OENO IVAS 2019 banner
IVES 9 IVES Conference Series 9 Aroma chemical profiles characterization of wines produced with moristel grapes harvested at different time points

Aroma chemical profiles characterization of wines produced with moristel grapes harvested at different time points

Abstract

The wine aroma is constituted by hundred of volatile chemical compounds that depend on many viticultural and oenological factors. One of the most important factors that will unequivocally affect the final wine pro-perties is the grape maturity level. Grape ripening is an extremely complex process, in which the metabolites and precursors concentrations change significantly with time. However, the knowledge of how grape ripe-ning affects wine aroma composition is still quite limited. Nowadays, wineries measure parameters such as sugar, pH, acidity and colorimetric tests to evaluate the degree of maturity of the vintage and decide the harvest data, but these analysis do not take into consideration the aromatic potential of the grape. The objective of the present work is to understand the differences in the aroma chemical profile of Moristel wines from different vineyards harvested at different time points. So, three different vineyards of Moris-tel grape variety in D.O. Somontano were selected, in two consecutive vintages: two in 2016 and one in 2017. Each block was harvested at different time points followed by microvinifications applying the same fermentation protocol. All of them have been elaborated in triplicated. This was assessed by the analysis of major aroma compounds (GC-FID), trace aroma compounds (GC-MS), methoxypyrazines (TD-GCxGC-MS), polyfunctionalmercaptans (SPE GC-MS), volatile sulfur compounds (BR-VSCs) and total acetaldehyde (HPLC-UV/VIS). The most important result is that the grapes harvested at 42 days postveraison, that is the “green” ones, pro-duce wines with high concentration of acetaldehyde and low IPT. Hence, low concentration of polyphenols facilitate the accumulation of this compound. Another reason for these acetaldehyde high concentrations could be problems associated with the lack of reduction factors (NADH or NADPH). This fact is also corroborated with the decreases of branched acid / fusel alcohol and branched ester/fu-sel alcohol ratios during the maturity. These facts can have very important sensory repercussion, the acetaldehyde and fusel alcohol are components of aroma buffer.

Finally, the evolution of certain maturity markers (c-3-hexenol, Y-nonalactona, rotundone) has been also observed, but these target compounds, by themselves, do not seem to have great sensory relevance in the final wines. This study has help to elucidate how grape maturity state contributes to final Moristel wine aroma profile and possible self-life.

Acknowledgements

This work has been funded by the Spanish MINECO (Project AGL2014-59840, RTC 2015-3379 and RTC-2016-4935-2) and partly co-funded by the European Union (FEDER). I.A. has re-ceived a grant from the Spanish FPU programs. Funding from D.G.A. (T53) and Fondo Social Europeo is acknowledged.

DOI:

Publication date: June 9, 2020

Issue: OENO IVAS 2019

Type: Article

Authors

Ignacio Arias, Sara Ferrero-del-Teso, María Pilar Sáenz-Navajas, Purificación Fernández-Zurbano,Blanca Lacau, Jesús Astraín, Cristina Barónv Vicente Ferreira, Ana Escudero

Instituto de Ciencias de la Vid y el Vino (ICVV) (Universidad de La Rioja-CSIC-Gobierno de La Rioja), Carre-tera de Burgos Km. 6, Finca La Grajera, 26007 Logroño, La Rioja, Spain
Laboratorio de análisis del aroma y enología (LAAE). Department of Analytical Chemistry, Universidad de Zaragoza, Instituto Agroalimentario de Aragón (IA2) (UNIZAR-CITA). Calle Pedro Cerbuna, 12, 50009 Zaragoza

Contact the author

Keywords

Wine aroma, maturity, acetaldehyde, reduction factors

Tags

IVES Conference Series | OENO IVAS 2019

Citation

Related articles…

Grape berry size is a key factor in determining New Zealand Pinot noir wine composition

Making high quality but affordable Pinot noir (PN) wine is challenging in most terroirs and New Zealand’s (NZ) situation is no exception. To increase the probability of making highly typical PN wines producers choose to grow grapes in cool climates on lower fertility soils while adopting labour intensive practices. Stringent yield targets and higher input costs necessarily mean that PN wine cost is high, and profitability lower, in line-priced varietal wine ranges. To understand the reasons why higher yielding vines are perceived to produce wines of lower quality we have undertaken an extensive study of PN in NZ. Since 2018, we established a network of twelve trial sites in three NZ regions to find individual vines that produced acceptable commercial yields (above 2.5kg per vine) and wines of composition comparable to “Icon” labels. Approximately 20% of 660 grape lots (N = 135) were selected from within a narrow juice Total Soluble Solids (TSS) range and made into single vine wines under controlled conditions. Principal Component Analysis of the vine, berry, juice and wine parameters from three vintages found grape berry mass to be most effective clustering variable. As berry mass category decreased there was a systematic increase in the probability of higher berry red colour and total phenolics with a parallel increase in wine phenolics, changed aroma fraction and decreased juice amino acids. The influence of berry size on wine composition would appear stronger than the individual effects of vintage, region, vineyard or vine yield. Our observations support the hypothesis that it is possible to produce PN wines that fall within an “Icon” benchmark composition range at yields above 2.5kg per vine provided that the Leaf Area:Fruit Weight ratio is above 12cm2 per g, mean berry mass is below 1.2g and juice TSS is above 22°Brix.

Grapevine yield-gap: identification of environmental limitations by soil and climate zoning in Languedoc-Roussillon region (south of France)

Grapevine yield has been historically overlooked, assuming a strong trade-off between grape yield and wine quality. At present, menaced by climate change, many vineyards in Southern France are far from the quality label threshold, becoming grapevine yield-gaps a major subject of concern. Although yield-gaps are well studied in arable crops, we know very little about grapevine yield-gaps. In the present study, we analysed the environmental component of grapevine yield-gaps linked to climate and soil resources in the Languedoc Roussillon. We used SAFRAN data and IGP Pays d’Oc wine yields from 2010 to 2018. We selected climate and soil indicators proving to have a significant effect on average wine yield-gaps at the municipality scale. The most significant factors of grapevine yield were the Soil Available Water Capacity; followed by the Huglin Index and the Climatic Dryness Index. The Days of Frost; the Soil pH; and the Very Hot Days were also significant. Then, we clustered geographical zones presenting similar indicators, facilitating the identification of resources yield-gaps. We discussed the number of zones with the experts of IGP Pays d’Oc label, obtaining 7 zones with similar limitations for grapevine yield. Finally, we analysed the main resources causing yield-gaps and the grapevine varieties planted on each zone. Mapping grapevine resource yield-gaps are the first stage for understanding grapevine yield-gaps at the regional scale.

Mechanisms involved in the heating of the environment by the aerodynamic action of a wind machine to protect a vineyard against spring frost

One of the main consequences of global warming is the rise of the mean temperature. Thus, the heat summation by the plants begins sooner in the early spring, and by cumulating growing degree-days, phenological development tends to happen earlier. However, spring frost is still a recurrent phenomenon causing serious damages to buds and therefore, threatening the harvests of the winegrowers. The wind machine is a solution to protect fruit crops against spring frost that is increasingly used. It is composed of a 10-m mast with a blowing fan at its peak. By tapping into the strength of the nocturnal thermal inversion, it sweeps the crop by propelling warm air above to the ground. Thus, stratification is momentarily suppressed. Furthermore, the continuous action of the machine, alone or in synergy, or the addition of a heater allow the bud to be bathed in a warmer environment. Also, the punctual action of the tower’s warm gust reaches the bud directly at each rotation period. All these actions allow the bud to continuously warm up, but with different intensities and over a different period. Although there is evidence of the effectiveness of the wind machines, the thermal transfers involved in those mechanisms raise questions about their true nature. Field measurements based on ultrasonic anemometers and fast responding thermocouples complemented by laboratory measurements on a reduced scale model allow to characterize both the airflow produced by the wind machine and the local temperature in its vicinity. Those experiments were realized in the vineyard of Quincy, in the framework of the SICTAG project. In the future paper, we will detail the aeraulic characterization of the wind machine and the thermal effects resulting from it and we will focus on how the wind machine warms up the local atmosphere and enables to reduce the freezing risk.

Second pruning as a strategy to delay maturation in cv. ‘Touriga nacional’ in the Portuguese Douro region

The advance in maturation of wine grapes is an important climate change risk related effect that could affect warm regions like Portuguese Douro Wine Region. Indeed, the climate analysis over the past years registered a decrease in the precipitation, significant higher average temperatures, and a more frequent occurrence of extreme weather events, including heat waves. In these conditions the length from anthesis until maturation is shortened and the uncoupling of technical and phenolic maturity results in berries with higher sugar concentration (and lower acidity), but lower anthocyanins, tannins, and total phenolic concentration, which produce unbalanced wines.
In this work, an innovative strategy of crop forcing, based on forcing vine regrowth after a second pruning of green shoots, was tested, aimed at delaying ripening until the temperature becomes lower and, therefore, preventing acidity loss and increasing anthocyanin-to-sugar ratio. The experiments were conducted in 2019 and 2020 in a commercial vineyard of ‘Touriga Nacional’ located in the Douro Region. Crop forcing was conducted 15 (CF1) to 30 (CF2) days after fruit set. Vines pruned with conventional methods were used as control (CF0). Results confirmed that fruit ripening was shifted from the hot season (August/September), until a cooler period (October through early-November). At harvest, grapevine berries from CF1 and CF2 presented lower pH and higher acidity, than control, with no significant differences in colour intensity and phenolic levels composition. Sugar content was lower in CF2-treated vines in both seasons. However, in CF-treated vines the number and size of clusters were significantly lower (up to 88% reduction) than in control plants. A metabolomics analysis of mature berries from CF-treated vines and control is underway. Crop forcing was indeed effective in producing a more balance berry composition but severely reduced grapevine yield,

A better understanding of the climate effect on anthocyanin accumulation in grapes using a machine learning approach

The current climate changes are directly threatening the balance of the vineyard at harvest time. The maturation period of the grapes is shifted to the middle of the summer, at a time when radiation and air temperature are at their maximum. In this context, the implementation of corrective practices becomes problematic. Unfortunately, our knowledge of the climate effect on the quality of different grape varieties remains very incomplete to guide these choices. During the Innovine project, original experiments were carried out on Syrah to study the combined effects of normal or high air temperature and varying degrees of exposure of the berries to the sun. Berries subjected to these different conditions were sampled and analyzed throughout the maturation period. Several quality characteristics were determined, including anthocyanin content. The objective of the experiments was to investigate which climatic determinants were most important for anthocyanin accumulation in the berries. Temperature and irradiance data, observed over time with a very thin discretization step, are called functional data in statistics. We developed the procedure SpiceFP (Sparse and Structured Procedure to Identify Combined Effects of Functional Predictors) to explain the variations of a scalar response variable (a grape berry quality variable for example) by two or three functional predictors (as temperature and irradiance) in a context of joint influence of these predictors. Particular attention was paid to the interpretability of the results. Analysis of the data using SpiceFP identified a negative impact of morning combinations of low irradiance (lower than about 100 μmol m−2 s−1 or 45 μmol m−2 s−1 depending on the advanced-delayed state of the berries) and high temperature (higher than 25oC). A slight difference associated with overnight temperature occurred between these effects identified in the morning.