IVAS 2022 banner
IVES 9 IVES Conference Series 9 IVAS 9 IVAS 2022 9 Red wine oxidation study by accelerating ageing tests and electrochemical method

Red wine oxidation study by accelerating ageing tests and electrochemical method

Abstract

Red wines can undergo many undesirable changes during the winemaking process and storage, particularly oxidative degradation due to numerous atmospheric oxygen intakes. This spoilage can impact organoleptic properties and color stabilization but this impact depends on the wine composition. Phenolic compounds constitute primary targets to oxidation reactions.
In order to obtain information on the oxidative behavior of red wines, oxygen consumption rates and electrochemical modifications (obtained by cyclic voltammetry) were measured for nine red wines subject to three different accelerated ageing tests (after wine air saturation). Chemical test (hydrogen peroxide add), enzymatic test (laccase from Trametes versicolor add) and temperature test (heat at 60°C) were carried out. Global phenolic composition, metals (Fe and Cu) and free SO2 concentrations were also determined. 
The obtained results showed oxidative behavior depended both on the wine sample and accelerated ageing test type. Good correlations were obtained between electrochemical parameters (charges at different potentials related to reductive properties) for non-oxidized wines and their variation after enzymatic and temperature tests, meaning that cyclic voltammetry could be used in order to predict these two oxidation tests and reflect the wine sensitivity towards respective oxidation targets. To strengthen this, good correlations were also obtained between the electrochemical parameters of the initial wines and oxygen consumption rates for these two tests. However, it was not possible to predict wine chemical oxidation test based on hydrogen peroxide from the electrochemical measurements.

DOI:

Publication date: June 24, 2022

Issue: IVAS 2022

Type: Poster

Authors

Garcia François1, Deshaies Stacy1, Garcia Luca1, Veran Frédéric2, Mouls Laetitia1 and Saucier Cédric1

1SPO-University of Montpellier
2SPO-INRAE Montpellier

Contact the author

Keywords

cyclic voltammetry; phenolic compounds; red wine; oxygen consumption rate; oxidation

Tags

IVAS 2022 | IVES Conference Series

Citation

Related articles…

Exemples de zonage au Chili et en Amérique Latine

Ce document présente la situation viticole des appellations d’origine en Argentine, Brésil, Chili et Uruguay. L’étude s’est restreinte uniquement à ces 4 pays, bien qu’il en existe d’autres avec une production viticole d’une certaine importance.

Non-saccharomyces yeasts in the biocontrol of grape molds in vineyards to reduce the use of pesticides

The wide diffusion of organic cultivation of vineyards and the need to reduce the use of pesticides highlights the urgent need for alternative and sustainable methods of vine protection by pathogen molds.

Bees, climate changes, and “environmental sustainability 4.1c” in viticulture and the territory for a new global multiproductive “biometaethical district 4.1c”

The use of bees as pollinators in vine varieties with physiologically female flowers (Picolit, Bicane, Ceresa, Moscato rosa, etc.) (Cargnello, 1983) and as bio-indicators for biodiversity and environmental sustainability is well-known. Furthermore, there are interests in: 1-a. Making the viticulture of Belluno (Province of Veneto in North-eastern Italy, which is also famous for the Dolomites -a UNESCO World Heritage-) regain the socioeconomic role which it is entitled to and which it had got in its past by aiming at the enhancement of local grape variety in harmony with others, for example with the neighboring area of the Conegliano and Valdobbiadene Prosecco Superiore DOCG; 2-a. Maintaining and further improving the important natural and healthy environment of Belluno, and making its territory and the “lookout” means of the environmental sustainability, including its vineyards, even more naturally original and sustainable 4.1C.

Stability of 3-mercaptohexanol during white wine storage in relationship to must pre-fermentative fining

3-Mercaptohexanol (3MH) is a volatile thiol occurring in several white and red wines, where it can contribute to fruity attributes. Its content is typically high in wines from certain grape varieties, in particular Sauvignon blanc, where it is considered a varietal marker. The strong nucleophilic character of thiols makes 3MH rather unstable during wine storage, due to the presence of several strong electrophilic species. Among these electrophilics, those arising from the oxidation of flavan3-ols such as catechin and epi-catechin have been indicated as critical for 3MH stability. Accordingly, there is a generalized interest towards the ability of vinification practices to reduce 3MH loss during aging through the management of wine flavan-3-ols content.

Assessment of environmental sustainability of wine growing activity in France

To meet the demand of assessment tool of vine growers and their advisers we adapted to the vine production the INDIGO® method to developed initially for arable farming.