WAC 2022 banner
IVES 9 IVES Conference Series 9 WAC 9 WAC 2022 9 1 - WAC - Posters 9 Wine by-products valorisation by green chemistry methods: Impact of the extraction process on the structure, functionalities and activity of the extracted molecules

Wine by-products valorisation by green chemistry methods: Impact of the extraction process on the structure, functionalities and activity of the extracted molecules

Abstract

Wine by-products valorisation by green chemistry methods: Impact of the extraction process on the structure, functionalities and activity of the extracted molecules

Viniculture is a huge socio-economic activity throughout the world, 57% of worldwide grape production is for wine-making industry. Wine-making generates huge amounts of by-products (grape pomace (skins, pulp, seeds and stalks), which is around 20 % of total wine production [1]. Wine by-products shown to have a big potential to be used for the extraction of valuable high-added components, however they are sent directly to distilleries for alcohol, spirits and piquette production. The treatment of biomass is often challenging due to its complex matrix

and composition. Heavy industrialization and associated huge environmental impact make reconsidering traditional chemistry methods.

The aim of our work is to valorise valuable components (pectins, fatty acids, polyphenols) from grape by-products by implementing green chemistry methods such as microwave-assisted extraction (MAE), and supercritical CO2 extraction (SFE). In this work, grape pomace from white grapes was considered for the extractions. By using MAE, we were able to extract pectin with a yield up to 8% from grape pomace. Fatty acids were successfully extracted by SFE from grape pomace with CO2 under 40° C, 400 bar and by using ethanol 5% as co-solvent. Water as co-solvent 10 % in supercritical CO2 extraction lead to burgundy coloured liquid, which contained wine related phenolic compounds detected by U-HPLC (gallic and caftaric acids, hydroxytyrosol, catechin). In addition, the coloured extracts undergo pectin isolation procedure and freeze-dried. Initial observation of the extract by FTIR show similar signature to industrial pectin. The findings show possible valorisation of pectin, grape seed oil and phenolic compounds from wine pomace.

[1]        Arvanitoyannis I. S., Ladas D., Mavromatis A., « Wine waste treatment methodology », Int J Food Sci Tech, vol. 41, no 10, p. 1117‑1151, 2006

DOI:

Publication date: June 27, 2022

Issue: WAC 2022

Type: Article

Authors

Gayane Hayrapetyan, Karen Trchounian, Maria Nikolantonaki , Régis Gougeon, Elias Bou-Maroun, Dijon, Ali Assifaoui

Presenting author

Gayane Hayrapetyan – UMR PAM, Equipe PCAV, Université de Bourgogne/Institut Agro, Dijon

Yerevan State University, Biochemistry, Microbiology, Biophysics, Biotechnologyi | UMR PAM, Equipe PCAV, Université de Bourgogne/Institut Agro, Dijon

Contact the author

Keywords

Winery waste, green chemistry, extraction, SFE CO2, oil, pectin

Tags

IVES Conference Series | WAC 2022

Citation

Related articles…

Defining the terroir of the Columbia gorge wine region, Oregon and Washington, USA using geographic information systems (GIS)

The Columbia Gorge Wine Region (CGWR) extends for about 100km along the Columbia River and includes the Columbia Gorge American Viticultural Area (AVA) and the southwest portion of the Columbia Valley AVA.

First step in the preparation of a soil map of the Protected Designation of Origin Valdepeñas (Central, Spain)

This work is a first step to make a map of vineyard soils. The characterization of the soils of the Protected Designation of Origin (D.P.O.) Valdepeñas will allow to group the studied profiles according to their physico-chemical characteristics and the concentrations of most relevant chemical elements. 90 soil profiles were analysed throughout the territory and the soils were sampled and described according to FAO (2006) and classified according to and Soil Taxonomy (2014). All samples were air dried, sieved and some physico-chemical parameters were determined following standard protocols. Also, major and trace elements were analysed by X-ray fluorescence. The statistically study was made using the SPSS program. Trend maps were made using the ArcGIS program. The studied soils have the following average properties: pH, 8.3; electrical conductivity, 0,20 dS/m (low); clay, 18.8% (medium) and CaCO3, 17.1% (high). In the study for the major elements. The major elements of these soils are Si, followed by Ca and Al, with an average content of 203.7 g/kg, 105.5 g/kg and 74.0 g/kg respectively. On the other hand, 27 trace elements have been studied. Of all of them, it can be highlighted the average values of Ba (361.8 mg/kg), Sr (129.3 mg/kg), Rb (83.4 mg/kg), V (74.2 mg/kg) and Ce (70.6 mg/kg). Ba, V and Ce values are higher and the values of Sr and Rb are lower to those found in the literature. The discriminant analysis shows a percentage of grouping of 91%. The content of chemical elements together with the physico-chemical characteristics allows grouping the soils in 4 group according to their order in the classification to Soil Taxonomy; due to the importance of the Calcisols in Castilla-La Mancha, it has been decided to establish them as their own group even if they do not appear in Soil Taxonomy classification.

Time vs drought: leaf age rather than drought drives osmotic adjustment in V. vinifera cv. Pinot Noir

Global warming and increased frequency and/or severity of drought events are among the most threatening consequences of climate change for agricultural crops. In response to drought, grapevine (as many other plants) exhibits osmotic adjustment through active accumulation of osmolytes which in turn shift the leaf turgor loss point (TLP) to more negative values, allowing to maintain stomata opened at lower water potentials1. We investigated the capacity of Pinot noir leaves to modulate their osmotic potential as a function of: (i) time (seasonal osmoregulation), (ii) growing temperatures, and (iii) drought events, to enhance comprehension of the resilience of grapevines in drought conditions. We performed trails under semi-controlled field conditions, and in two different greenhouse chambers (20/15 °C vs 25/20 °C day/night). For two consecutive vegetative seasons, grafted potted grapevines (Pinot noir/SO4) were subjected to two different water regimes for at least 30 days: well-watered (WW) and water deficit (WD).

Monitoring water deficit in vineyards by means of Red and Infrared measurements

Vineyard water availability is one of the most important variables both in plant’s production and wine quality, once it regulates several processes, among which the stomata activity. To avoid water deficit, wine producers introduced artificial irrigation in their vineyard, using a semi-empirical process to calculate water amount.

Méthodologie pour application et valorisation des études de terroir dans les caves cooperatives des Côtes du Rhône (France)

L’appellation d’origine contrôlée “Côtes du Rhône” se caractérise par une très forte implantation du mouvement coopératif. Afin de mieux exploiter le potentiel qualitatif de leurs terroirs, plusieurs coopératives élaborent des “cuvées terroir”, résultat des sélections de vendanges provenant de différents secteurs.