exploiting the time-dependent changes of their peak areas in the 1H-NMR spectra taken at different temperatures. A unifying reaction mechanism is also proposed based on our detailed kinetic observations, even taking into account pH and solvent effects. Molecular modelling and QM calculations were also carried out to shed more light on several molecular details of the proposed mechanism.

Changing New Zealand climate equals a changing New Zealand terroir